NIST High Temp. Superconducting Materials (HTS) Database:

NIST Standard Reference Database 62

Last Update to Data Content: 1996

DOI: https://doi.org/10.18434/T4KP8J


Bibliographic Information

Title: Neutron Diffraction and Hall Effect Measurements on Y-Ba-Cu(Mn)-O System
Author(s): N.L. Saini, K.B. Garg, H. Rajagopal, and A. Sequeira
Publication: Solid State Communications Volume: 82 Issue: 11 Year: 1992 Page(s): 895-899
Editor(s): Not Available
Publisher: Pergamon Press Ltd
Language: English
Notes: Not Available
Keywords: Material Specification, Crystallography, Critical Temperature

Materials and Properties

Y:123; [Y-Ba-Cu(Mn)-O]<
Material Specification for Y:123; [Y-Ba-Cu(Mn)-O] Process: Solid State Reaction
Notes: "The samples... were prepared by usual solid state reaction method using high purity (>99.99%) oxides in stoichiometric proportions." No additional processing details were noted.
Formula: YBa2Cu3-xMnxOy
Informal Name: Y:123
Chemical Family: Y-Ba-Cu(Mn)-O
Chemical Class: Oxide
Structure Type: Polycrystalline
Manufacturer: In House
Commercial Name: In House
Production Date:
Lot Number:
Production Form:

Crystallography for Y:123; [Y-Ba-Cu(Mn)-O]
Crystal System: Orthorhombic
Formula Units per Cell:
Space Group: Pmmm
Cell Parameters
x of Mnx (formula units) Occupancy () Temp K a Å b Å c Å
0.00 -- 296 3.8297 3.8930 11.707
0.03 -- 296 3.8345 3.8986 11.711
0.15 -- 296 3.8376 3.8830 11.654
0.21 -- 296 3.8323 3.8767 11.638
0.30 -- 296 3.8303 3.8698 11.606
Atomic Coordinates
x of Mnx (formula units) Occupancy () Atom Temp K a-axis b-axis c-axis
0.15 0.957(8) Y 296 0.5 0.5 0.5
0.15 1.988(13) Ba 296 0.5 0.5 0.1865(5)
0.15 0.912(7) Cu(1) 296 0.0 0.0 0.0
0.15 2.005(9) Cu(2) 296 0.0 0.0 0.3584(5)
0.15 0.819(19) O(1) 296 0.0 0.5 0.0
0.15 2.008(13) O(2) 296 0.0 0.0 0.1604(6)
0.15 2.002(24) O(3) 296 0.5 0.0 0.3863(13)
0.15 2.004(26) O(4) 296 0.0 0.5 0.3735(12)
0.15 0.170(18) O(5) 296 0.5 0.0 0.0
Measurement Method: Neutron diffraction
"Neutron diffraction pattern was recorded at a wave length of 1.216 σ using the T-1011 diffractometer at the high flux DHRUVA reactor in Trombay. A cylindrical pellet (10 mm dia. and 18 mm high) of the compound was used for the measurements. The instrument collimations were 0.7°/0.5°/0.5° from the in-pile to the detector end. The refinement of the collected data was done by Rietveld technique using the program DBW9005."

Cautions: Evaluated Data
Critical Temperature for Y:123; [Y-Ba-Cu(Mn)-O]
x of Mnx (formula units) Critical Temperature (K)
0.00 91.0
0.03 86.8
0.15 75.0
0.21 72.0
0.30 67.0
Measurement Method: Tc methods
"The samples were characterized by resistivity (and) susceptibility... and it was found that Tc is decreasing with a rate of 2.4 K/% of Mn."

Cautions: Unevaluated Data
No measurement details were noted.