NIST High Temp. Superconducting Materials (HTS) Database:

NIST Standard Reference Database 62

Last Update to Data Content: 1996

DOI: https://doi.org/10.18434/T4KP8J


Bibliographic Information

Title: Effects of Cu Substitution by Fe on the Magnetic Properties of YBa2Cu3O7-y Single Crystals
Author(s): M.D. Lan, J.Z. Liu, and R.N. Shelton
Publication: Physical Review B Volume: 43 Issue: 16 Year: 1991 Page(s): 12989-12993
Editor(s): Not Available
Publisher: American Physical Society
Language: English
Notes: Not Available
Keywords: Material Specification, Critical Temperature, Critical Field Strength Hc1

Materials and Properties

Y:123; [Y-Ba-Cu(Fe)-O]
Material Specification for Y:123; [Y-Ba-Cu(Fe)-O] Process: Flux Growth
Notes: The authors cite J.Z. Liu et al., Phys. Lett., Vol. 121, 305 (1987), and summarize the procedure as follows. "The high-quality single crystals used in our experiments were grown by a modified self-flux technique. Measurements were performed on a...single crystal with typical dimensions of 0.8 mm x 0.6 mm x 0.4 mm."
Formula: YBa2Cu3-xFexO7-y
Informal Name: Y:123
Chemical Family: Y-Ba-Cu(Fe)-O
Chemical Class: Oxide
Structure Type: Single Crystal
Manufacturer: In House
Commercial Name: In House
Production Date:
Lot Number:
Production Form:

Critical Temperature for Y:123; [Y-Ba-Cu(Fe)-O]
x of Fex (formula units) Tc (onset) (K) ΔTc (10%-90%) (K) Critical Temperature (K)
0 92.7 2.6 89.6
0.06 87.2 8.4 75.7
0.12 86.1 14.6 68.2
0.24 70.0 22.2 35.5
Measurement Method: SQUID magnetometer
"The low-field dc magnetization was measured using a commercial superconducting quantum interference device (SQUID) magnetometer between 6 and 120 K. A small single crystal with the typical mass of 0.1 mg was fixed in place by GE 7031 varnish inside a capsule. In order to have the flux lines parallel to twin boundaries, the specimen was prepared so that the applied magnetic field was perpendicular to the Cu-O plane... The lower critical field is determined by using a least-squares method to fit the magnetization data in the region around zero field to the expression M=-H /[4¦(1-D)], where M is the volume magnetization, H is the external applied field, and D is the demagnetization factor. The magnetic field at which the magnetization starts to deviate from the fitting is defined the lower critical field H ."

Cautions: Evaluated Data