NIST High Temp. Superconducting Materials (HTS) Database:

NIST Standard Reference Database 62

Last Update to Data Content: 1996

DOI: https://doi.org/10.18434/T4KP8J


Bibliographic Information

Title: Superconducting Properties of Tl1-yPbyCaSr2Cu2O7: Role of Pb and Oxygen Stoichiometry
Author(s): R. Vijayaraghavan and C.N.R. Rao
Publication: Solid State Communications Volume: 83 Issue: 1 Year: 1992 Page(s): 73-76
Editor(s): Not Available
Publisher: Pergamon Press Ltd
Language: English
Notes: Not Available
Keywords: Material Specification, Crystallography, Critical Temperature

Materials and Properties

Tl:1212; [Tl(Pb)-Sr-Ca-Cu-O]
Material Specification for Tl:1212; [Tl(Pb)-Sr-Ca-Cu-O] Process: Solid State Reaction
Notes: "Various compositions of... were prepared by starting with a precursor matrix of all the component oxides other than Tl2O3 and PbO2. The Ca-Sr-Cu-O precursor was obtained by heating the mixture of oxides and carbonates at 1200 K for 24 h. Appropriate amounts of Tl2O3 and PbO2 were mixed with the required quantity of the matrix and the mixture, in the form of a pellet, was heated at 1170 K for 3 h in a sealed silver tube."
Formula: Tl1-xPbxSr2CaCu2O7
Informal Name: Tl:1212
Chemical Family: Tl(Pb)-Sr-Ca-Cu-O
Chemical Class: Oxide
Structure Type:
Manufacturer: In House
Commercial Name: In House
Production Date:
Lot Number:
Production Form:

Crystallography for Tl:1212; [Tl(Pb)-Sr-Ca-Cu-O]
Crystal System: Tetragonal
Formula Units per Cell:
Space Group:
Cell Parameters
x of Pbx (formula units) Temp K a Å b Å c Å
0.30 296 3.794 -- 12.115
0.50 296 3.810 -- 12.160
0.60 296 3.814 -- 12.152
Measurement Method: X-ray diffraction
"... powder x-ray diffraction (data were) recorded with a JEOL - 8P diffractometer using Cu-Kα radiation." No additional measurement details were noted.

Cautions: Evaluated Data
Critical Temperature for Tl:1212; [Tl(Pb)-Sr-Ca-Cu-O]
x of Pbx (formula units) Tc(onset) (K) Critical Temperature (K)
0.30 40 22
0.50 91 78
0.60 85 70
Measurement Method: Four-probe method
"Four-probe D.C. resistivity of polycrystalline pellets was measured with a home-built apparatus." No additional measurement details were noted.

Cautions: Unevaluated Data