NIST High Temp. Superconducting Materials (HTS) Database:

NIST Standard Reference Database 62

Last Update to Data Content: 1996

DOI: https://doi.org/10.18434/T4KP8J


Bibliographic Information

Title: Crystal Structure of DyBa2Cu4O8: A New 77 K Bulk Superconductor
Author(s): R.M. Hazen, L.W. Finger, and D.E. Morris
Publication: Applied Physics Letters Volume: 54 Issue: 11 Year: 1989 Page(s): 1057-1059
Editor(s): Not Available
Publisher: American Institute of Physics
Language: English
Notes: Not Available
Keywords: Material Specification, Crystallography

Materials and Properties

Dy:124; [Dy-Ba-Cu-O]
Material Specification for Dy:124; [Dy-Ba-Cu-O] Process: Solid State Reaction
Notes: "The... sample was prepared by grinding an oxide mix of 1-2-4 stoichiometry, pressing the powder into a pellet, and heating at 930 °C for 8 h at (10.3 MPa = 102 atm) oxygen pressure. After slow cooling for 8 h the pellet was reground, repressed, and the high-pressure heating and cooling treatment in oxygen was repeated... single crystal of size 0.01 x 0.05 x 0.05 mm3 was selected for diffraction studies..."
Formula: DyBa2Cu4O8
Informal Name: Dy:124
Chemical Family: Dy-Ba-Cu-O
Chemical Class: Oxide
Structure Type: Single Crystal
Manufacturer: In House
Commercial Name: In House
Production Date:
Lot Number:
Production Form:

Crystallography for Dy:124; [Dy-Ba-Cu-O]
Crystal System: Orthorhombic
Formula Units per Cell: 2
Space Group: Ammm
Cell Parameters
Temp K a Å b Å c Å
296 3.8463(3) 3.8726(3) 27.237(2)
Atomic Coordinates
Atom Temp K a-axis b-axis c-axis
Dy 296 0.5 0.5 0
Ba 296 0.5 0.5 0.13496(3)
Cu(1) 296 0 0 0.21312(5)
Cu(2) 296 0 0 0.06180(6)
O(1) 296 0 0 0.1458(3)
O(2) 296 0.5 0 0.0526(3)
O(3) 296 0 0.5 0.0532(3)
O(4) 296 0 0.5 0.2186(3)
Measurement Method: X-ray diffraction
"... a Rigaku four-circle diffractometer equipped with rotating-anode generator (was used). Unit-cell parameters were calculated from the measured positions of 20 reflections corrected for crystal centering errors... A complete sphere of diffracted intensities was measured with MoK α radiation to a maximum 2 θ of 60°."

Cautions: Evaluated Data