NIST High Temp. Superconducting Materials (HTS) Database:

NIST Standard Reference Database 62

Last Update to Data Content: 1996

DOI: https://doi.org/10.18434/T4KP8J


Bibliographic Information

Title: Pressure Dependence of the Superconducting Critical Temperature Tc of HgBa2Ca2Cu3O8+x up to 26 GPa
Author(s): D.T. Jover, R.J. Wijngaarden, A. Schilling, H.R. Ott, and R. Griessen
Publication: Physica C Volume: 235 Issue: Not Available Year: 1994 Page(s): 893-894
Editor(s): Not Available
Publisher: Elsevier Science Publishers B.V.
Language: English
Notes: Vol. 235-240, multivolume issue
Keywords: Material Specification, Critical Temperature

Materials and Properties

Hg:1223; [Hg-Ba-Ca-Cu-O]
Material Specification for Hg:1223; [Hg-Ba-Ca-Cu-O] Process: Solid State Reaction
Notes: "From a well ground mixture of the respective metal nitrates, sintered at 900 °C in O2, the precursor material with nominal composition Ba2CaCu2O5+x is obtained. After regrinding and mixing with powdered HgO, pressed pellets are sealed in evacuated quartz tubes and heated for 5 h at 800 °C. Finally, the pellets are cooled down to room temperature and annealed at 300 °C in flowing oxygen for several hours. Pressure is applied using a cryogenic diamond anvil cell made entirely of stainless steel and can be increased at any temperature simply by turning a knob at the top of the cryostat. Measuring the pressure-induced shift of the ruby R1 fluorescence line the applied pressure is determined in situ at temperatures close to Tc. The temperature is measured using a standard platinum resistor mounted near the diamonds..."
Formula: HgBa2Ca2Cu3O8+x
Informal Name: Hg:1223
Chemical Family: Hg-Ba-Ca-Cu-O
Chemical Class: Oxide
Structure Type: Polycrystalline
Manufacturer: In House
Commercial Name: In House
Production Date:
Lot Number:
Production Form:

Critical Temperature for Hg:1223; [Hg-Ba-Ca-Cu-O]
Pressure (GPa) Critical Temperature (K)
0.0 135.3
3.9 137.0
3.7 137.5
7.1 140.6
7.4 140.9
7.6 140.3
8.1 140.4
9.1 140.5
11.8 141.2
16.5 142.0
16.5 142.4
18.7 142.3
18.7 142.6
23.1 143.4
23.6 144.0
26.1 144.8
Measurement Method: Resistance method
"...Tc is defined as the intersection of the tangent through the inflection point of the resistive transition with a straight-line fit of the normal state just above the transition." No additional measurement details were noted.

Cautions: Unevaluated Data
Digitized data were obtained from Figure 2 of the paper.