NIST High Temp. Superconducting Materials (HTS) Database:

NIST Standard Reference Database 62

Last Update to Data Content: 1996

DOI: https://doi.org/10.18434/T4KP8J


Bibliographic Information

Title: High-Temperature X-ray Diffraction of the PbBi-2223 Phase Superconductor in Different Atmospheres
Author(s): J. Niska, O. Babushki, and B. Loberg
Publication: Journal of Materials Science Letters Volume: 12 Issue: Not Available Year: 1993 Page(s): 1337-1339
Editor(s): Not Available
Publisher: Chapman and Hall
Language: English
Notes: Not Available
Keywords: Material Specification, Thermal Expansion

Materials and Properties

Bi:2223; [Bi(Pb)-Sr-Ca-Cu-O]
Material Specification for Bi:2223; [Bi(Pb)-Sr-Ca-Cu-O] Process: Solid State Reaction
Notes: "The 2223 phase was prepared from a percursor powder with a cation ratio of 1.6Bi:0.4OPb:2.0Ca:2.0Sr:3.0Cu using a long sintering time. The resultant powder containing primarily the 2223 high-Tc phase was mixed with silver powder... The silver powder was used as an internal standard."
Formula: Bi1.6Pb0.4Sr2Ca2Cu3Ox
Informal Name: Bi:2223
Chemical Family: Bi(Pb)-Sr-Ca-Cu-O
Chemical Class: Oxide
Structure Type: Polycrystalline
Manufacturer: In House
Commercial Name: In House
Production Date:
Lot Number:
Production Form:

Thermal Expansion for Bi:2223; [Bi(Pb)-Sr-Ca-Cu-O]
Axis () Atmosphere () Thermal Expansion (10-6 K-1)
a-axis Vacuum 16.0
a-axis Helium 10.5
a-axis Air 8.0
c-axis Vacuum 23.0
c-axis Helium 22.5
c-axis Air 11.5
Measurement Method: X-ray diffraction
"In this study the lattice expansion was measured using a modified Philips 1710 system high-temperature X-ray diffractometer and three different atmospheres: a vacuum, helium and air... The temperature was increased in steps and scans were made from 22° to 36° of 2θ to obtain the strongest peaks of the 2223 phase with at least 10 min between individual runs for temperature stabilization. The vacuum level was about 10 mPa and the helium was a standard commercial purity grade gas."

Cautions: Evaluated Data