NIST High Temp. Superconducting Materials (HTS) Database:

NIST Standard Reference Database 62

Last Update to Data Content: 1996

DOI: https://doi.org/10.18434/T4KP8J


Bibliographic Information

Title: Pressure Dependence of the Superconducting Transition Temperature of Compounds Bi2-yPbySr2Ca1-xYxCu2O8+δ
Author(s): A. Struk and K. Westerholt
Publication: Physica C Volume: 200 Issue: Not Available Year: 1992 Page(s): 215-219
Editor(s): Not Available
Publisher: Elsevier Science Publishers B.V.
Language: English
Notes: Not Available
Keywords: Material Specification, Crystallography, Critical Temperature

Materials and Properties

Bi:2212; [Bi(Pb)-Sr-Ca(Y)-Cu-O]
Material Specification for Bi:2212; [Bi(Pb)-Sr-Ca(Y)-Cu-O] Process: Solid State Reaction
Notes: "Polycrystalline samples... were prepared by mixing stoichiometric portions of the oxides and annealing at 800 °C for 3 days in air with several intermediate grindings. As a final step the samples were homogenized in pure oxygen atmosphere for 7 days at 820 °C."
Formula: Bi2-xPbxSr2Ca1-yYyCu2O8.2
Informal Name: Bi:2212
Chemical Family: Bi(Pb)-Sr-Ca(Y)-Cu-O
Chemical Class: Oxide
Structure Type:
Manufacturer: In House
Commercial Name: In House
Production Date:
Lot Number:
Production Form:

Crystallography for Bi:2212; [Bi(Pb)-Sr-Ca(Y)-Cu-O]
Crystal System: Orthorhombic
Formula Units per Cell:
Space Group:
Cell Parameters
x of Pbx (formula units) y of Yy (formula units) Temp K a Å b Å c Å
0 0 296 5.40 5.45 31.1
0 0.1 296 5.41 5.44 30.7
0 0.2 296 5.40 5.45 31.0
0.1 0 296 5.39 5.44 31.0
Measurement Method: X-ray diffraction

Cautions: Unevaluated Data
No measurement details were noted.
Critical Temperature for Bi:2212; [Bi(Pb)-Sr-Ca(Y)-Cu-O]
x of Pbx (formula units) y of Yy (formula units) Pressure (GPa) Critical Temperature (K)
0 0.0 0.00 85.1
0 0.0 0.22 85.9
0 0.0 0.55 86.3
0 0.0 0.90 86.8
0 0.1 0.00 88.9
0 0.1 0.02 89.0
0 0.1 0.20 89.4
0 0.1 0.35 89.3
0 0.1 0.60 89.6
0 0.1 0.73 89.7
0 0.2 0.10 88.0
0 0.2 0.20 87.9
0 0.2 0.34 88.1
0 0.2 0.44 88.1
0 0.2 0.56 88.6
0 0.2 0.85 88.7
0.1 0 0.00 73.9
0.1 0 0.25 74.0
0.1 0 0.35 74.1
0.1 0 0.55 74.7
0.1 0 0.70 75.0
0.1 0 0.95 75.6
Measurement Method: SQUID magnetometer
The authors cite R. Kubiak et al., Physica C, Vol. 166, 523 (1990), and summarize the procedure as follows. "The magnetic susceptibility under hydrostatic pressure was measured by a noncommercial SQUID-magnetometer. The quasihydrostatic pressure was generated in a miniature Cu(Be)-pressure clamp with the sample immersed in a teflon capsule filled with a mixture of isoamyl alcohol and isopentane. The pressure was determined at low temperatures by measuring the shift of the superconducting transition temperature of a minute Pb-sample inside the pressure cell."

Cautions: Evaluated Data
Digitized data were obtained from Figure 3 of the paper.