NIST High Temp. Superconducting Materials (HTS) Database:

NIST Standard Reference Database 62

Last Update to Data Content: 1996

DOI: https://doi.org/10.18434/T4KP8J


Bibliographic Information

Title: Crystal Structure of the High-Temperature Superconductor Tl2Ba2CaCu2O8
Author(s): M.A. Subramanian, J.C. Calabrese, C.C. Torardi, J. Gopalakrishnan, T.R. Askew, R.B. Flippen, et al.
Publication: Nature Volume: 332 Issue: Not Available Year: 1988 Page(s): 420-422
Editor(s): Not Available
Publisher: Macmillan Magazines Ltd.
Language: English
Notes: et al. = K.J. Morrissey, U. Chowdhry, and A.W. Sleight
Keywords: Material Specification, Density (mass), Crystallography

Materials and Properties

<
Tl:2212; [Tl-Ba-Ca-Cu-O]
Material Specification for Tl:2212; [Tl-Ba-Ca-Cu-O] Process: Solid State Reaction
Notes: "Single crystals of the 2122 superconducting phase were grown from a copper-rich melt with oxides in the molar ration 2:1:1:3 (Tl:Ba:Ca:Cu) in a sealed gold tube. The mixture was heated to 900-920 °C, held for 1 h and cooled at 2°C/min. Plate-like crystals found in the melt were mechanically separated..."
Formula: Tl2Ba2CaCu2O8
Informal Name: Tl:2212
Chemical Family: Tl-Ba-Ca-Cu-O
Chemical Class: Oxide
Structure Type: Single Crystal
Manufacturer: In House
Commercial Name: In House
Production Date:
Lot Number:
Production Form:

Density (mass) for Tl:2212; [Tl-Ba-Ca-Cu-O]
Density (g cm-3)
7.46
Measurement Method: X-ray diffraction
"... we present X-ray diffraction data for a single-crystal." Crystal dimensions: 0.07 x 0.05 x 0.01 mm Diffractomer: CAD4 Radiation: MoKα Monochromater: graphite 2θ range: 0° - 60°

Cautions: Evaluated Data
Crystallography for Tl:2212; [Tl-Ba-Ca-Cu-O]
Crystal System: Tetragonal
Formula Units per Cell:
Space Group: I4/mmm
Cell Parameters
Temp K a Å b Å c Å
296 3.8550(6) -- 29.318(4)
Atomic Coordinates
Atom Temp K a-axis b-axis c-axis
Tl(1) 296 0.50 0.50 0.21359(2)
Ba(1) 296 0.00 0.00 0.12179(3)
Cu(1) 296 0.50 0.50 0.0540(1)
Ca(1) 296 0.00 0.00 0.00
O(1) 296 0.00 0.50 0.0531(2)
O(2) 296 0.50 0.50 0.1461(3)
O(3) 296 0.604(9) 0.50 0.2815(7)
Measurement Method: X-ray diffraction
"... we present X-ray diffraction data for a single-crystal." Crystal dimensions: 0.07 x 0.05 x 0.01 mm Diffractomer: CAD4 Radiation: MoKα Monochromater: graphite 2θ range: 0° - 60°

Cautions: Evaluated Data