NIST High Temp. Superconducting Materials (HTS) Database:

NIST Standard Reference Database 62

Last Update to Data Content: 1996

DOI: https://doi.org/10.18434/T4KP8J


Bibliographic Information

Title: Influence of the Oxygen Content on the Critical Temperature Tc and the Thermopower of Y0.7Ca0.3Ba2Cu3Oz
Author(s): C.L. Gledel, J.F. Marucco, E. Vincent, D. Favrot, B. Poumellec, B. Touzelin, M. Gupta, and H. Alloul
Publication: Physica C Volume: 175 Issue: Not Available Year: 1991 Page(s): 279-284
Editor(s): Not Available
Publisher: Elsevier Science Publishers B.V.
Language: English
Notes: Not Available
Keywords: Material Specification, Critical Temperature

Materials and Properties

Y:123; [Y(Ca)-Ba-Cu-O]
Material Specification for Y:123; [Y(Ca)-Ba-Cu-O] Process: Solid State Reaction
Notes: The authors cite C. Gledel, Physica C, Vol. 165, 437 (1990), and summarize the procedure as follows. "The fully oxidized samples... were prepared by the standard solid state reaction of Y2O3, CaCO3, BaCO3 and CuO powders at 940 °C under P = (0.1 MPa = 1 atm)... The reduced compounds were obtained by reduction of the Y0.7Ca0.3Ba2Cu3O6.845 oxide under a N2 atmosphere at various temperatures depending on the oxygen content we would achieve."
Formula: Y0.7Ca0.3Ba2Cu3Ox
Informal Name: Y:123
Chemical Family: Y(Ca)-Ba-Cu-O
Chemical Class: Oxide
Structure Type: Polycrystalline
Manufacturer: In House
Commercial Name: In House
Production Date:
Lot Number:
Production Form:

Critical Temperature for Y:123; [Y(Ca)-Ba-Cu-O]
x of Ox (formula units) Critical Temperature (K)
6.02 35
6.47 82
6.73 84
6.80 84
6.85 88
Measurement Method: Four-probe method
"Electrical resistance was measured... using a stnadard four probe technique. Electrical contacts were made by soldering indium ultrasonically onto the faces fo the pellet. Carbon glass and platinum resistance thermometers were used for the mesurements fo the temperature. The overall accuracy of measuring temperature was better than 1 K. The superconducting temperature Tc was taken to be the temperature at which the resistance of the samples becomes null."

Cautions: Evaluated Data