NIST High Temp. Superconducting Materials (HTS) Database:

NIST Standard Reference Database 62

Last Update to Data Content: 1996

DOI: https://doi.org/10.18434/T4KP8J


Bibliographic Information

Title: Oxygen Stoichiometry, Structure and Superconductivity in Bi2Sr2CaCu2O8+x
Author(s): P. Krishnaraj, M. Lelovic, N.G. Eror, and U. Balachandran
Publication: Physica C Volume: 246 Issue: Not Available Year: 1995 Page(s): 271-276
Editor(s): Not Available
Publisher: Elsevier Science Publishers B.V.
Language: English
Notes: Not Available
Keywords: Material Specification, Crystallography, Critical Temperature

Materials and Properties

Bi:2212; [Bi-Sr-Ca-Cu-O]
Material Specification for Bi:2212; [Bi-Sr-Ca-Cu-O] Process: Solid State Reaction
Notes: The authors cite P. Krishnaraj et al., Physica C, Vol. 215, 305 (1993), and summarize the procedure as follows. "Samples with the stoichiometry Bi:Sr:Ca:Cu=2:2:1:2 were synthesized from freeze-dried nitrate percursors... It should be noted here that all of the following results from oxygen content and Tc refer to the precise stoichiometry of Bi:Sr:Ca:Cu=2:2:1:2. It is difficult to synthesize 2212 with exact cation stoichiometry by conventional ceramic techniques. These techniques usually yield samples with a Bi:Sr ratio <1 which can, therefore, be expected to have values for oxygen content, tc, and lattice parameters at variance with those reported in this paper."
Formula: Bi2Sr2CaCu2Ox
Informal Name: Bi:2212
Chemical Family: Bi-Sr-Ca-Cu-O
Chemical Class: Oxide
Structure Type: Polycrystalline
Manufacturer: In House
Commercial Name: In House
Production Date:
Lot Number:
Production Form:
Crystallography for Bi:2212; [Bi-Sr-Ca-Cu-O]
Crystal System:
Formula Units per Cell:
Space Group:
Cell Parameters
x of Ox (formula units) Temp K a Å b Å c Å
8.00 296 -- -- 30.810
8.15 296 -- -- 30.833
8.16 296 -- -- 30.830
8.26 296 -- -- 30.779
8.28 296 -- -- 30.773
Measurement Method: X-ray diffraction
"Changes in lattice parameters were studied by X-ray diffraction." No additional measurement details were noted.

Cautions: Unevaluated Data
Digitized data were obtained from Figure 3 of the paper.
Critical Temperature for Bi:2212; [Bi-Sr-Ca-Cu-O]
x of Ox (formula units) Critical Temperature (K)
8.00 83
8.15 87
8.16 85
8.26 75
8.28 75
Measurement Method: SQUID magnetometer
The authors cite P. Krishnaraj et al., Physica C, Vol. 234, 318 (1994), and summarize the procedure as follows. "Magnetic susceptibility measurements were made on a SQUID magnetometer to determine the Tc... The oxygen content ...was determined by thermogravimetry." No additional measurement details were noted.

Cautions: Unevaluated Data
Digitized data were obtained from Figure 3 of the paper.