Material Specification for Tl:2223; [Tl(Hg)-Ba-Ca-Cu-O]
Process: Solid State Reaction
Notes: "Bulk polycrystalline samples of Tl2-xHgxBa2Ca2Cu3O10-δ were prepared by solid state reaction method. Appropriate amounts of HgO, Tl2O3, and Ba2Ca2Cu3O7 precursor were mixed, ground, and pressed into pellets. All the chemical handling was done in a dry box. The pellets were vacuum sealed into quartz tubes. The quartz ampoules were sintered at 830 °C to 870 °C, and finally slow cooled to room temperature."
Formula: Tl2-xHgxBa2Ca2Cu3O10-y
Informal Name: Tl:2223
Chemical Family: Tl(Hg)-Ba-Ca-Cu-O
Chemical Class: Oxide
Structure Type: Polycrystalline
Manufacturer: In House
Commercial Name: In House
Production Date:
Lot Number:
Production Form:
Critical Temperature for Tl:2223; [Tl(Hg)-Ba-Ca-Cu-O]
x of Hgx (formula units) |
Tc(onset) (K) |
Critical Temperature (K) |
0.0 |
122 |
116 |
0.4 |
130 |
126 |
0.6 |
125 |
122 |
Measurement Method: Resistivity method
"The superconducting properties of the samples were characterized by... transport measurements." No additional measurement details were noted.
Cautions: Unevaluated Data
Resistivity (normal state) for Tl:2223; [Tl(Hg)-Ba-Ca-Cu-O]
x of Hgx (formula units) |
Temperature (K) |
Resistivity (normal state) (mΩ·cm) |
0 |
75 |
0 |
0 |
100 |
0 |
0 |
116 |
0 |
0 |
119 |
0.6 |
0 |
120 |
1.2 |
0 |
128 |
1.6 |
0 |
148 |
1.8 |
0 |
173 |
2.1 |
0 |
203 |
2.3 |
0 |
232 |
2.6 |
0 |
254 |
2.7 |
0 |
275 |
2.8 |
0 |
297 |
3.0 |
0.4 |
75 |
0 |
0.4 |
100 |
0 |
0.4 |
126 |
0 |
0.4 |
128 |
0.7 |
0.4 |
130 |
1.1 |
0.4 |
138 |
1.6 |
0.4 |
148 |
1.8 |
0.4 |
175 |
2.2 |
0.4 |
208 |
2.6 |
0.4 |
238 |
3.0 |
0.4 |
248 |
3.1 |
0.4 |
255 |
3.2 |
0.4 |
265 |
3.4 |
0.4 |
287 |
3.5 |
0.4 |
291 |
3.6 |
0.6 |
75 |
0 |
0.6 |
100 |
0 |
0.6 |
122 |
0 |
0.6 |
123 |
0.5 |
0.6 |
124 |
1.1 |
0.6 |
126 |
1.4 |
0.6 |
132 |
1.8 |
0.6 |
138 |
1.9 |
0.6 |
155 |
2.2 |
0.6 |
169 |
2.4 |
0.6 |
187 |
2.6 |
0.6 |
206 |
2.9 |
0.6 |
222 |
3.1 |
0.6 |
240 |
3.3 |
0.6 |
263 |
3.5 |
0.6 |
279 |
3.7 |
0.6 |
295 |
3.9 |
Measurement Method: Resistivity method
"The superconducting properties of the samples were characterized by... transport measurements." No additional measurement details were noted.
Cautions: Unevaluated Data
Digitized data were obtained from Figure 2 of the paper.