NIST High Temp. Superconducting Materials (HTS) Database:

NIST Standard Reference Database 62

Last Update to Data Content: 1996

DOI: https://doi.org/10.18434/T4KP8J


Bibliographic Information

Title: Anisotropic Thermal Expansion and Gruneisen Coefficients of the bismuth cuprate 2-2-1-2
Author(s): M. Mouallem-Bahout, J. Gaude, G. Calvarin, J.R. Gavarri, and C. Carel
Publication: Materials Letters Volume: 18 Issue: Not Available Year: 1994 Page(s): 181-185
Editor(s): Not Available
Publisher: Elsevier Science B.V.
Language: English
Notes: Not Available
Keywords: Material Specification, Crystallography, Specific Heat, Thermal Expansion, Gruneisen Parameter

Materials and Properties

Bi:2212; [Bi-Sr-Ca-Cu-O]
Material Specification for Bi:2212; [Bi-Sr-Ca-Cu-O] Process:
Notes: The authors cite J. Gaude et al., Mater. Letters, Vol. 11, 317 (1991), and summarize the procedure as follows. "The sample has been obtained in the course of a study of an alternative route to the preparation of the superconducting 2-2-1-2 phase." No additional processing details were noted.
Formula: Bi2Sr2CaCu2O8
Informal Name: Bi:2212
Chemical Family: Bi-Sr-Ca-Cu-O
Chemical Class: Oxide
Structure Type: Polycrystalline
Manufacturer: In House
Commercial Name: In House
Production Date:
Lot Number:
Production Form:

Crystallography for Bi:2212; [Bi-Sr-Ca-Cu-O]
Crystal System:
Formula Units per Cell:
Space Group:
Cell Parameters
Temp K a Å b Å c Å
10.0 5.38991 -- 30.6067
15.1 5.39009 -- 30.6059
19.2 5.38988 -- 30.6068
24.7 5.38968 -- 30.6059
29.9 5.38969 -- 60.6054
34.7 5.38953 -- 30.6079
39.6 5.38966 -- 30.6075
44.4 5.38994 -- 30.6083
49.2 5.38965 -- 30.6079
54.6 5.38972 -- 30.6094
59.8 5.38976 -- 30.6104
59.9 5.38965 -- 30.6094
64.9 5.39100 -- 30.6187
69.9 5.39038 -- 30.6144
75.6 5.39046 -- 30.6157
79.7 5.39014 -- 30.6144
79.8 5.39020 -- 30.6150
85.6 5.39073 -- 30.6183
90.4 5.39081 -- 30.6194
95.5 5.39158 -- 30.6258
100.3 5.39083 -- 30.6262
109.9 5.39135 -- 30.6263
120.5 5.39173 -- 30.6338
120.9 5.39199 -- 30.6336
130.2 5.39219 -- 30.6329
139.8 5.39241 -- 30.6377
149.7 5.39239 -- 30.6409
159.7 5.39336 -- 30.6467
169.8 5.39379 -- 30.6500
179.9 5.39392 -- 30.6554
189.8 5.39457 -- 30.6611
199.8 5.39490 -- 30.6660
219.3 5.39611 -- 30.6757
Measurement Method: X-ray diffraction
The authors cite J.F. Berar et al., J. Appl. Cryst., Vol. 13, 201 (1980), and summarize the procedure as follows. "X-ray powder diffraction patterns have been recorded at fixed temperatures between 5 K and 220 K on a home-made high-accuracy diffractometer. The refinement of the cell parameters a and c has been done from ten angular positions. Despite the orthorhombic space space group Bmmm, parameters a and b could not be separated..."

Cautions: Evaluated Data
Specific Heat for Bi:2212; [Bi-Sr-Ca-Cu-O]
Temperature (K) Specific Heat (J kg-1 K-1)
10 0.09
20 6
30 20
40 42
50 71
70 135
80 165
90 193
100 218
120 260
140 292
160 316
180 335
200 350
220 361
Measurement Method: Debye model
"The anisotropic specific heats C and Cc are characteristic of various vibration modes. Such modes can be represented by the anisotropic Debye temperatures θ and θc. The classical Debye model has been used to calculate C (T/θ ) and Cc(T/θ/c)."

Cautions: Evaluated Data
The volumetric specific heat was calculated as C = (2C
+Cc)/3.