Bibliographic Information

Title: Iodometric Determination of Oxygen Contents of the Tl Single Layer System and their Relevance to Superconductivity
Author(s): S. Nakajima, M. Kikuchi, Y. Syono, T. Oku, K. Nagase, N. Kobayashi, D. Shindo, and K. Hiraga
Publication: Physica C Volume: 182 Issue: Not Available Year: 1991 Page(s): 89-94
Editor(s): Not Available
Publisher: Elsevier Science Publishers B.V.
Language: English
Notes: Not Available
Keywords: Material Specification, Critical Temperature

Materials and Properties

TlBa:1212; [Tl-Ba-Ca(Y)-Cu-O]
Material Specification for TlBa:1212; [Tl-Ba-Ca(Y)-Cu-O] Process: Solid State Reaction
Notes: The authors cite S. Nakajima, et al., Physica C Vol. 168 (1990) 57, and summarize the procedure as follows. "The mixtures of Tl2O3, BaO2, CaO, Y2O3 and CuO were wrapped with gold foil and fired at 880-900 °C for 60-90 min in a flowing oxygen gas of 120 ml/min. The reaction products were slowly cooled in furnace in an oxygen atmosphere and then annealed in oxygen at 400 °C for 20-30 h."
Formula: TlBa2Ca1-xYxCu2Oy
Informal Name: TlBa:1212
Chemical Family: Tl-Ba-Ca(Y)-Cu-O
Chemical Class: Oxide
Structure Type: Polycrystalline
Manufacturer: In House
Commercial Name: In House
Production Date:
Lot Number:
Production Form:

Critical Temperature for TlBa:1212; [Tl-Ba-Ca(Y)-Cu-O]
x of Yx (formula units) Critical Temperature (K)
0.0 80
0.1 87
0.2 95
0.35 100
0.4 96
0.5 0
0.8 0
1.0 0
Measurement Method: Dc susceptibility
"Tc was determined from the temperature dependence of resistivity and DC susceptibility. The resistivity was measured by the conventional four-probe method with a measuring current 1 mA. DC susceptibility was measured by a SQUID magnetometer in a field of (796 A/m = 10 Oe)." No additional measurement details were noted.

Cautions: Evaluated Data
Digitized data were obtained from Figure 2 of the paper.