Material Specification for Bi:2212; [Bi-Sr-Ca-Cu-O]
Process: Solid State Reaction
Notes: The authors cite P. Krishnaraj et al., Physica C, Vol. 215, 305 (1993), and summarize the procedure as follows. "Samples with the stoichiometry Bi:Sr:Ca:Cu=2:2:1:2 were synthesized from freeze-dried nitrate percursors... It should be noted here that all of the following results from oxygen content and Tc refer to the precise stoichiometry of Bi:Sr:Ca:Cu=2:2:1:2. It is difficult to synthesize 2212 with exact cation stoichiometry by conventional ceramic techniques. These techniques usually yield samples with a Bi:Sr ratio <1 which can, therefore, be expected to have values for oxygen content, tc, and lattice parameters at variance with those reported in this paper."
Formula: Bi2Sr2CaCu2Ox
Informal Name: Bi:2212
Chemical Family: Bi-Sr-Ca-Cu-O
Chemical Class: Oxide
Structure Type: Polycrystalline
Manufacturer: In House
Commercial Name: In House
Production Date:
Lot Number:
Production Form:
Crystallography for Bi:2212; [Bi-Sr-Ca-Cu-O]
Crystal System: | |
Formula Units per Cell: | |
Space Group: |
|
Cell Parameters
x of Ox (formula units) |
Temp
K
|
a
Å
|
b
Å
|
c
Å
|
8.00 |
296 |
-- |
-- |
30.810 |
8.15 |
296 |
-- |
-- |
30.833 |
8.16 |
296 |
-- |
-- |
30.830 |
8.26 |
296 |
-- |
-- |
30.779 |
8.28 |
296 |
-- |
-- |
30.773 |
Measurement Method: X-ray diffraction
"Changes in lattice parameters were studied by X-ray diffraction." No additional measurement details were noted.
Cautions: Unevaluated Data
Digitized data were obtained from Figure 3 of the paper.
Critical Temperature for Bi:2212; [Bi-Sr-Ca-Cu-O]
x of Ox (formula units) |
Critical Temperature (K) |
8.00 |
83 |
8.15 |
87 |
8.16 |
85 |
8.26 |
75 |
8.28 |
75 |
Measurement Method: SQUID magnetometer
The authors cite P. Krishnaraj et al., Physica C, Vol. 234, 318 (1994), and summarize the procedure as follows. "Magnetic susceptibility measurements were made on a SQUID magnetometer to determine the T
c... The oxygen content ...was determined by thermogravimetry." No additional measurement details were noted.
Cautions: Unevaluated Data
Digitized data were obtained from Figure 3 of the paper.