Material Specification for Bi:2212; [Bi-Sr-Ca-Cu-O]
Process:
Notes: The authors cite J. Gaude et al., Mater. Letters, Vol. 11, 317 (1991), and summarize the procedure as follows. "The sample has been obtained in the course of a study of an alternative route to the preparation of the superconducting 2-2-1-2 phase." No additional processing details were noted.
Formula: Bi2Sr2CaCu2O8
Informal Name: Bi:2212
Chemical Family: Bi-Sr-Ca-Cu-O
Chemical Class: Oxide
Structure Type: Polycrystalline
Manufacturer: In House
Commercial Name: In House
Production Date:
Lot Number:
Production Form:
Crystallography for Bi:2212; [Bi-Sr-Ca-Cu-O]
Crystal System: | |
Formula Units per Cell: | |
Space Group: |
|
Cell Parameters
Temp
K
|
a
Å
|
b
Å
|
c
Å
|
10.0 |
5.38991 |
-- |
30.6067 |
15.1 |
5.39009 |
-- |
30.6059 |
19.2 |
5.38988 |
-- |
30.6068 |
24.7 |
5.38968 |
-- |
30.6059 |
29.9 |
5.38969 |
-- |
60.6054 |
34.7 |
5.38953 |
-- |
30.6079 |
39.6 |
5.38966 |
-- |
30.6075 |
44.4 |
5.38994 |
-- |
30.6083 |
49.2 |
5.38965 |
-- |
30.6079 |
54.6 |
5.38972 |
-- |
30.6094 |
59.8 |
5.38976 |
-- |
30.6104 |
59.9 |
5.38965 |
-- |
30.6094 |
64.9 |
5.39100 |
-- |
30.6187 |
69.9 |
5.39038 |
-- |
30.6144 |
75.6 |
5.39046 |
-- |
30.6157 |
79.7 |
5.39014 |
-- |
30.6144 |
79.8 |
5.39020 |
-- |
30.6150 |
85.6 |
5.39073 |
-- |
30.6183 |
90.4 |
5.39081 |
-- |
30.6194 |
95.5 |
5.39158 |
-- |
30.6258 |
100.3 |
5.39083 |
-- |
30.6262 |
109.9 |
5.39135 |
-- |
30.6263 |
120.5 |
5.39173 |
-- |
30.6338 |
120.9 |
5.39199 |
-- |
30.6336 |
130.2 |
5.39219 |
-- |
30.6329 |
139.8 |
5.39241 |
-- |
30.6377 |
149.7 |
5.39239 |
-- |
30.6409 |
159.7 |
5.39336 |
-- |
30.6467 |
169.8 |
5.39379 |
-- |
30.6500 |
179.9 |
5.39392 |
-- |
30.6554 |
189.8 |
5.39457 |
-- |
30.6611 |
199.8 |
5.39490 |
-- |
30.6660 |
219.3 |
5.39611 |
-- |
30.6757 |
Measurement Method: X-ray diffraction
The authors cite J.F. Berar et al., J. Appl. Cryst., Vol. 13, 201 (1980), and summarize the procedure as follows. "X-ray powder diffraction patterns have been recorded at fixed temperatures between 5 K and 220 K on a home-made high-accuracy diffractometer. The refinement of the cell parameters a and c has been done from ten angular positions. Despite the orthorhombic space space group Bmmm, parameters a and b could not be separated..."
Cautions: Evaluated Data
Thermal Expansion for Bi:2212; [Bi-Sr-Ca-Cu-O]
Axis () |
Temperature (K) |
Thermal Expansion (10-6 K-1) |
a |
10 |
-0.009 |
a |
20 |
-0.073 |
a |
30 |
-0.218 |
a |
40 |
0.663 |
a |
50 |
1.784 |
a |
70 |
4.254 |
a |
80 |
5.682 |
a |
90 |
5.862 |
a |
100 |
6.172 |
a |
120 |
7.366 |
a |
140 |
7.864 |
a |
160 |
8.055 |
a |
180 |
8.387 |
a |
200 |
8.471 |
a |
220 |
8.367 |
c |
10 |
0.109 |
c |
20 |
0.868 |
c |
30 |
2.787 |
c |
40 |
4.657 |
c |
50 |
6.622 |
c |
70 |
9.587 |
c |
80 |
10.258 |
c |
90 |
11.774 |
c |
100 |
12.843 |
c |
120 |
13.703 |
c |
140 |
14.594 |
c |
160 |
15.374 |
c |
180 |
15.745 |
c |
200 |
16.180 |
c |
220 |
16.675 |
Measurement Method: X-ray diffraction
The authors cite J.F. Berar et al., J. Appl. Cryst., Vol. 13, 201 (1980), and summarize the procedure as follows. "X-ray powder diffraction patterns have been recorded at fixed temperatures between 5 K and 220 K on a home-made high-accuracy diffractometer. The refinement of the cell parameters a and c has been done from ten angular positions. Despite the orthorhombic space space group Bmmm, parameters a and b could not be separated..."
Cautions: Evaluated Data
Gruneisen Parameter for Bi:2212; [Bi-Sr-Ca-Cu-O]
Axis () |
Temperature (K) |
Gruneisen Parameter (no unit) |
a |
10 |
1.20 |
a |
20 |
1.20 |
a |
30 |
1.20 |
a |
40 |
2.50 |
a |
50 |
2.60 |
a |
70 |
2.25 |
a |
80 |
2.15 |
a |
90 |
1.85 |
a |
100 |
1.67 |
a |
120 |
1.53 |
a |
140 |
1.40 |
a |
160 |
1.30 |
a |
180 |
1.25 |
a |
200 |
1.20 |
a |
220 |
1.15 |
c |
10 |
0.85 |
c |
20 |
0.85 |
c |
30 |
0.85 |
c |
40 |
0.85 |
c |
50 |
0.85 |
c |
70 |
0.85 |
c |
80 |
0.85 |
c |
90 |
0.85 |
c |
100 |
0.85 |
c |
120 |
0.85 |
c |
140 |
0.85 |
c |
160 |
0.85 |
c |
180 |
0.85 |
c |
200 |
0.85 |
c |
220 |
0.85 |
Measurement Method: Gruneisen calculation
The authors cite J.R. Gavarri et al., Physica C, Vol. 172, 213 (1990), and summarize the procedure as follows. "The mean Gruneisen parameter is calculated by the usual relation:
γ = α
v·V/C
v·x,
where α
v is the volumic expansion coefficient, V the molar volume, C
v the heat content and x the isotropic compressibility factor. ... The anisotropic compressibility factors have been obtained from neutron and X-ray diffraction data at high pressure (0-10 kbar)."
Cautions: Evaluated Data