NIST Standard Reference Database 30
Last Update to Data Content: 2002
"Effect of CaF2 on the Thermal Expansion of a Sample with the Composition Si3N4 + 10 mass % MgO," A.A. Korneev and I.T. Ostapenko, Inorganic Materials, Vol. 22 [9], pp. 1279-1281 (1987), published by Plenum Publishing Corporation.Language: English
The authors cite I. T. Ostapenko et al., Izv. Akad. Nauk SSSR, Neorg. Mater., Vol. 16, No. 5, 846 (1980), and summarize the procedure as follows. Starting materials included MgO, CaF2, and Si3N4 powder having mass fraction composition (%): 57-60 total Si, 35-39.4 N, 5.5 free Si. Samples were hot pressed and had dimensions 4 mm x 5 mm x 5 mm. Material Number 1-- Sintering Aids: 10% MgO Material Number 2-- Sintering Aids: 10% MgO; 10% CaF2 Material Number 3-- Sintering Aids: 10% MgO; 20% CaF2.
The authors cite M. G. Kolendovskii et al., "Dilatometer with automatic recording of the magnitude of the thermal expansion of solids", Teplofiz. Vys. Temp., Vol. 13, No. 5, 1116 (1975), and summarize the procedure as follows. "The coefficient of thermal expansion α was determined on a quartz dilatometer in the temperature range 300 K to 1300 K. The relative error equalled 5%." No additional measurement details were noted.
| Amount of Element ( formula units ) |
Element ( no unit ) |
|---|---|
| 3 | Si |
| 4 | N |
| Sintering Aid Mass Fraction ( % ) |
Sintering Aid ( no unit ) |
|---|---|
| 10 | MgO |
| Temperature ( °C ) |
Thermal Expansion ( 10-6 K-1 ) |
|---|---|
| 115 | 1.5 |
| 198 | 1.7 |
| 284 | 2.1 |
| 399 | 2.2 |
| 510 | 2.4 |
| 599 | 2.5 |
| 695 | 2.6 |
| 786 | 2.7 |
| 891 | 2.8 |
| 991 | 2.9 |
Digitized data were obtained from Figure 2 of the paper.
| Amount of Element ( formula units ) |
Element ( no unit ) |
|---|---|
| 3 | Si |
| 4 | N |
| Sintering Aid Mass Fraction ( % ) |
Sintering Aid ( no unit ) |
|---|---|
| 10 | MgO |
| 10 | CaF2 |
| Temperature ( °C ) |
Thermal Expansion ( 10-6 K-1 ) |
|---|---|
| 113 | 1.9 |
| 194 | 2.1 |
| 290 | 2.5 |
| 411 | 2.8 |
| 513 | 3.0 |
| 602 | 3.1 |
| 695 | 3.3 |
| 787 | 3.4 |
| 889 | 3.5 |
| 998 | 3.6 |
Digitized data were obtained from Figure 2 of the paper.
| Amount of Element ( formula units ) |
Element ( no unit ) |
|---|---|
| 3 | Si |
| 4 | N |
| Sintering Aid Mass Fraction ( % ) |
Sintering Aid ( no unit ) |
|---|---|
| 10 | MgO |
| 20 | CaFe2 |
| Temperature ( °C ) |
Thermal Expansion ( 10-6 K-1 ) |
|---|---|
| 113 | 3.0 |
| 197 | 3.5 |
| 290 | 3.9 |
| 398 | 4.2 |
| 515 | 4.5 |
| 602 | 4.6 |
| 710 | 4.8 |
| 786 | 4.9 |
| 891 | 5.0 |
| 993 | 5.0 |
Digitized data were obtained from Figure 2 of the paper.