NIST High Temp. Superconducting Materials (HTS) Database:

NIST Standard Reference Database 62

Last Update to Data Content: 1996

DOI: https://doi.org/10.18434/T4KP8J


Bibliographic Information

Title: Critical Current Density and Mechanical Strength of YBa2Cu3O7-δ Superconducting Composites Containing Zr, Ag and Y2BaCuO5 Dispersions by Melt-Processing
Author(s): T. Oka, Y. Itoh, Y. Yanagi, H. Tanaka, S. Takashima, Y. Yamada, and U. Mizutani
Publication: Physica C Volume: 200 Issue: Not Available Year: 1992 Page(s): 55-64
Editor(s): Not Available
Publisher: Elsevier Science Publishers B.V.
Language: English
Notes: Not Available
Keywords: Material Specification, Critical Current Density, Flexural Strength

Materials and Properties

Y:123; [Y-Ba-Cu-O]
Y:123; [Y-Ba(Zr)-Cu-O]
Y:123; [Y-Ba-Cu-O:Ag]
Y:123; [Y-Ba-Cu-O]
Y:123; [Y-Ba-Cu-O:Ag]
Material Specification for Y:123; [Y-Ba-Cu-O] Process: Melt Processed
Notes: "YBCO superconductors with and without Zr were prepared from an appropriate mixture of high-purity Y2O3, BaCO3, CuO and ZrO2 powders, which was uniaxially pressed into a pellet and calcined at 930 °C for 12 h in oxygen atmosphere. The composition was adjusted in the following two series: Zrx-YBa2Cu3O7-δ (type A) and ZrxYBa2+xCu3O7-δ (type B), where 0 ≤ x ≤ 0.8. The calcination was repeated three times... Ag metal powders (2 µm in diameter) were also mixed with the calcined YBCO powders and pressed into a pellet 20 mm in diameter and about 10 mm thick. The pellet thus obtained was heated to 1040 °C at a heating rate of 100 °C/h, and was held for 2 h. It was cooled to 1000 °C and then slowly cooled down to 940 °C at a rate of 1 °C/h, with subsequent furnace cooling to room temperature. The post annealing was added at 400-600 °C for 20-60 h for oxygen uptake. All heat treatments were performed in oxygen flowing atmosphere at an ambient pressure. The heat-treated sample was cut into a rectangular form using a slow speed diamond saw."
Formula: YBa2Cu3O7-y•Zrx
Informal Name: Y:123
Chemical Family: Y-Ba-Cu-O
Chemical Class: Oxide
Structure Type: Polycrystalline
Manufacturer: In House
Commercial Name: In House
Production Date:
Lot Number:
Production Form:

Critical Current Density for Y:123; [Y-Ba-Cu-O]
Amount of Y211 (mol%) Mass Fraction of Ag (%) x of Zrx (formula units) Critical Current Density (kA/cm2)
-- -- 0 13.5
-- -- 0.03 16.0
-- -- 0.06 11.0
-- -- 0.1 8.8
-- -- 0.2 5.1
-- -- 0.3 3.8
-- -- 0.5 2.3
-- -- 0.8 1.5
Measurement Method: Vibrating sample magnetometer
"Magnetization curves were measured with a vibrating sample magnetometer... at 77 K using a magnetic field up to 1 T and a sweep rate of 0.1 T/min for the sample with a size of approximately 3 x 3 x 0.6 mm3... the direction of a sample with regard to the magnetic field was chosen such that the larget hysteresis was observed in the M-H curve... The Bean critical state model may be applied to the evaluation (of the critical current)."

Cautions: Evaluated Data
Flexural Strength for Y:123; [Y-Ba-Cu-O]
Amount of Y211 (mol%) Mass Fraction of Ag (%) x of Zrx (formula units) Flexural Strength (MPa)
-- -- 0 27.8
-- -- 0.6 6.7
-- -- 0.1 9.5
-- -- 0.2 6.7
-- -- 0.3 14.9
-- -- 0.5 23.7
-- -- 0.8 54.8
Measurement Method: Three-point bend
The authors cite "Testing Method for Flexural Strength of High Performance Ceramics: Japanese Industrial Standards," R1601 (1981), and summarize the procedure as follows. "The mechanical strength was evaluated by measuring the flexural strength... in the 3-point bending mode at room temperature with a span length of 14.7 mm and a cross-head speed of 0.5 mm/min. The size of the samples was 3.5 x 1 x 20 mm3. A surface of the sample was polished in order to reduce cracks on the surface."

Cautions: Evaluated Data
Material Specification for Y:123; [Y-Ba(Zr)-Cu-O] Process: Melt Processed
Notes: "YBCO superconductors with and without Zr were prepared from an appropriate mixture of high-purity Y2O3, BaCO3, CuO and ZrO2 powders, which was uniaxially pressed into a pellet and calcined at 930 °C for 12 h in oxygen atmosphere. The composition was adjusted in the following two series: Zrx-YBa2Cu3O7-δ (type A) and ZrxYBa2+xCu3O7-δ (type B), where 0 ≤ x ≤ 0.8. The calcination was repeated three times... Ag metal powders (2 µm in diameter) were also mixed with the calcined YBCO powders and pressed into a pellet 20 mm in diameter and about 10 mm thick. The pellet thus obtained was heated to 1040 °C at a heating rate of 100 °C/h, and was held for 2 h. It was cooled to 1000 °C and then slowly cooled down to 940 °C at a rate of 1 °C/h, with subsequent furnace cooling to room temperature. The post annealing was added at 400-600 °C for 20-60 h for oxygen uptake. All heat treatments were performed in oxygen flowing atmosphere at an ambient pressure. The heat-treated sample was cut into a rectangular form using a slow speed diamond saw."
Formula: YBa2-xZrxCu3O7-y
Informal Name: Y:123
Chemical Family: Y-Ba(Zr)-Cu-O
Chemical Class: Oxide
Structure Type: Polycrystalline
Manufacturer: In House
Commercial Name: In House
Production Date:
Lot Number:
Production Form:

Critical Current Density for Y:123; [Y-Ba(Zr)-Cu-O]
Amount of Y211 (mol%) Mass Fraction of Ag (%) x of Zrx (formula units) Critical Current Density (kA/cm2)
-- -- 0 14.0
-- -- 0.03 14.0
-- -- 0.1 16.3
-- -- 0.2 10.5
-- -- 0.3 7.7
-- -- 0.5 6.6
-- -- 0.8 3.5
Measurement Method: Vibrating sample magnetometer
"Magnetization curves were measured with a vibrating sample magnetometer... at 77 K using a magnetic field up to 1 T and a sweep rate of 0.1 T/min for the sample with a size of approximately 3 x 3 x 0.6 mm3... the direction of a sample with regard to the magnetic field was chosen such that the larget hysteresis was observed in the M-H curve... The Bean critical state model may be applied to the evaluation (of the critical current)."

Cautions: Evaluated Data
Material Specification for Y:123; [Y-Ba-Cu-O:Ag] Process: Melt Processed
Notes: "YBCO superconductors with and without Zr were prepared from an appropriate mixture of high-purity Y2O3, BaCO3, CuO and ZrO2 powders, which was uniaxially pressed into a pellet and calcined at 930 °C for 12 h in oxygen atmosphere. The composition was adjusted in the following two series: Zrx-YBa2Cu3O7-δ (type A) and ZrxYBa2+xCu3O7-δ (type B), where 0 ≤ x ≤ 0.8. The calcination was repeated three times... Ag metal powders (2 µm in diameter) were also mixed with the calcined YBCO powders and pressed into a pellet 20 mm in diameter and about 10 mm thick. The pellet thus obtained was heated to 1040 °C at a heating rate of 100 °C/h, and was held for 2 h. It was cooled to 1000 °C and then slowly cooled down to 940 °C at a rate of 1 °C/h, with subsequent furnace cooling to room temperature. The post annealing was added at 400-600 °C for 20-60 h for oxygen uptake. All heat treatments were performed in oxygen flowing atmosphere at an ambient pressure. The heat-treated sample was cut into a rectangular form using a slow speed diamond saw."
Formula: YBa2Cu3O7-y•pAg
Informal Name: Y:123
Chemical Family: Y-Ba-Cu-O:Ag
Chemical Class: Oxide
Structure Type: Polycrystalline
Manufacturer: In House
Commercial Name: In House
Production Date:
Lot Number:
Production Form:

Critical Current Density for Y:123; [Y-Ba-Cu-O:Ag]
Amount of Y211 (mol%) Mass Fraction of Ag (%) x of Zrx (formula units) Critical Current Density (kA/cm2)
-- 0 -- 13.1
-- 10 -- 18.8
-- 15 -- 16.0
-- 20 -- 15.2
-- 25 -- 8.3
Measurement Method: Vibrating sample magnetometer
"Magnetization curves were measured with a vibrating sample magnetometer... at 77 K using a magnetic field up to 1 T and a sweep rate of 0.1 T/min for the sample with a size of approximately 3 x 3 x 0.6 mm3... the direction of a sample with regard to the magnetic field was chosen such that the larget hysteresis was observed in the M-H curve... The Bean critical state model may be applied to the evaluation (of the critical current)."

Cautions: Evaluated Data
Flexural Strength for Y:123; [Y-Ba-Cu-O:Ag]
Amount of Y211 (mol%) Mass Fraction of Ag (%) x of Zrx (formula units) Flexural Strength (MPa)
-- 10 -- 32.0
-- 15 -- 33.0
-- 20 -- 36.3
-- 25 -- 36.5
Measurement Method: Three-point bend
The authors cite "Testing Method for Flexural Strength of High Performance Ceramics: Japanese Industrial Standards," R1601 (1981), and summarize the procedure as follows. "The mechanical strength was evaluated by measuring the flexural strength... in the 3-point bending mode at room temperature with a span length of 14.7 mm and a cross-head speed of 0.5 mm/min. The size of the samples was 3.5 x 1 x 20 mm3. A surface of the sample was polished in order to reduce cracks on the surface."

Cautions: Evaluated Data
Material Specification for Y:123; [Y-Ba-Cu-O] Process: Melt Processed
Notes: "YBCO superconductors with and without Zr were prepared from an appropriate mixture of high-purity Y2O3, BaCO3, CuO and ZrO2 powders, which was uniaxially pressed into a pellet and calcined at 930 °C for 12 h in oxygen atmosphere. The composition was adjusted in the following two series: Zrx-YBa2Cu3O7-δ (type A) and ZrxYBa2+xCu3O7-δ (type B), where 0 ≤ x ≤ 0.8. The calcination was repeated three times... Ag metal powders (2 µm in diameter) were also mixed with the calcined YBCO powders and pressed into a pellet 20 mm in diameter and about 10 mm thick. The pellet thus obtained was heated to 1040 °C at a heating rate of 100 °C/h, and was held for 2 h. It was cooled to 1000 °C and then slowly cooled down to 940 °C at a rate of 1 °C/h, with subsequent furnace cooling to room temperature. The post annealing was added at 400-600 °C for 20-60 h for oxygen uptake. All heat treatments were performed in oxygen flowing atmosphere at an ambient pressure. The heat-treated sample was cut into a rectangular form using a slow speed diamond saw."
Formula: YBa2Cu3O7-y•qY2BaCuOz
Informal Name: Y:123
Chemical Family: Y-Ba-Cu-O
Chemical Class: Oxide
Structure Type: Polycrystalline
Manufacturer: In House
Commercial Name: In House
Production Date:
Lot Number:
Production Form:

Critical Current Density for Y:123; [Y-Ba-Cu-O]
Amount of Y211 (mol%) Mass Fraction of Ag (%) x of Zrx (formula units) Critical Current Density (kA/cm2)
9 -- -- 24.0
14.2 -- -- 28.7
25 -- -- 33.0
40 -- -- 50.1
50 -- -- 64.8
60 -- -- 46.3
67 -- -- 41.1
Measurement Method: Vibrating sample magnetometer
"Magnetization curves were measured with a vibrating sample magnetometer... at 77 K using a magnetic field up to 1 T and a sweep rate of 0.1 T/min for the sample with a size of approximately 3 x 3 x 0.6 mm3... the direction of a sample with regard to the magnetic field was chosen such that the larget hysteresis was observed in the M-H curve... The Bean critical state model may be applied to the evaluation (of the critical current)."

Cautions: Evaluated Data
Material Specification for Y:123; [Y-Ba-Cu-O:Ag] Process: Melt Processed
Notes: "YBCO superconductors with and without Zr were prepared from an appropriate mixture of high-purity Y2O3, BaCO3, CuO and ZrO2 powders, which was uniaxially pressed into a pellet and calcined at 930 °C for 12 h in oxygen atmosphere. The composition was adjusted in the following two series: Zrx-YBa2Cu3O7-δ (type A) and ZrxYBa2+xCu3O7-δ (type B), where 0 ≤ x ≤ 0.8. The calcination was repeated three times... Ag metal powders (2 µm in diameter) were also mixed with the calcined YBCO powders and pressed into a pellet 20 mm in diameter and about 10 mm thick. The pellet thus obtained was heated to 1040 °C at a heating rate of 100 °C/h, and was held for 2 h. It was cooled to 1000 °C and then slowly cooled down to 940 °C at a rate of 1 °C/h, with subsequent furnace cooling to room temperature. The post annealing was added at 400-600 °C for 20-60 h for oxygen uptake. All heat treatments were performed in oxygen flowing atmosphere at an ambient pressure. The heat-treated sample was cut into a rectangular form using a slow speed diamond saw."
Formula: YBa2Cu3O7-y•pAg•qY2BaCuO2
Informal Name: Y:123
Chemical Family: Y-Ba-Cu-O:Ag
Chemical Class: Oxide
Structure Type: Polycrystalline
Manufacturer: In House
Commercial Name: In House
Production Date:
Lot Number:
Production Form:

Critical Current Density for Y:123; [Y-Ba-Cu-O:Ag]
Amount of Y211 (mol%) Mass Fraction of Ag (%) x of Zrx (formula units) Critical Current Density (kA/cm2)
16.7 10 -- 44.7
20 10 -- 23.9
25 10 -- 44.7
Measurement Method: Vibrating sample magnetometer
"Magnetization curves were measured with a vibrating sample magnetometer... at 77 K using a magnetic field up to 1 T and a sweep rate of 0.1 T/min for the sample with a size of approximately 3 x 3 x 0.6 mm3... the direction of a sample with regard to the magnetic field was chosen such that the larget hysteresis was observed in the M-H curve... The Bean critical state model may be applied to the evaluation (of the critical current)."

Cautions: Evaluated Data
Flexural Strength for Y:123; [Y-Ba-Cu-O:Ag]
Amount of Y211 (mol%) Mass Fraction of Ag (%) x of Zrx (formula units) Flexural Strength (MPa)
16.7 10 -- 36.0
20 10 -- 39.7
25 10 -- 21.8
Measurement Method: Three-point bend
The authors cite "Testing Method for Flexural Strength of High Performance Ceramics: Japanese Industrial Standards," R1601 (1981), and summarize the procedure as follows. "The mechanical strength was evaluated by measuring the flexural strength... in the 3-point bending mode at room temperature with a span length of 14.7 mm and a cross-head speed of 0.5 mm/min. The size of the samples was 3.5 x 1 x 20 mm3. A surface of the sample was polished in order to reduce cracks on the surface."

Cautions: Evaluated Data