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NIST High Temp. Superconducting Materials (HTS) Database:

NIST Standard Reference Database 62

Last Update to Data Content: 1996

DOI: https://doi.org/10.18434/T4KP8J

Bibliographic Information

Title: Substitution of 3d Metals for Cu in (Bi,Pb)2Sr2Ca2Cu3Oy
Author(s): R.K. Nkum, A. Punnet, and W.R. Datars
Publication: Physica C Volume: 202 Issue: Not Available Year: 1992 Page(s): 371-378
Editor(s): Not Available
Publisher: Elsevier Science Publishers B.V.
Language: English
Notes: Not Available
Keywords: Material Specification, Crystallography, Critical Temperature, Resistivity (normal state), Magnetic Susceptibility

Materials and Properties

Bi:2223; [Bi(Pb)-Sr-Ca-Cu(Mn)-O]
Bi:2223; [Bi(Pb)-Sr-Ca-Cu(Zn)-O]
Bi:2223; [Bi(Pb)-Sr-Ca-Cu(Fe)-O]
Material Specification for Bi:2223; [Bi(Pb)-Sr-Ca-Cu(Mn)-O] Process: Solid State Reaction
Notes: "Samples... were prepared using the conventional solid state reaction method. Chemically pure powders of Bi2O3, PbO, SrCO3, CaCO3, CuO, MnO2, Fe2O3 and ZnO were used as starting materials. The powders were mixed in the appropriate amounts in acetone in an agate mortar and calcined in air at 820 °C for 5 h. The resulting materials were ground, pressed into pellets and sintered at 850 °C for 100 h with several intermediate grindings and pressings. The pellets were cooled at 0.2 °C/min to 700 °C, 0.1 °C to 200 °C and then cooled to room temperature with the furnace turned off. All samples were heat treated in alumina boats."
Formula: Bi1.6Pb0.4Sr2Ca2Cu3-xMnxOy
Informal Name: Bi:2223
Chemical Family: Bi(Pb)-Sr-Ca-Cu(Mn)-O
Chemical Class: Oxide
Structure Type: Polycrystalline
Manufacturer: In House
Commercial Name: In House
Production Date:
Lot Number:
Production Form:

Crystallography for Bi:2223; [Bi(Pb)-Sr-Ca-Cu(Mn)-O]
Cell Parameters
Crystal System: Tetragonal
Formula Units per Cell:
Space Group:
Cell Parameters
x (formula units) Temp K a Å b Å c Å
0 296 5.41 -- 37.12
0.01 296 5.40 -- 37.00
0.05 296 5.39 -- 36.81
0.20 296 5.41 -- 37.04
0.30 296 5.40 -- 36.98
0.40 296 5.41 -- 36.94
0.50 296 5.40 -- 36.80
Measurement Method: X-ray diffraction
"Phase identification of the samples was carried out by recording X-ray diffraction patterns in the 2θ range of 10° to 70° at room temperature with a Nicolet powder diffractometer using CuKα radiation." No additional measurement details were noted.

Cautions: Evaluated Data
Critical Temperature for Bi:2223; [Bi(Pb)-Sr-Ca-Cu(Mn)-O]
x (formula units) Tc(onset) (K) Critical Temperature (K)
0 110.1 99.7
0.05 109.7 95.9
0.20 108.4 95.0
0.30 106.8 88.4
0.40 106.8 65.9
0.50 106.8 63.0
Measurement Method: Four-probe method
"The electrical resistivity of the samples was measured ... by the standard four-probe technique. The 50 K temperature was obtained by pumping on liquid nitrogen. A constant current of 1 mA was used for all the samples. The temperature was monitored with carbon glass and platinum resistance thermometers." No additional measurement details were noted.

Cautions: Evaluated Data
Resistivity (normal state) for Bi:2223; [Bi(Pb)-Sr-Ca-Cu(Mn)-O]
x (formula units) Temperature (K) Resistivity (normal state) (mΩ·cm)
0.5 64 0.0
0.5 83 1.6
0.5 98 2.9
0.5 112 5.9
0.5 149 6.9
0.5 252 8.7
0.5 279 9.1
0.4 71 0.0
0.4 96 1.0
0.4 107 2.6
0.4 150 3.4
0.4 250 4.6
0.4 270 4.8
0.3 91 0.0
0.3 98 0.8
0.3 108 1.8
0.3 151 2.4
0.3 251 3.4
0.3 276 3.7
0.2 97 0.0
0.2 107 1.0
0.2 116 1.3
0.2 150 1.7
0.2 250 2.6
0.2 277 2.8
0.05 99 0.0
0.05 107 1.0
0.05 149 1.4
0.05 250 2.1
0.05 278 2.3
0 101 0.0
0 109 0.8
0 149 1.2
0 277 1.9
Measurement Method: Four-probe method
"The electrical resistivity of the samples was measured ... by the standard four-probe technique. The 50 K temperature was obtained by pumping on liquid nitrogen. A constant current of 1 mA was used for all the samples. The temperature was monitored with carbon glass and platinum resistance thermometers." No additional measurement details were noted.

Cautions: Evaluated Data
Digitized data were obtained from Figure 3 of the paper.
Magnetic Susceptibility for Bi:2223; [Bi(Pb)-Sr-Ca-Cu(Mn)-O]
x (formula units) Temperature (K) Magnetic Susceptibility (arbitrary)
0 45 -0.7
0 62 -0.7
0 82 -0.5
0 101 -0.2
0 105 0.0
0 140 0.0
0.05 40 -0.8
0.05 60 -0.7
0.05 72 -0.5
0.05 81 -0.4
0.05 96 -0.3
0.05 103 0.0
0.05 140 0.0
Measurement Method: Dc susceptibility
"DC susceptibility measurements were made with a superconducting quantum interference device magnetometer in an applied magnetic field of (2 mT = 20 G)." No additional measurement details were noted.

Cautions: Evaluated Data
Digitized data were obtained from Figure 2a and 2b of the paper.
Material Specification for Bi:2223; [Bi(Pb)-Sr-Ca-Cu(Zn)-O] Process: Solid State Reaction
Notes: "Samples... were prepared using the conventional solid state reaction method. Chemically pure powders of Bi2O3, PbO, SrCO3, CaCO3, CuO, MnO2, Fe2O3 and ZnO were used as starting materials. The powders were mixed in the appropriate amounts in acetone in an agate mortar and calcined in air at 820 °C for 5 h. The resulting materials were ground, pressed into pellets and sintered at 850 °C for 100 h with several intermediate grindings and pressings. The pellets were cooled at 0.2 °C/min to 700 °C, 0.1 °C to 200 °C and then cooled to room temperature with the furnace turned off. All samples were heat treated in alumina boats."
Formula: Bi1.6Pb0.4Sr2Ca2Cu3-xZnxOy
Informal Name: Bi:2223
Chemical Family: Bi(Pb)-Sr-Ca-Cu(Zn)-O
Chemical Class: Oxide
Structure Type: Polycrystalline
Manufacturer: In House
Commercial Name: In House
Production Date:
Lot Number:
Production Form:

Crystallography for Bi:2223; [Bi(Pb)-Sr-Ca-Cu(Zn)-O]
Crystal System: Tetragonal
Formula Units per Cell:
Space Group:
Cell Parameters
x (formula units) Temp K a Å b Å c Å
0.01 296 5.40 -- 37.03
0.05 296 5.42 -- 37.09
0.20 296 5.42 -- 37.16
0.40 296 5.38 -- 37.09
Measurement Method: X-ray diffraction
"Phase identification of the samples was carried out by recording X-ray diffraction patterns in the 2θ range of 10° to 70° at room temperature with a Nicolet powder diffractometer using CuKα radiation." No additional measurement details were noted.

Cautions: Evaluated Data
Critical Temperature for Bi:2223; [Bi(Pb)-Sr-Ca-Cu(Zn)-O]
x (formula units) Tc(onset) (K) Critical Temperature (K)
0.01 101.1 95.9
0.05 107.7 86.5
0.07 107.1 79.0
0.10 105.2 78.1
0.20 106.0 78.0
0.40 108.1,81.8 63.8
0.50 74.3 55.0
Measurement Method: Four-probe method
"The electrical resistivity of the samples was measured ... by the standard four-probe technique. The 50 K temperature was obtained by pumping on liquid nitrogen. A constant current of 1 mA was used for all the samples. The temperature was monitored with carbon glass and platinum resistance thermometers." No additional measurement details were noted.

Cautions: Evaluated Data
Resistivity (normal state) for Bi:2223; [Bi(Pb)-Sr-Ca-Cu(Zn)-O]
x (formula units) Temperature (K) Resistivity (normal state) (mΩ·cm)
0.4 64 0.0
0.4 72 2.1
0.4 83 3.1
0.4 105 3.7
0.4 112 4.5
0.4 151 5.3
0.4 199 6.2
0.4 247 7.1
0.4 269 7.5
0.07 79 0.0
0.07 99 1.1
0.07 109 2.0
0.07 151 2.6
0.07 199 3.1
0.07 247 3.4
0.07 269 3.5
0.05 88 0.0
0.05 99 0.6
0.05 105 1.5
0.05 116 1.9
0.05 151 2.4
0.05 201 2.9
0.05 247 3.3
0.05 269 3.5
0.0 96 0.0
0.0 105 0.4
0.0 109 0.7
0.0 151 1.2
0.0 201 1.5
0.0 250 1.9
0.0 280 2.1
0.01 96 0.0
0.01 107 0.7
0.01 123 0.9
0.01 151 1.1
0.01 199 1.4
0.01 247 1.7
0.01 272 1.9
0.5 55 0.0
0.5 64 2.1
0.5 66 10.5
0.5 67 20.4
0.5 67 30.6
0.5 72 40.4
0.5 79 45.2
0.5 98 41.5
0.5 148 33.0
0.5 198 27.9
0.5 249 24.9
0.5 275 24.5
Measurement Method: Four-probe method
"The electrical resistivity of the samples was measured ... by the standard four-probe technique. The 50 K temperature was obtained by pumping on liquid nitrogen. A constant current of 1 mA was used for all the samples. The temperature was monitored with carbon glass and platinum resistance thermometers." No additional measurement details were noted.

Cautions: Evaluated Data
Digitized data were obtained from Figure 4 of the paper.
Material Specification for Bi:2223; [Bi(Pb)-Sr-Ca-Cu(Fe)-O] Process: Solid State Reaction
Notes: "Samples... were prepared using the conventional solid state reaction method. Chemically pure powders of Bi2O3, PbO, SrCO3, CaCO3, CuO, MnO2, Fe2O3 and ZnO were used as starting materials. The powders were mixed in the appropriate amounts in acetone in an agate mortar and calcined in air at 820 °C for 5 h. The resulting materials were ground, pressed into pellets and sintered at 850 °C for 100 h with several intermediate grindings and pressings. The pellets were cooled at 0.2 °C/min to 700 °C, 0.1 °C to 200 °C and then cooled to room temperature with the furnace turned off. All samples were heat treated in alumina boats."
Formula: Bi1.6Pb0.4Sr2Ca2Cu3-xFexOy
Informal Name: Bi:2223
Chemical Family: Bi(Pb)-Sr-Ca-Cu(Fe)-O
Chemical Class: Oxide
Structure Type: Polycrystalline
Manufacturer: In House
Commercial Name: In House
Production Date:
Lot Number:
Production Form:

Crystallography for Bi:2223; [Bi(Pb)-Sr-Ca-Cu(Fe)-O]
Crystal System: Tetragonal
Formula Units per Cell:
Space Group:
Cell Parameters
x (formula units) Temp K a Å b Å c Å
0.01 296 5.40 -- 37.00
0.05 296 5.39 -- 37.14
0.07 296 5.39 -- 37.08
0.10 296 5.38 -- 36.89
Measurement Method: X-ray diffraction
"Phase identification of the samples was carried out by recording X-ray diffraction patterns in the 2θ range of 10° to 70° at room temperature with a Nicolet powder diffractometer using CuKα radiation." No additional measurement details were noted.

Cautions: Evaluated Data
Critical Temperature for Bi:2223; [Bi(Pb)-Sr-Ca-Cu(Fe)-O]
x (formula units) Tc(onset) (K) Critical Temperature (K)
0.01 109.7 96.8
0.05 101.9 85.6
0.07 98.8 79.9
Measurement Method: Four-probe method
"The electrical resistivity of the samples was measured ... by the standard four-probe technique. The 50 K temperature was obtained by pumping on liquid nitrogen. A constant current of 1 mA was used for all the samples. The temperature was monitored with carbon glass and platinum resistance thermometers." No additional measurement details were noted.

Cautions: Evaluated Data
Resistivity (normal state) for Bi:2223; [Bi(Pb)-Sr-Ca-Cu(Fe)-O]
x (formula units) Temperature (K) Resistivity (normal state) (mΩ·cm)
0.10 63 2.3
0.10 91 2.3
0.10 100 2.7
0.10 102 2.7
0.10 150 2.9
0.10 201 3.2
0.10 249 3.4
0.10 269 3.5
0.07 79 0.0
0.07 86 0.4
0.07 97 1.3
0.07 101 1.5
0.07 150 2.2
0.07 201 2.7
0.07 251 2.9
0.07 269 3.1
0.05 87 0.0
0.05 94 0.6
0.05 101 1.3
0.05 121 1.6
0.05 150 2.0
0.05 203 2.4
0.05 249 2.7
0.05 275 2.9
0.01 98 0.0
0.01 103 0.4
0.01 108 1.0
0.01 112 1.3
0.01 150 1.8
0.01 200 2.2
0.01 251 2.6
0.01 275 2.8
0 101 0.0
0 105 0.4
0 108 0.7
0 112 0.9
0 149 1.3
0 202 1.6
0 251 1.9
0 281 2.1
Measurement Method: Four-probe method
"The electrical resistivity of the samples was measured ... by the standard four-probe technique. The 50 K temperature was obtained by pumping on liquid nitrogen. A constant current of 1 mA was used for all the samples. The temperature was monitored with carbon glass and platinum resistance thermometers." No additional measurement details were noted.

Cautions: Evaluated Data
Digitized data were obtained from Figure 5 of the paper.
Magnetic Susceptibility for Bi:2223; [Bi(Pb)-Sr-Ca-Cu(Fe)-O]
x (formula units) Temperature (K) Magnetic Susceptibility (arbitrary)
0.05 40 -0.7
0.05 53 -0.5
0.05 60 -0.4
0.05 69 -0.3
0.05 82 -0.2
0.05 92 -0.1
0.05 96 0.0
0.05 140 0.0
Measurement Method: Dc susceptibility
"DC susceptibility measurements were made with a superconducting quantum interference device magnetometer in an applied magnetic field of (2 mT = 20 G)." No additional measurement details were noted.

Cautions: Evaluated Data
Digitized data were obtained from Figure 2c of the paper.