NIST High Temp. Superconducting Materials (HTS) Database:

NIST Standard Reference Database 62

Last Update to Data Content: 1996

DOI: https://doi.org/10.18434/T4KP8J


Bibliographic Information

Title: Electrochemical Synthesis and Characterization of Superconducting Ba1-xKxBiO3 Single Crystals
Author(s): J. Marcus, C. Escribe-Filippini, S.K. Agarwal, C. Chaillout, J. Durr, T. Fournier, and J.L. Tholence
Publication: Solid State Communications Volume: 78 Issue: 11 Year: 1991 Page(s): 967-969
Editor(s): Not Available
Publisher: Pergamon Press Ltd
Language: English
Notes: Not Available
Keywords: Material Specification, Crystallography, Critical Temperature

Materials and Properties

Ba:11; [Ba(K)-Bi-O]
Material Specification for Ba:11; [Ba(K)-Bi-O] Process: Melt Processed
Notes: "Single crystal (samples) were obtained by electrolytic oxidation of a molten mixture of KOH, Ba(OH)28H2O and Bi2O3 in the molar ratio 70:1:1. We used a platinum crucible as well as platinum electrodes. The bath was maintained in air at 210 °C. We found that 5mA as current gives single crystals which keep the cubic shape and with plane crystallographic faces... All the examined samples were grown in air and no annealing was made."
Formula: Ba1-xKxBiO3
Informal Name: Ba:11
Chemical Family: Ba(K)-Bi-O
Chemical Class: Oxide
Structure Type: Single Crystal
Manufacturer: In House
Commercial Name: In House
Production Date:
Lot Number:
Production Form:

Crystallography for Ba:11; [Ba(K)-Bi-O]
Crystal System: Cubic
Formula Units per Cell:
Space Group:
Cell Parameters
x of Kx (formula units) Temp K a Å b Å c Å
0.38 296 4.2832(5) -- --
0.43 296 4.2788(3) -- --
0.46 296 4.2775(4) -- --
0.48 296 4.2772(6) -- --
0.50 296 4.2661(19) -- --
Measurement Method: X-ray diffraction
"By X-Ray diffraction (Gandolfi camera, FeKα radiation) we were able to determine the lattice parameters on single crystals..." No additional measurement details were noted.

Cautions: Evaluated Data
Critical Temperature for Ba:11; [Ba(K)-Bi-O]
x of Kx (formula units) Critical Temperature (K)
0.38 21.5
0.43 21.2
0.46 19.0
0.48 18.7
0.50 16.5
Measurement Method: Ac susceptibility

Cautions: Unevaluated Data
No measurement details were noted.