Material Specification for PbSr:2213; [Pb-Sr-Y(Ca)-Cu-O]
Process: Flux Growth
Notes: The authors cite C. Changkang et al., J. Cryst. Growth, Vol. 118, 101 (1992), and summarize the procedure as follows. "... crystals were grown by spontaneous nucleation from a PbO-NaCl flux in air. No chemical precursor was used. The starting materials, SrCO3, Y2O3, CaCO3, CuO and PbO in the molar ratio 2:025:0.5:3:3 were thoroughly milled, placed in a platinum crucible and covered by NaCl. The crucible was heated up to 1005 °C at 300 °C/h, held at this temperature for 10 h and then cooled to 900 °C at 10 °C/h and to 760 °C at 0.5 °C/h. The resulting crystals were separated mechanically and washed in methanol. The crystals used for the present measurements were about 1 x 1 x 0.5 mm3."
Formula: Pb2Sr2Y0.82Ca0.18Cu3O8+x
Informal Name: PbSr:2213
Chemical Family: Pb-Sr-Y(Ca)-Cu-O
Chemical Class: Oxide
Structure Type: Single Crystal
Manufacturer: In House
Commercial Name: In House
Production Date:
Lot Number:
Production Form:
Critical Temperature for PbSr:2213; [Pb-Sr-Y(Ca)-Cu-O]
Critical Temperature (K) |
35 |
Measurement Method: Vibrating sample magnetometer
"DC magnetisation measurements to identify the irreversibility temperature were carried out in field-cooled (FC) and in zero-field-cooled (ZFC) mode by a vibrating sample magnetometer... in a field of (5 mT = 50 G)... The temperature at which... the two curves (FC and ZFC) diverged (is defined as the irreversibility temperature)..."
Cautions: Evaluated Data
Magnetic Susceptibility for PbSr:2213; [Pb-Sr-Y(Ca)-Cu-O]
Cooling Method () |
Temperature (K) |
Magnetic Susceptibility (arbitrary) |
FC |
10 |
-0.04 |
FC |
20 |
-0.04 |
FC |
30 |
-0.03 |
FC |
40 |
0.00 |
FC |
50 |
0.00 |
ZFC |
10 |
-0.82 |
ZFC |
20 |
-0.76 |
ZFC |
27 |
-0.48 |
ZFC |
30 |
-0.20 |
ZFC |
33 |
-0.04 |
ZFC |
40 |
0.0 |
ZFC |
50 |
0.0 |
Measurement Method: Vibrating sample magnetometer
"DC magnetisation measurements to identify the irreversibility temperature were carried out in field-cooled (FC) and in zero-field-cooled (ZFC) mode by a vibrating sample magnetometer... in a field of (5 mT = 50 G)... The temperature at which... the two curves (FC and ZFC) diverged (is defined as the irreversibility temperature)..."
Cautions: Evaluated Data
Digitized data were obtained from Figure 1 of the paper.
Irreversibility Field for PbSr:2213; [Pb-Sr-Y(Ca)-Cu-O]
Temperature (K) |
Irreversibility Field (T) |
32 |
0.005 |
Measurement Method: Vibrating sample magnetometer
"DC magnetisation measurements to identify the irreversibility temperature were carried out in field-cooled (FC) and in zero-field-cooled (ZFC) mode by a vibrating sample magnetometer... in a field of (5 mT = 50 G)... The temperature at which... the two curves (FC and ZFC) diverged (is defined as the irreversibility temperature)..."
Cautions: Evaluated Data