Material Specification for Tl:221; [Tl-Ba-Cu-O]
Process: Melt Processed
Notes: "This paper reports the crystal growth... in a liquid coexisting with solid. ... Nominal cations ratio of Tl:Ba:Ca:Cu in starting mixtures were 2:2:0:2 for Tl-2201 and 1.5:2:3:1.5 for Tl-2212. Each mixture of raw materials of Tl2O3(3N), BaO2(4N), CuO(4N) and CaO(3N) was sealed tightly in a gold capsule. It was heated in a vertical electric furnace in a flow of oxygen gas. After soaking at each prescribed temperature for several hours, it was cooled down to another prescribed temperature at a rate of 2 °C/h and then rapidly to the room temperature in the furnace. The conditions were in the coexisting region of liquid and solid. ... Platelet thick crystals of Tl-2201 are obtained in the typical size of about 0.8 mm x 0.8 mm x 50 µm. The maximum size is about 1.5 mm x 1.5 mm x 100 µm. Polyhedral thick crystals of Tl-2212 are obtained... The typical size is about 1 mm x 1 mm x 100 µm and the maximum size about 2 mm x 2 mm x 500 µm."
Formula: Tl1.7Ba2CuOx
Informal Name: Tl:221
Chemical Family: Tl-Ba-Cu-O
Chemical Class: Oxide
Structure Type: Single Crystal
Manufacturer: In House
Commercial Name: In House
Production Date:
Lot Number:
Production Form:
Critical Flux Density Hc2 for Tl:221; [Tl-Ba-Cu-O]
| Angle(c,H) (degrees) |
Temperature (K) |
Crit.Mag.Flux Density Hc2 (T) |
| 0 |
1.4 |
9.0 |
| 0 |
4.3 |
5.9 |
| 0 |
7.9 |
3.9 |
| 0 |
9.7 |
2.9 |
| 0 |
13.1 |
2.0 |
| 0 |
17.4 |
0.9 |
| 0 |
21.6 |
0.5 |
| 0 |
29.2 |
0.06 |
| 90 |
25.6 |
8.9 |
| 90 |
27.2 |
2.9 |
| 90 |
28.2 |
0.9 |
| 90 |
29.2 |
0.06 |
Measurement Method: Four-probe method
The authors cite Y. Iye et al., Physica C, Vol. 153-155, 26 (1988), and summarize the procedure as follows. "Temperature dependence of resistivity of several crystals was measured by a conventional dc four probe method between 1.5 K and 300 K in applied magnetic fields up to 9 T. The direction of the excitation current of 1 mA was in the ab-phane."
Cautions: Evaluated Data
Angle(c,H) is the angle between the c-axis and the direction of the applied magnetic field.
Resistivity (normal state) for Tl:221; [Tl-Ba-Cu-O]
| Angle(c,H) (degrees) |
Temperature (K) |
Magnetic Field (T) |
Resistivity (normal state) (mΩ·cm) |
| 0 |
25.0 |
0.0 |
0.031 |
| 0 |
25.0 |
1.0 |
0.030 |
| 0 |
25.0 |
2.0 |
0.031 |
| 0 |
25.0 |
3.0 |
0.031 |
| 0 |
25.0 |
4.0 |
0.031 |
| 0 |
25.0 |
5.9 |
0.031 |
| 0 |
25.0 |
7.0 |
0.032 |
| 0 |
25.0 |
7.9 |
0.032 |
| 0 |
25.0 |
9.0 |
0.032 |
| 0 |
22.7 |
0.0 |
0.026 |
| 0 |
22.7 |
0.2 |
0.029 |
| 0 |
22.7 |
1.0 |
0.029 |
| 0 |
22.7 |
2.0 |
0.029 |
| 0 |
22.7 |
3.0 |
0.030 |
| 0 |
22.7 |
4.0 |
0.030 |
| 0 |
22.7 |
5.0 |
0.030 |
| 0 |
22.7 |
5.9 |
0.030 |
| 0 |
22.7 |
7.0 |
0.030 |
| 0 |
22.7 |
7.9 |
0.030 |
| 0 |
22.7 |
9.0 |
0.031 |
| 0 |
16.8 |
0.0 |
0 |
| 0 |
16.8 |
0.3 |
0 |
| 0 |
16.8 |
0.5 |
0.009 |
| 0 |
16.8 |
0.7 |
0.016 |
| 0 |
16.8 |
0.8 |
0.023 |
| 0 |
16.8 |
1.0 |
0.025 |
| 0 |
16.8 |
1.9 |
0.026 |
| 0 |
16.8 |
3.0 |
0.026 |
| 0 |
16.8 |
3.9 |
0.027 |
| 0 |
16.8 |
5.0 |
0.027 |
| 0 |
16.8 |
5.9 |
0.027 |
| 0 |
16.8 |
7.0 |
0.027 |
| 0 |
16.8 |
7.9 |
0.028 |
| 0 |
16.8 |
9.0 |
0.028 |
| 0 |
9.70 |
0.0 |
0.000 |
| 0 |
9.70 |
1.0 |
0.000 |
| 0 |
9.70 |
1.3 |
0.000 |
| 0 |
9.70 |
1.6 |
0.007 |
| 0 |
9.70 |
2.0 |
0.018 |
| 0 |
9.70 |
2.5 |
0.022 |
| 0 |
9.70 |
3.1 |
0.023 |
| 0 |
9.70 |
4.0 |
0.024 |
| 0 |
9.70 |
5.0 |
0.024 |
| 0 |
9.70 |
5.9 |
0.025 |
| 0 |
9.70 |
7.0 |
0.025 |
| 0 |
9.70 |
7.9 |
0.025 |
| 0 |
9.70 |
9.0 |
0.025 |
| 0 |
1.56 |
0.0 |
0.000 |
| 0 |
1.56 |
1.0 |
0.000 |
| 0 |
1.56 |
2.0 |
0.000 |
| 0 |
1.56 |
3.0 |
0.000 |
| 0 |
1.56 |
3.7 |
0.000 |
| 0 |
1.56 |
4.0 |
0.001 |
| 0 |
1.56 |
4.6 |
0.010 |
| 0 |
1.56 |
5.0 |
0.016 |
| 0 |
1.56 |
6.0 |
0.021 |
| 0 |
1.56 |
7.0 |
0.022 |
| 0 |
1.56 |
7.9 |
0.023 |
| 0 |
1.56 |
9.0 |
0.023 |
Measurement Method: Four-probe method
The authors cite Y. Iye et al., Physica C, Vol. 153-155, 26 (1988), and summarize the procedure as follows. "Temperature dependence of resistivity of several crystals was measured by a conventional dc four probe method between 1.5 K and 300 K in applied magnetic fields up to 9 T. The direction of the excitation current of 1 mA was in the ab-phane."
Cautions: Evaluated Data
Angle(c,H) is the angle between the c-axis and the direction of the applied magnetic field.
Material Specification for Tl:2212; [Tl-Ba-Ca-Cu-O]
Process: Melt Processed
Notes: "This paper reports the crystal growth... in a liquid coexisting with solid. ... Nominal cations ratio of Tl:Ba:Ca:Cu in starting mixtures were 2:2:0:2 for Tl-2201 and 1.5:2:3:1.5 for Tl-2212. Each mixture of raw materials of Tl2O3(3N), BaO2(4N), CuO(4N) and CaO(3N) was sealed tightly in a gold capsule. It was heated in a vertical electric furnace in a flow of oxygen gas. After soaking at each prescribed temperature for several hours, it was cooled down to another prescribed temperature at a rate of 2 °C/h and then rapidly to the room temperature in the furnace. The conditions were in the coexisting region of liquid and solid. ... Platelet thick crystals of Tl-2201 are obtained in the typical size of about 0.8 mm x 0.8 mm x 50 µm. The maximum size is about 1.5 mm x 1.5 mm x 100 µm. Polyhedral thick crystals of Tl-2212 are obtained... The typical size is about 1 mm x 1 mm x 100 µm and the maximum size about 2 mm x 2 mm x 500 µm."
Formula: Tl1.8Ba2Ca0.85Cu2.2Ox
Informal Name: Tl:2212
Chemical Family: Tl-Ba-Ca-Cu-O
Chemical Class: Oxide
Structure Type: Single Crystal
Manufacturer: In House
Commercial Name: In House
Production Date:
Lot Number:
Production Form:
Critical Flux Density Hc2 for Tl:2212; [Tl-Ba-Ca-Cu-O]
| Angle(c,H) (degrees) |
Temperature (K) |
Crit.Mag.Flux Density Hc2 (T) |
| 0 |
66.4 |
9.0 |
| 0 |
73.5 |
5.9 |
| 0 |
81.2 |
4.0 |
| 0 |
84.7 |
2.8 |
| 0 |
90.6 |
1.9 |
| 0 |
95.7 |
1.0 |
| 0 |
98.3 |
0.4 |
| 0 |
101 |
0.1 |
| 0 |
105 |
0 |
| 90 |
98.9 |
8.9 |
| 90 |
101 |
5.9 |
| 90 |
101 |
3.9 |
| 90 |
102 |
2.9 |
| 90 |
103 |
1.9 |
| 90 |
104 |
0.9 |
| 90 |
105 |
0.4 |
| 90 |
105 |
0.1 |
| 90 |
105 |
0 |
Measurement Method: Four-probe method
The authors cite Y. Iye et al., Physica C, Vol. 153-155, 26 (1988), and summarize the procedure as follows. "Temperature dependence of resistivity of several crystals was measured by a conventional dc four probe method between 1.5 K and 300 K in applied magnetic fields up to 9 T. The direction of the excitation current of 1 mA was in the ab-phane."
Cautions: Evaluated Data
Angle(c,H) is the angle between the c-axis and the direction of the applied magnetic field.
