NIST High Temp. Superconducting Materials (HTS) Database:

NIST Standard Reference Database 62

Last Update to Data Content: 1996

DOI: https://doi.org/10.18434/T4KP8J


Bibliographic Information

Title: The Effect of Sr Substitution on the Structure and Superconducting Properties of Tl2(Ba2-xSrx)Ca3Cu4O12
Author(s): D.M. Ogborne and M.T. Weller
Publication: Physica C Volume: 235 Issue: Not Available Year: 1994 Page(s): 961-962
Editor(s): Not Available
Publisher: Elsevier Science Publishers B.V.
Language: English
Notes: Vol. 235-240, multivolume issue
Keywords: Material Specification, Crystallography, Critical Temperature, Magnetic Susceptibility

Materials and Properties

Tl:2234; [Tl-Ba(Sr)-Ca-Cu-O]
Material Specification for Tl:2234; [Tl-Ba(Sr)-Ca-Cu-O] Process: Solid State Reaction
Notes: "Samples of Tl1.5(Ba2-xSrx)Ca3.5Cu4O12, x = 0.1, 0.2, 0.3 were synthesized from powders of Tl2O3, BaO2, CaO, CuO and SrO. Samples were crimped in gold tubes fired at 850-865 °C for up to 24 h followed by quenching to room temperature."
Formula: Tl2Ba2-xSrxCa3Cu4O12
Informal Name: Tl:2234
Chemical Family: Tl-Ba(Sr)-Ca-Cu-O
Chemical Class: Oxide
Structure Type: Polycrystalline
Manufacturer: In House
Commercial Name: In House
Production Date:
Lot Number:
Production Form:

Crystallography for Tl:2234; [Tl-Ba(Sr)-Ca-Cu-O]
Crystal System: Tetragonal
Formula Units per Cell:
Space Group:
Cell Parameters
x of Srx (formula units) Temp K a Å b Å c Å
0.0 296 3.8497 -- 42.042
0.1 296 3.8495 -- 42.026
0.2 296 3.8490 -- 41.920
0.3 296 3.8470 -- 41.878
Measurement Method: X-ray diffraction
"Materials were characterized by powder x-ray diffraction (PXD) employing a Siemens D5000 diffractometer with Cu radiation." No additional measurement details were noted.

Cautions: Unevaluated Data
Critical Temperature for Tl:2234; [Tl-Ba(Sr)-Ca-Cu-O]
Critical Temperature (K)
115
Measurement Method: Ac susceptibility
"The superconducting properties were characterized by a.c. susceptibility..." No additional measurement details were noted.

Cautions: Unevaluated Data
Magnetic Susceptibility for Tl:2234; [Tl-Ba(Sr)-Ca-Cu-O]
x of Srx (formula units) Temperature (K) Magnetic Susceptibility (arbitrary)
0.1 90 -0.061
0.1 95 -0.059
0.1 100 -0.055
0.1 105 -0.049
0.1 107 -0.028
0.1 109 -0.011
0.1 111 -0.008
0.1 114 -0.004
0.1 115 0.000
0.1 120 0.000
0.2 90 -0.075
0.2 95 -0.070
0.2 100 -0.064
0.2 105 -0.055
0.2 108 -0.041
0.2 110 -0.012
0.2 113 -0.007
0.2 115 0.000
0.2 120 0.000
0.3 90 -0.092
0.3 95 -0.086
0.3 100 -0.072
0.3 105 -0.059
0.3 108 -0.041
0.3 109 -0.021
0.3 110 -0.011
0.3 112 -0.007
0.3 115 0.000
0.3 120 0.000
Measurement Method: Ac susceptibility
"The superconducting properties were characterized by a.c. susceptibility..." No additional measurement details were noted.

Cautions: Unevaluated Data
Digitized data were obtained from Figure 2 of the paper.