Material Specification for Tl:2212; [Tl-Ba-Ca-Cu-O]
Process: Solid State Reaction
Notes: "... single crystals were grown... Powders of BaO, Ca, CuO, and Tl2O3 mixed in appropriate ratio were prebaked at 650 °C for half an hour and then heated to 960 °C for thorough reaction. After slowly cooling to room temperature, crystals of generally...(0.2 x 0.2 x 0.04)mm3 in size were obtained."
Formula: Tl2Ba2CaCu2O8
Informal Name: Tl:2212
Chemical Family: Tl-Ba-Ca-Cu-O
Chemical Class: Oxide
Structure Type: Single Crystal
Manufacturer: In House
Commercial Name: In House
Production Date:
Lot Number:
Production Form:
Thermoelectric Power for Tl:2212; [Tl-Ba-Ca-Cu-O]
Direction () |
Temperature (K) |
Thermoelectric Power (µV/K) |
c-axis |
80 |
1.5 |
c-axis |
95 |
10.6 |
c-axis |
103 |
24.9 |
c-axis |
108 |
31.3 |
c-axis |
132 |
32.8 |
c-axis |
199 |
30.5 |
c-axis |
220 |
29.5 |
c-axis |
232 |
30.4 |
c-axis |
242 |
29.5 |
c-axis |
260 |
30.4 |
c-axis |
272 |
29.4 |
c-axis |
288 |
29.7 |
c-axis |
293 |
28.4 |
ab-plane |
82 |
0.0 |
ab-plane |
94 |
1.1 |
ab-plane |
101 |
8.1 |
ab-plane |
109 |
18.9 |
ab-plane |
114 |
21.7 |
ab-plane |
133 |
23.9 |
ab-plane |
147 |
23.6 |
ab-plane |
173 |
23.2 |
ab-plane |
224 |
19.6 |
ab-plane |
250 |
17.7 |
ab-plane |
285 |
15.7 |
ab-plane |
294 |
14.5 |
Measurement Method: Thermopower method
The authors cite L. Li et al., Europhys. Lett., Vol. 7, 555 (1988), and summarize the procedure as follows. "At very constant reference temperature a voltage difference was recorded in response to a sweeping temperature differential monitored by a constantan-copper thermocouple, which resulted in a satisfactory straight line (except at the superconducting transition) without thermal hysteresis. The slope, normalized to the sensitivity of the constantan-copper thermocouple, gives the thermopower of the sample after correcting the contribution of electric leads."
Cautions: Evaluated Data