Material Specification for Hg:1212; [Hg-Ba-Ca-Cu-O]
Process: Solid State Reaction
Notes: The authors cite A. Schilling et al., Nature (London), Vol. 363, 56 (1993), and summarize the procedure as follows. "After sintering, the resulting materials were usually annealed for several hours in flowing oxygen."
Formula: HgBa2CaCu2O6+x
Informal Name: Hg:1212
Chemical Family: Hg-Ba-Ca-Cu-O
Chemical Class: Oxide
Structure Type: Polycrystalline
Manufacturer: In House
Commercial Name: In House
Production Date:
Lot Number:
Production Form:
Crystallography for Hg:1212; [Hg-Ba-Ca-Cu-O]
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Crystal System: | Tetragonal |
Formula Units per Cell: | |
Space Group: |
P4/mmm
|
Cell Parameters
Temp
K
|
a
Å
|
b
Å
|
c
Å
|
296 |
3.85 |
-- |
12.75 |
Atomic Coordinates
Atom |
Temp
K
|
a-axis |
b-axis |
c-axis |
Hg |
296 |
0 |
0 |
0 |
Ba |
296 |
0.5 |
0.5 |
0.22 |
Ca |
296 |
0.5 |
0.5 |
0.5 |
Cu |
296 |
0 |
0 |
0.375 |
O(1) |
296 |
0 |
0.5 |
0.38 |
O(2) |
296 |
0 |
0 |
0.154 |
O(3) |
296 |
0.5 |
0.5 |
0 |
Measurement Method: X-ray diffraction
"... the samples were structurally characterised by X-ray diffraction (Guinier-technique)." No additional measurement details were noted.
Cautions: Unevaluated Data
Magnetic Susceptibility for Hg:1212; [Hg-Ba-Ca-Cu-O]
Temperature (K) |
Magnetic Susceptibility (arbitrary) |
110 |
-0.0022 |
113 |
-0.0016 |
114 |
-0.0014 |
115 |
-0.0011 |
116 |
-0.0011 |
119 |
-0.0007 |
123 |
-0.0001 |
125 |
0 |
130 |
0 |
Measurement Method: SQUID magnetometer
"The critical temperatures for superconductivity were determined by measurements of the magnetic susceptibility using a SQUID magnetometer..." No additional measurement details were noted.
Cautions: Evaluated Data
Digitized data were obtained from Figure 1 of the paper.