| INTERNATIONAL UNION OF PURE AND APPLIED CHEMISTRY |
| ANALYTICAL CHEMISTRY DIVISION |
| COMMISSION ON SOLUBILITY DATA |
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| SOLUBILITY DATA SERIES |
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| Editor-in-Chief |
| A. S. KERTES |
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| Volume 26 |
| SULFITES, SELENITES AND TELLURITES |
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| Volume Editors |
| MARY R. MASSON | University of Aberdeen Scotland, UK |
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| Co-Editors |
| H. D. LUTZ | University of Siegen Federal Republic of Germany |
| B. ENGELEN | University of Siegen Federal Republic of Germany |
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| Contributors |
| M. R. MASSON | |
| H. D. LUTZ | |
| B. ENGELEN | |
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| Copyright � 1986 International Union of Pure and Applied Chemistry |
| Contents | v |
| Foreword | viii |
| Preface | xi |
| Introduction to the Solubility of Solids in Liquids | xvi |
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| 1 | Sodium Bisulfite |
| | 1.1 | Evaluation | 1 |
| | 1.2 | Binary system | 8 |
| | 1.3 | Ternary systems | 16 |
| | 1.4 | More complex systems | 59 |
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| 2 | SodIum pyrosulfIte (sodIum dIsulflte) |
| | 2.1 | Evaluation | 72 |
| | 2.2 | Binary system | 72 |
| | 2.3 | Ternary systems | 76 |
| | 2.4 | More complex systems | 78 |
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| 3 | Potassium sulfite |
| | 3.1 | Evaluation | 90 |
| | 3.2 | Binary system | 93 |
| | 3.3 | Ternary systems | 95 |
| | 3.4 | More complex systems | 107 |
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| 4 | Potassium pyrosulfite (potassium disulfite) |
| | 4.1 | Evaluation | 108 |
| | 4.2 | Binary system | 110 |
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| 5 | Ammonium sulfite |
| | 5.1 | Evaluation | 113 |
| | 5.2 | Binary system | 117 |
| | 5.3 | Ternary systems | 121 |
| | 5.4 | More complex systems | 141 |
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| 6 | Ammonium pyrosulfite (ammonium disulfite) |
| | 6.1 | Evaluation | 144 |
| | 6.2 | Binary system | 146 |
| | 6.3 | Ternary systems | 147 |
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| 7 | Beryllium sulfite | 152 |
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| 8 | Magnesium sulfite |
| | 8.1 | Evaluation | 153 |
| | 8.2 | Binary system | 160 |
| | 8.3 | Ternary systems | 165 |
| | 8.4 | More complex systems | 180 |
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| 9 | Calcium sulfite |
| | 9.1 | Evaluation | 187 |
| | 9.2 | Binary system | 194 |
| | 9.3 | Ternary systems | 196 |
| | 9.4 | More complex systems | 220 |
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| 10 | Strontium sulfite | 236 |
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| 11 | Barium sulfite | 240 |
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| 12 | Manganese (II) sulfite | 248 |
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| 13 | Iron(II) sulfite | 252 |
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| 14 | Cobalt (II) sulfite | 256 |
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| 15 | Nickel (II) sulfite | 258 |
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| 16. | Copper (I) sulfite | 260 |
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| 17 | Copper (I,II) sulfite | 262 |
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| 18 | Silver sulflte | 267 |
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| 19 | Zinc sulfite | 271 |
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| 20 | Cadmium sulfite | 286 |
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| 21 | Mercury (I) sulfite | 291 |
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| 22. | Lead (II) sulfite | 293 |
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| 23 | Sodium selenite | 303 |
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| 24 | Potassium selenite | 322 |
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| 25 | Alkali-metal selenites |
| | 25.1�� | Evaluation | 331 |
| | 25.2�� | Lithium selenite | 332 |
| | 25.3�� | Sodium pyroselenite (sodium diselenite) | 333 |
| | 25.4�� | Sodium trihydrogen diselenite | 336 |
| | 25.5�� | Potassium pyroselenite (diselenite) | 338 |
| | 25.6�� | Potassium trihydrogen diselenite | 340 |
| | 25.7�� | Ammonium selenite | 342 |
| | 25.8�� | Ammonium pyroselenite (diselenite) | 344 |
| | 25.9�� | Ammonium trihydrogen diselenite | 346 |
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| 26 | Sparingly soluble selenites |
| | 26.1�� | Evaluation | 348 |
| | 26.2�� | Beryllium selenite | 353 |
| | 26.3�� | Magnesium selenite | 354 |
| | 26.4�� | Calcium selenite | 356 |
| | 26.5�� | Strontium selenite | 358 |
| | 26.6�� | Barium selenite | 362 |
| | 26.7�� | Manganese (II) selenite | 367 |
| | 26.8 | Iron(III) selenite | 368 |
| | 26.9�� | Cobalt (II) selenite | 370 |
| | 26.10� | Nickel (II) selenite | 374 |
| | 26.11� | Copper (II) selenite | 377 |
| | 26.12� | Silver selenite | 380 |
| | 26.13 | Zinc selenite | 389 |
| | 26.14� | Cadmium selenite | 391 |
| | 26.15� | Mercury( I) selenite | 394 |
| | 26.16� | Mercury (II) selenite | 397 |
| | 26.17� | Lead( II) selenite | 401 |
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| 27 | Tellurites (salts of the tellurate (IV) ion) |
| | 27.1�� | Evaluation | 403 |
| | 27.2�� | Lithium tellurite | 406 |
| | 27.3�� | Sodium tellurite | 407 |
| | 27.4�� | Cesium tellurite | 419 |
| | 27.5�� | Barium tellurite | 420 |
| | 27.6�� | Cobalt (II) tellurite | 421 |
| | 27.7 | Nickel (II) tellurite | 422 |
| | 27.8 | Copper (II) tellurite | 423 |
| | 27.9 | Silver tellurite | 424 |
| | 27.1 | Lead( II) tellurite | 427 |
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| System Index | 429 |
| Registry Number Index | 443 |
| Author Index | 446 |