Material Specification for Tl:2234; [Tl-Ba(Sr)-Ca-Cu-O]
Process: Solid State Reaction
Notes: "Samples of Tl1.5(Ba2-xSrx)Ca3.5Cu4O12, x = 0.1, 0.2, 0.3 were synthesized from powders of Tl2O3, BaO2, CaO, CuO and SrO. Samples were crimped in gold tubes fired at 850-865 °C for up to 24 h followed by quenching to room temperature."
Formula: Tl2Ba2-xSrxCa3Cu4O12
Informal Name: Tl:2234
Chemical Family: Tl-Ba(Sr)-Ca-Cu-O
Chemical Class: Oxide
Structure Type: Polycrystalline
Manufacturer: In House
Commercial Name: In House
Production Date:
Lot Number:
Production Form:
Crystallography for Tl:2234; [Tl-Ba(Sr)-Ca-Cu-O]
Crystal System: | Tetragonal |
Formula Units per Cell: | |
Space Group: |
|
Cell Parameters
x of Srx (formula units) |
Temp
K
|
a
Å
|
b
Å
|
c
Å
|
0.0 |
296 |
3.8497 |
-- |
42.042 |
0.1 |
296 |
3.8495 |
-- |
42.026 |
0.2 |
296 |
3.8490 |
-- |
41.920 |
0.3 |
296 |
3.8470 |
-- |
41.878 |
Measurement Method: X-ray diffraction
"Materials were characterized by powder x-ray diffraction (PXD) employing a
Siemens D5000 diffractometer with Cu
radiation." No additional measurement details were noted.
Cautions: Unevaluated Data
Critical Temperature for Tl:2234; [Tl-Ba(Sr)-Ca-Cu-O]
Critical Temperature (K) |
115 |
Measurement Method: Ac susceptibility
"The superconducting properties were characterized by a.c. susceptibility..." No additional measurement details were noted.
Cautions: Unevaluated Data
Magnetic Susceptibility for Tl:2234; [Tl-Ba(Sr)-Ca-Cu-O]
x of Srx (formula units) |
Temperature (K) |
Magnetic Susceptibility (arbitrary) |
0.1 |
90 |
-0.061 |
0.1 |
95 |
-0.059 |
0.1 |
100 |
-0.055 |
0.1 |
105 |
-0.049 |
0.1 |
107 |
-0.028 |
0.1 |
109 |
-0.011 |
0.1 |
111 |
-0.008 |
0.1 |
114 |
-0.004 |
0.1 |
115 |
0.000 |
0.1 |
120 |
0.000 |
0.2 |
90 |
-0.075 |
0.2 |
95 |
-0.070 |
0.2 |
100 |
-0.064 |
0.2 |
105 |
-0.055 |
0.2 |
108 |
-0.041 |
0.2 |
110 |
-0.012 |
0.2 |
113 |
-0.007 |
0.2 |
115 |
0.000 |
0.2 |
120 |
0.000 |
0.3 |
90 |
-0.092 |
0.3 |
95 |
-0.086 |
0.3 |
100 |
-0.072 |
0.3 |
105 |
-0.059 |
0.3 |
108 |
-0.041 |
0.3 |
109 |
-0.021 |
0.3 |
110 |
-0.011 |
0.3 |
112 |
-0.007 |
0.3 |
115 |
0.000 |
0.3 |
120 |
0.000 |
Measurement Method: Ac susceptibility
"The superconducting properties were characterized by a.c. susceptibility..." No additional measurement details were noted.
Cautions: Unevaluated Data
Digitized data were obtained from Figure 2 of the paper.