NIST High Temp. Superconducting Materials (HTS) Database:

NIST Standard Reference Database 62

Last Update to Data Content: 1996

DOI: https://doi.org/10.18434/T4KP8J


Bibliographic Information

Title: Fracture Toughness of YBa2Cu3Ox Containing Y2BaCuO5 and ZrO2
Author(s): K.C. Goretta, M.L. Kullberg, D. Bar, G.A. Risch, and J.L. Routbort
Publication: Superconductor Science and Technology Volume: 4 Issue: Not Available Year: 1991 Page(s): 544-547
Editor(s): Not Available
Publisher: IOP Publishing Ltd
Language: English
Notes: Not Available
Keywords: Material Specification, Fracture Toughness

Materials and Properties

Y:123; [Y-Ba-Cu-O]
Material Specification for Y:123; [Y-Ba-Cu-O] Process: Solid State Reaction
Notes: "Phase-pure, orthorhombic 123 was synthesized by solid state reaction of reagent-grade Y2O3, BaCO3 and CuO powders. Synthesis was accomplished in 4 h at 800 °C by exposure to pure O2 of reduced total pressure. Part of the 123 powder was mixed by mortar and pestle with (about) 10 or 20 mol% tetragonal ZrO2 particles (composition) 97 mol% ZrO2, 3 mol% Y2O3; average particle size (about) 0.8 µm) that had been coated with 211... The 211 solution... was prepared from metal acetate salts dissolved in distilled water... Bar specimens were cold pressed from the 123 and 123/211/ZrO3 powders. The average bar dimensions before firing were about 50 mm x 7 mm x 3 mm. The bars were sintered for 3-6 h in flowing O2 at temperatures for 950 to 990 °C... Some of the bars were annealed in O2 at 425-450 °C for 10 h to convert the tetragonal 123 to the superconducting orthorhombic phase." Three compostions were reported: Y123: Phase-pure orthorhombic Y:123 YZ10: Y123/Y211/10% ZrO2 YZ20: Y123/Y211/20% ZrO2
Formula: YBa2Cu3Ox
Informal Name: Y:123
Chemical Family: Y-Ba-Cu-O
Chemical Class: Oxide
Structure Type: Polycrystalline
Manufacturer: In House
Commercial Name: In House
Production Date:
Lot Number:
Production Form:
Fracture Toughness for Y:123; [Y-Ba-Cu-O]
Composition () Sintering Temperature (°C) Sintering Time (h) Density (%theoretical) (%) Fracture Toughness (MPa·m1/2)
Y123 930 6 85 1.2 ± 0.1
Y123 950 6 90 1.5 ± 0.3
Y123 990 6 93 3.1 ± 0.4
YZ10 990 6 85-90 3.6 ± 0.4
YZ20 990 6 85-90 4.5 ± 0.3
Measurement Method: Single-edge notched beam
The authors cite W. F. Brown, Jr. et al., 1967 Plane Strain Crack Toughness Testing of High Strength Metallic Materials (ASTM TP 410) (Philadelphia: ASTM) p 12, and summarize the procedure as follows. "Fracture toughness values were determined... by the single-edge notched beam method. Notches were cut normal to a 3 mm x 50 mm face (into the 7 mm dimension) and were about 3 mm deep. Four bars of each composition were loaded separately in three-point bending at a rate of 1.27 mm min-1. K was calculated..."

Cautions: Evaluated Data