NIST High Temp. Superconducting Materials (HTS) Database:

NIST Standard Reference Database 62

Last Update to Data Content: 1996

DOI: https://doi.org/10.18434/T4KP8J


Bibliographic Information

Title: Neutron-Powder-Diffraction Study of the Nuclear and Magnetic Structures of the Antiferromagnetic Superconductor HoNi2B2C
Author(s): Q. Huang, A. Santoro, T.E. Grigereit, J.W. Lynn, R.J. Cava, J.J. Krajewski, and W.F. Peck, Jr.
Publication: Physical Review B Volume: 51 Issue: 6 Year: 1995 Page(s): 3701-3708
Editor(s): Not Available
Publisher: American Physical Society
Language: English
Notes: Not Available
Keywords: Material Specification, Crystallography

Materials and Properties

[Ho-Ni-B-C]
Material Specification for ; [Ho-Ni-B-C] Process: Melt Processed
Notes: The authors cite R.J. Cava et al., Nature, Vol. 367, 252 (1994), and summarize the procedure as follows. "The sample used in this study was prepared by arc-melting and subsequent annealing... using boron in the starting materials that was enriched to 98.5% with the isotope 11B to reduce nuclear absorption."
Formula: HoNi2B2C
Informal Name:
Chemical Family: Ho-Ni-B-C
Chemical Class: Carbide
Structure Type: Polycrystalline
Manufacturer: In House
Commercial Name: In House
Production Date:
Lot Number:
Production Form:

Crystallography for ; [Ho-Ni-B-C]
Crystal System: Tetragonal
Formula Units per Cell:
Space Group: I4/mmm
Cell Parameters
Temp K a Å b Å c Å
296 3.5170(1) -- 10.5217(3)
10 3.50866(4) -- 10.5274(2)
5.1 3.5087(1) -- 10.5272(5)
2.2 3.50834(4) -- 10.5272(3)
Atomic Coordinates
Atom Temp K a-axis b-axis c-axis
Ho -- 0 0 0
Ni -- 0.5 0 0.25
B 296 0 0 0.3589(1)
B 10 0 0 0.3592(2)
B 5.1 0 0 0.3586(2)
B 2.2 0 0 0.3588(2)
C -- 0.5 0.5 0
Measurement Method: Neutron diffraction
"The neutron-powder-diffraction measurements were made using the new high-resolution 32-counter diffractometer of the National Institute of Standards and Technology, with the experimental conditions listed..." Monochromatic beam: 311 reflection of Cu monochromator. Wavelength: 1.539(1) σ Sample container: V cans with 12 mm diameter for the 296 K, 10 K, and 2.2 K experiments, respectively. V annular can of 12 mm and 6 mm diameter for the 5.1 K experiment. 2θ angular range: 4° to 164° steps: 0.05°

Cautions: Evaluated Data