Bibliographic Information

Title: Ambient Pressure Synthesis and Neutron Structure Analysis of YBa2Cu4O8
Author(s): I.K. Gopalakrishnan, J.V. Yakhmi, H. Rajagopal, A. Sequeira, and R.M. Iyer
Publication: Physica C Volume: 182 Issue: Not Available Year: 1991 Page(s): 67-72
Editor(s): Not Available
Publisher: Elsevier Science Publishers B.V.
Language: English
Notes: Not Available
Keywords: Material Specification, Crystallography, Critical Temperature, Magnetic Susceptibility

Materials and Properties

Y:124; [Y-Ba-Cu-O]
Material Specification for Y:124; [Y-Ba-Cu-O] Process: Solid State Reaction
Notes: "The synthesis protocol... was essentially a two-step process. In the first step, a stable precursor matrix with the nominal composition BaCu2O3 (essentially it is a 1:1 mixture of BaCuO2 and CuO) was prepared by reacting CuO and Ba(NO3)2 in the appropriate ratio at 1175 K for about 48 h, with several intermittent grindings. In the second step the matrix was ground, mixed thoroughly with Y2O3, pelletised and sintered at 1085 K in flowing oxygen at ambient pressure for long intervals of time (more than one week) during which the material was taken out from the furnace several times and ground for homogenisation, repelletised and kept for further sintering."
Formula: YBa2Cu4O8
Informal Name: Y:124
Chemical Family: Y-Ba-Cu-O
Chemical Class: Oxide
Structure Type: Polycrystalline
Manufacturer: In House
Commercial Name: In House
Production Date:
Lot Number:
Production Form:

Crystallography for Y:124; [Y-Ba-Cu-O]
Crystal System: Orthorhombic
Formula Units per Cell:
Space Group: Ammm
Cell Parameters
Occupancy () Temp K a Å b Å c Å
-- 296 3.840(2) 3.870(2) 27.245(18)
Atomic Coordinates
Occupancy () Atom Temp K a-axis b-axis c-axis
1.0 Cu(1) 296 0 0 0.2096(4)
1.0 Cu(2) 296 0 0 0.0617(4)
0.86(2) Ba 296 0.5 0.5 0.1355(5)
0.96(1) Y 296 0.5 0.5 0
0.91(2) O(1) 296 0 0.5 0.2201(7)
1.0 O(2) 296 0.5 0 0.0524(5)
0.97(2) O(3) 296 0 0.5 0.0554(6)
0.99(2) O(4) 296 0 0 0.1429(4)
Measurement Method: Neutron diffraction
"The neutron powder diffraction pattern was recorded at room temperature at the Dhruva reactor at Trombay using neutrons of wave length 1.216 σ... The sample was in the form of a cylindrical pellet (12 mm diam., 14 mm height). The pattern was analysed by the Rietveld profile refinement method..."

Cautions: Evaluated Data
Critical Temperature for Y:124; [Y-Ba-Cu-O]
Critical Temperature (K)
78.5
Measurement Method: Dc four-probe method
"Electrical resistivity measurements were made using a DC four-probe method." No additional measurement details were noted.

Cautions: Unevaluated Data
Magnetic Susceptibility for Y:124; [Y-Ba-Cu-O]
Temperature (K) Magnetic Susceptibility (arbitrary)
5 -0.0167
11 -0.0164
20 -0.0160
30 -0.0150
45 -0.0128
55 -0.0107
65 -0.0072
75 -0.0023
80 -0.0002
90 0
Measurement Method: SQUID magnetometer
"DC magnetic susceptibility measurements were made using a SQUID magnetometer... in an applied field of (10 mT = 100 G)." No additional measurement details were noted.

Cautions: Evaluated Data
Digitized data were obtained from Figure 3 of the paper.