Material Specification for Bi:221; [Bi(Pb)-Sr-Cu-O]
Process: Melt Processed
Notes: "Superconducting single crystals... were grown in air in gold crucibles from copper-rich melts... Samples were typically soaked at 950 °C for 12 h, slowly cooled at a rate of 5 °C/h to 850 °C, and then furnace-cooled to room temperature."
Formula: Bi2-xPbxSr2CuO6+x
Informal Name: Bi:221
Chemical Family: Bi(Pb)-Sr-Cu-O
Chemical Class: Oxide
Structure Type: Single Crystal
Manufacturer: In House
Commercial Name: In House
Production Date:
Lot Number:
Production Form:
Density (mass) for Bi:221; [Bi(Pb)-Sr-Cu-O]
Temperature (K) |
Density (g cm-3) |
293 |
7.169 |
Measurement Method: X-ray diffraction
"Crystals were selected from the preparations in which the 1/2Bi
2O
3:PbO
2 ratio of the melt was 2-y:y (y = 0.5). Their diffraction patterns were indexed on an Enraf-Nonius CAD4 single-crystal X-ray diffractometer... Structural refinements were performed using a series of computer programs developed by Calabrese." Data were collected using MoKα radiation on the range 1.7 ≤ 2θ ≤ 60.0 degrees.
Cautions: Evaluated Data
Crystallography for Bi:221; [Bi(Pb)-Sr-Cu-O]
Crystal System: | Orthorhombic |
Formula Units per Cell: | |
Space Group: |
Pnan
|
Cell Parameters
Temp
K
|
a
Å
|
b
Å
|
c
Å
|
293 |
5.2757(7) |
5.3797(8) |
24.558(3) |
Atomic Coordinates
Atom |
Temp
K
|
a-axis |
b-axis |
c-axis |
Bi(1) |
293 |
0.9829(4) |
0.2681(3) |
0.06311(4) |
Sr(1) |
293 |
0.9604(6) |
0.7530(8) |
0.1772(1) |
Cu(1) |
293 |
0.4640(12) |
0.75 |
0.25 |
O(1) |
293 |
0.7071(46) |
0.9998(91) |
0.2523(12) |
O(2) |
293 |
0.4662(62) |
0.7667(68) |
0.1454(7) |
O(3) |
293 |
0.9153(74) |
0.6643(73) |
0.0716(12) |
Measurement Method: X-ray diffraction
"Crystals were selected from the preparations in which the 1/2Bi
2O
3:PbO
2 ratio of the melt was 2-y:y (y = 0.5). Their diffraction patterns were indexed on an Enraf-Nonius CAD4 single-crystal X-ray diffractometer... Structural refinements were performed using a series of computer programs developed by Calabrese." Data were collected using MoKα radiation on the range 1.7 ≤ 2θ ≤ 60.0 degrees.
Cautions: Evaluated Data
Critical Temperature for Bi:221; [Bi(Pb)-Sr-Cu-O]
Critical Temperature (K) |
18 |
Measurement Method: Ac inductance
"T
c data were determined by AC inductance measurements of magnetic flux exclusion."
Cautions: Evaluated Data