NIST Standard Reference Database 30
Last Update to Data Content: 2002
"Measurement of Thermal Diffusivity of Reaction Bonded Silicon Nitride," J.J. Serra, M. Jaymes, and M. Cantarel, Journal de Physique, Vol. 47 [2], pp. 635-639 (1986), published by Societe Francaise de Physique.Language: English
Samples measured 50 mm in diameter and 5 mm in thickness. Material #1 had 21% β-Si3N4, 79% α-Si3N4 with trace amounts of Si2ON2. Material # 2 had 91% β-Si3N4, 4.5% α-Si3N4, and 4.5% Si2ON2. Material #3 had 33% β-Si3N4, 67% α-Si3N4, and no detectable amount of silicon oxynitride.
A 45 kW ETCA solar furnace was used to subject the test samples to an incident light flux. Samples were held at three points by concentric grip clips with ceramic pads. This assembly was placed behind a H2O-cooled diaphragm of the same diameter as the sample. Optical pyrometry was used to measure the temperatures on both sides of the samples. Thermal diffusivities were calculated on the basis of the model of a plane wall of finite thickness.
| Mass Fraction ( % ) |
Phase ( no unit ) |
|---|---|
| 79 | αSi3N4 |
| 21 | βSi3N4 |
| Trace amnt | Si2ON2 |
| Amount of Element ( formula units ) |
Element ( no unit ) |
|---|---|
| 3 | Si |
| 4 | N |
| Density ( g cm-3 ) |
|---|
| 2.45 |
| Elastic Modulus ( GPa ) |
|---|
| 155 |
| Poisson's Ratio ( no unit ) |
|---|
| 0.235 |
| Temperature ( °C ) |
Thermal Diffusivity ( cm2 s-1 ) |
|---|---|
| 161 | 0.035 |
| 397 | 0.030 |
| 424 | 0.030 |
| 493 | 0.029 |
| 594 | 0.026 |
| 642 | 0.026 |
| 762 | 0.023 |
| 821 | 0.023 |
| 914 | 0.022 |
Digitized data were obtained from Figure 4 of the paper.
| Mass Fraction ( % ) |
Phase ( no unit ) |
|---|---|
| 91.0 | βSi3N4 |
| 4.5 | αSi3N4 |
| 4.5 | Si2ON2 |
| Amount of Element ( formula units ) |
Element ( no unit ) |
|---|---|
| 3 | Si |
| 4 | N |
| Density ( g cm-3 ) |
|---|
| 2.35 |
| Elastic Modulus ( GPa ) |
|---|
| 135 |
| Poisson's Ratio ( no unit ) |
|---|
| 0.225 |
| Temperature ( °C ) |
Thermal Diffusivity ( cm2 s-1 ) |
|---|---|
| 191 | 0.041 |
| 336 | 0.034 |
| 450 | 0.032 |
| 618 | 0.026 |
| 727 | 0.024 |
Digitized data were obtained from Figure 4 of the paper.
| Mass Fraction ( % ) |
Phase ( no unit ) |
|---|---|
| 67 | αSi3N4 |
| 33 | βSi3N4 |
| Amount of Element ( formula units ) |
Element ( no unit ) |
|---|---|
| 3 | Si |
| 4 | N |
| Density ( g cm-3 ) |
|---|
| 2.55 |
| Elastic Modulus ( GPa ) |
|---|
| 170 |
| Poisson's Ratio ( no unit ) |
|---|
| 0.235 |
| Temperature ( °C ) |
Thermal Diffusivity ( cm2 s-1 ) |
|---|---|
| 155 | 0.054 |
| 315 | 0.048 |
| 444 | 0.041 |
| 532 | 0.037 |
| 593 | 0.035 |
| 717 | 0.031 |
| 812 | 0.030 |
| 948 | 0.027 |
Digitized data were obtained from Figure 4 of the paper.