NIST High Temp. Superconducting Materials (HTS) Database:

NIST Standard Reference Database 62

Last Update to Data Content: 1996

DOI: https://doi.org/10.18434/T4KP8J


Bibliographic Information

Title: Oxygen Nonstoichiometry Effect on Structural Modulation in Bi-2212 Cuprate Superconductors
Author(s): F. Munakata, T. Kawano, H. Yamauchi, and Y. Inoue
Publication: Physica C Volume: 190 Issue: Not Available Year: 1992 Page(s): 471-476
Editor(s): Not Available
Publisher: Elsevier Science Publishers B.V.
Language: English
Notes: Not Available
Keywords: Material Specification, Crystallography

Materials and Properties


Material Specification for Bi:2212; [Bi-Sr-Ca(Y)-Cu-O] Process: Solid State Reaction
Notes: "... compounds were prepared by a conventional solid-state reaction method. Powders of Bi2O3, SrCO3, CaCO3, Y2O3, La2O3, and CuO were mixed and calcined at 1123 K for 10 h in air. The mixed powders were ground and pressed into parallelepiped bars of 3x3x10 mm3. The bar samples of the Bi2Sr2Ca1-xYxCu2O8+y compound were sintered under two different conditions... the Bi2Sr1.5La0.5CaCu2O8+y... was sintered at 1133 K in air and cooled in room temperature at a rate of 200 K/h. All the samples were found to be single phase."
Formula: Bi2Sr2Ca1-xYxCu2O8+y
Informal Name: Bi:2212
Chemical Family: Bi-Sr-Ca(Y)-Cu-O
Chemical Class: Oxide
Structure Type: Polycrystalline
Manufacturer: In House
Commercial Name: In House
Production Date:
Lot Number:
Production Form:

Crystallography for Bi:2212; [Bi-Sr-Ca(Y)-Cu-O]
Crystal System:
Formula Units per Cell:
Space Group:
Cell Parameters
Sintering gas/ temperature (K) x of Yx (no unit) Temp K a Å b Å c Å
air/1183 0.0 296 5.400 -- 30.781
air/1183 0.2 296 5.404 -- 30.637
air/1183 0.4 296 5.406 -- 30.451
air/1183 0.5 296 5.414 5.434 30.368
air/1183 0.6 296 5.415 5.440 30.285
air/1183 0.8 296 5.420 5.446 30.151
air/1183 1.0 296 5.423 5.464 30.153
Ar/1093 0.5 296 5.412 5.421 30.378
Ar/1093 0.6 296 5.415 5.431 30.285
Ar/1093 0.8 296 5.419 5.435 30.151
Ar/1093 1.0 296 5.422 5.443 30.153
Measurement Method: X-ray diffraction
"The lattice parameters were determined by X-ray powder diffraction (XRD) using CuKα." No additional measurement details were noted.

Cautions: Evaluated Data
Digitized data were obtained from Figure 1 of the paper.