Material Specification for Hg:1212; [Hg-Ba-Ca(Sr)-Cu-O]
Process: Solid State Reaction
Notes: "Polycrystalline samples of HBCSCO were synthesized from stoichiometric mixtures of HgO, Ba2CuO3+x, and Ca1-xSrxCuO2 (x=0.14)... Post heat-treatment was preformed under O2 at 250 °C for 8 h." No additional processing details were noted.
Formula: HgBa2Ca1-xSrxCu2O6+y
Informal Name: Hg:1212
Chemical Family: Hg-Ba-Ca(Sr)-Cu-O
Chemical Class: Oxide
Structure Type: Polycrystalline
Manufacturer: In House
Commercial Name: In House
Production Date:
Lot Number:
Production Form:
Crystallography for Hg:1212; [Hg-Ba-Ca(Sr)-Cu-O]
Crystal System: | Tetragonal |
Formula Units per Cell: | |
Space Group: |
P/4mmm
|
Cell Parameters
Temp
K
|
a
Å
|
b
Å
|
c
Å
|
296 |
3.8584(1) |
-- |
12.6646(5) |
Measurement Method: X-ray diffraction
"X-ray powder diffraction patterns (were measured). ... All of the major diffraction lines are well indexed on a tetragonal cell (P4/mmm)... The diffraction data of the oxygen-annealed HBCSCO are almost identical with those of the as-synthesized HBCSCO... The content of the extra oxygen is about 0.11 per formula unit estimated by a TGA analysis." No additional measurement details were noted.
Cautions: Unevaluated Data
Critical Temperature for Hg:1212; [Hg-Ba-Ca(Sr)-Cu-O]
Annealing Time at 250 °C (h) |
Critical Temperature (K) |
0 |
120 |
8 |
124 |
Measurement Method: SQUID magnetometer
Zero field cooled "magnetic susceptibility data (were) obtained using a SQUID magnetometer." No additional measurement details were noted.
Cautions: Unevaluated Data
Magnetic Susceptibility for Hg:1212; [Hg-Ba-Ca(Sr)-Cu-O]
Annealing Time at 250 °C (h) |
Temperature (K) |
Magnetic Susceptibility (arbitrary) |
0 |
6 |
-8.7 |
0 |
21 |
-8.8 |
0 |
35 |
-8.8 |
0 |
51 |
-8.7 |
0 |
71 |
-8.6 |
0 |
85 |
-8.4 |
0 |
100 |
-7.9 |
0 |
110 |
-7.1 |
0 |
114 |
-6.7 |
0 |
115 |
-5.1 |
0 |
116 |
-0.5 |
0 |
118 |
-0.1 |
0 |
120 |
0 |
0 |
140 |
0 |
8 |
6 |
-10.0 |
8 |
21 |
-10.0 |
8 |
41 |
-10.0 |
8 |
60 |
-9.9 |
8 |
80 |
-9.7 |
8 |
92 |
-9.5 |
8 |
100 |
-9.1 |
8 |
109 |
-8.2 |
8 |
119 |
-6.4 |
8 |
122 |
-5.0 |
8 |
123 |
-2.1 |
8 |
124 |
0 |
8 |
130 |
0 |
8 |
140 |
0 |
Measurement Method: SQUID magnetometer
Zero field cooled "magnetic susceptibility data (were) obtained using a SQUID magnetometer." No additional measurement details were noted.
Cautions: Unevaluated Data
Digitized data were obtained from Figure 2 of the paper.