NIST High Temp. Superconducting Materials (HTS) Database:

NIST Standard Reference Database 62

Last Update to Data Content: 1996

DOI: https://doi.org/10.18434/T4KP8J


Bibliographic Information

Title: Substitution Effects of Yttrium in the BISCCO (2212) System
Author(s): E. L. Narsaiah, U.V.S. Rao, O. Pena, and M. Sergent
Publication: Materials Chemistry and Physics Volume: 33 Issue: Not Available Year: 1993 Page(s): 58-62
Editor(s): Not Available
Publisher: Elsevier Sequoia
Language: English
Notes: Not Available
Keywords: Material Specification, Crystallography, Critical Temperature, Magnetic Susceptibility

Materials and Properties

Bi:2212; [Bi-Sr-Ca(Y)-Cu-O]
Material Specification for Bi:2212; [Bi-Sr-Ca(Y)-Cu-O] Process: Solid State Reaction
Notes: "Samples... were prepared by the solid state reaction method. A mixture containing stoichiometric amounts of Ca and Sr carbonates and Bi, Cu, Y oxides were calcinated at 800 °C for 24 h. The resulting material was pelletized and sintered for 48 h and then quenched to LN2 temperature. The final sintering temperature varied from 860 °C (x=0.1) to 900 °C (x=1.0)."
Formula: Bi2Sr2Ca1-xYxCu2O8+y
Informal Name: Bi:2212
Chemical Family: Bi-Sr-Ca(Y)-Cu-O
Chemical Class: Oxide
Structure Type: Polycrystalline
Manufacturer: In House
Commercial Name: In House
Production Date:
Lot Number:
Production Form:

Crystallography for Bi:2212; [Bi-Sr-Ca(Y)-Cu-O]
Crystal System: Tetragonal
Formula Units per Cell:
Space Group:
Cell Parameters
x of Yx (formula units) Temp K a Å b Å c Å
0.1 296 5.41 -- 30.80
0.2 296 5.41 -- 30.72
0.3 296 5.42 -- 30.55
0.5 296 5.42 -- 30.40
1.0 296 5.43 5.45 30.23
Measurement Method: X-ray diffraction
"... an INEL CPS 120 X-ray (CuKα) diffractometer (was used)." No additional measurement details were noted.

Cautions: Evaluated Data
Critical Temperature for Bi:2212; [Bi-Sr-Ca(Y)-Cu-O]
x of Yx (formula units) Critical Temperature (K)
0.1 93.5
0.3 81
Measurement Method: SQUID magnetometer
"DC Magnetization measurements were performed with a SHE-VTS SQUID Susceptometer model 906 (in a magnetic field of 1.59 kA/m)." No additional measurement details were noted.

Cautions: Evaluated Data
Magnetic Susceptibility for Bi:2212; [Bi-Sr-Ca(Y)-Cu-O]
x of Yx (formula units) Temperature (K) Magnetic Susceptibility (arbitrary)
0.1 24 -0.0060
0.1 30 -0.0060
0.1 40 -0.0060
0.1 50 -0.0060
0.1 60 -0.0059
0.1 70 -0.0054
0.1 80 -0.0042
0.1 90 -0.0013
0.1 95 0.000
0.1 100 0.000
0.2 30 -0.0059
0.2 40 -0.0056
0.2 50 -0.0048
0.2 60 -0.0039
0.2 70 -0.0026
0.2 81 -0.0012
0.2 90 0.000
0.2 93 0.000
0.2 100 0.000
0.3 20 -0.0059
0.3 30 -0.0052
0.3 40 -0.0043
0.3 50 -0.0029
0.3 60 -0.0015
0.3 70 -0.0005
0.3 80 0.000
0.3 90 0.000
0.3 100 0.000
Measurement Method: SQUID magnetometer
"DC Magnetization measurements were performed with a SHE-VTS SQUID Susceptometer model 906 (in a magnetic field of 1.59 kA/m)." No additional measurement details were noted.

Cautions: Evaluated Data
Digitized data were obtained from Figure 4 of the paper.