NIST High Temp. Superconducting Materials (HTS) Database:

NIST Standard Reference Database 62

Last Update to Data Content: 1996

DOI: https://doi.org/10.18434/T4KP8J


Bibliographic Information

Title: Anisotropy of Oxygen Self-Diffusion in YBa2Cu3O7-δ Single Crystals
Author(s): S. Bredikhin, G. Emel'chenko, V. Shechtman, A.A. Zhokhov, S. Carter, R.J. Chater, J.A. Kilner, and B.C.H. Steele
Publication: Physica C Volume: 179 Issue: Not Available Year: 1991 Page(s): 286-290
Editor(s): Not Available
Publisher: Elsevier Science Publishers B.V.
Language: English
Notes: Not Available
Keywords: Material Specification, Diffusion Coefficient

Materials and Properties

Materials and Properties

Y:123; [Y-Ba-Cu-O]
Material Specification for Y:123; [Y-Ba-Cu-O] Process: Solid State Reaction
Notes: The authors cite G.A. Emel'chenko et al., Mater. Lett., Vol. 9, 96 (1990), and summarize the procedure as follows. "Single crystals of YBa2Cu3O7-δ were... monocrystalline plates of maximum dimensions 4x3x0.15 mm3, the c-axis being perpendicular to the largest plane of the plate."
Formula: YBa2Cu3O7-x
Informal Name: Y:123
Chemical Family: Y-Ba-Cu-O
Chemical Class: Oxide
Structure Type:
Manufacturer: In House
Commercial Name: In House
Production Date:
Lot Number:
Production Form:


Diffusion Coefficient for Y:123; [Y-Ba-Cu-O]
Direction () Temperature (°C) Diffusion Coefficient (nm2/s) Diffusion Coefficient (log10(cm2/s))
ab-plane 400 300 -11.5
ab-plane 800 78000 -8.1
c-axis 400 0.004 -16.4
c-axis 800 6200 -10.2
Measurement Method: Isotopic exchange
The authors cite J.A. Kilner et al., Solid State Ionics, Vol. 12, 89 (1984), and summarize the procedure as follows. "The isotopic exchange... was carried out in an atmosphere containing 70% O218, 5% O216 and 25% N2. The diffusion profiling of O16 and O18 isotopes was performed in a secondary ion mass spectrometer (SIM) Atomika 6500 and the surface ion etching was carried out by 10 keV Xe+ ions. The diffusion coefficients... and the surface exchange coefficients... of oxygen were determined by fitting..."

Cautions: Evaluated Data