Material Specification for Bi:2223; [Bi(Pb)-Sr-Ca-Cu-O:Ag]
Process: Solid State Reaction
Notes: "The compound... was prepared by the solid state ceramic technique. Appropriate quantities of Bi2O3, PbO, SrCO3, CaCO3 and CuO, all of 4 N purity, were thoroughly mixed, ground and calcined in air at 835 °C for 24 h. The calcination was carried out twice. The calcined powder was ground and five bar-shaped (45 x 4 x 3 mm3) specimens were prepared by using this pure calcined powder as well as after mixing it with varying amounts of AgNO3 corresponding to a silver concentration of 5, 10, 20 and 50% by weight. All the specimens were finally sintered at 840 °C for 48 h and furnace cooled to room temperature."
Formula: Bi1.6Pb0.4Sr1.6Ca2Cu3O10+x·yAg
Informal Name: Bi:2223
Chemical Family: Bi(Pb)-Sr-Ca-Cu-O:Ag
Chemical Class: Oxide
Structure Type: Polycrystalline
Manufacturer: In House
Commercial Name: In House
Production Date:
Lot Number:
Production Form:
Critical Temperature for Bi:2223; [Bi(Pb)-Sr-Ca-Cu-O:Ag]
| Mass Fraction of Ag (%) |
Tc(onset) (K) |
Critical Temperature (K) |
| 0 |
110 |
102 |
| 5 |
110 |
93 |
| 10 |
110 |
88 |
| 20 |
110 |
81 |
| 50 |
110 |
76 |
Measurement Method: Four-probe method
"Electrical resistance of the specimens was measured as a function of temperature by the four-probe method." No additional measurement details were noted.
Cautions: Evaluated Data
Thermoelectric Power for Bi:2223; [Bi(Pb)-Sr-Ca-Cu-O:Ag]
| Mass Fraction of Ag (%) |
Temperature (K) |
Thermoelectric Power (µV/K) |
| 0 |
95 |
0.0 |
| 0 |
101 |
0.0 |
| 0 |
104 |
2.1 |
| 0 |
106 |
6.5 |
| 0 |
111 |
9.5 |
| 0 |
123 |
10.8 |
| 0 |
127 |
11.0 |
| 0 |
145 |
9.5 |
| 0 |
173 |
7.6 |
| 0 |
211 |
5.1 |
| 0 |
220 |
3.8 |
| 0 |
226 |
3.4 |
| 0 |
232 |
3.1 |
| 0 |
238 |
2.9 |
| 0 |
264 |
1.3 |
| 0 |
281 |
0.8 |
| 0 |
299 |
0.2 |
| 5 |
105 |
0.2 |
| 5 |
110 |
3.9 |
| 5 |
118 |
8.3 |
| 5 |
123 |
9.2 |
| 5 |
128 |
9.5 |
| 5 |
143 |
9.0 |
| 5 |
171 |
7.2 |
| 5 |
229 |
3.1 |
| 5 |
268 |
0.8 |
| 5 |
299 |
-1.6 |
| 10 |
104 |
0.2 |
| 10 |
106 |
5.6 |
| 10 |
114 |
7.4 |
| 10 |
126 |
8.1 |
| 10 |
148 |
6.7 |
| 10 |
183 |
4.7 |
| 10 |
215 |
3.3 |
| 10 |
237 |
2.4 |
| 10 |
259 |
1.8 |
| 10 |
299 |
1.1 |
| 20 |
107 |
0.2 |
| 20 |
112 |
3.0 |
| 20 |
112 |
4.5 |
| 20 |
119 |
5.6 |
| 20 |
155 |
4.0 |
| 20 |
204 |
2.7 |
| 20 |
240 |
1.5 |
| 20 |
268 |
0.4 |
| 20 |
298 |
-0.8 |
| 20 |
300 |
-0.8 |
| 50 |
105 |
0.2 |
| 50 |
111 |
2.7 |
| 50 |
115 |
4.5 |
| 50 |
145 |
3.4 |
| 50 |
183 |
1.4 |
| 50 |
219 |
-0.3 |
| 50 |
259 |
-2.1 |
| 50 |
295 |
-3.9 |
Measurement Method: Thermopower method
"Thermoelectric power... was measured using differential technique in the temperature range of 80 to 300 K." No additional measurement details were noted.
Cautions: Evaluated Data
Digitized data were obtained from Figure 4 of the paper.
