NIST Structural Ceramics Database (SCD) Database

NIST Standard Reference Database 30

Last Update to Data Content: 2002

DOI: http://dx.doi.org/10.18434/T4F30D


SCD Citation Number: Z00023

Bibliographic Information

Reference:
"Analysis of Candidate Silicon Carbide Recuperator Materials Exposed to Industrial Furnace Environments," J.J. Federer, T.N. Tiegs, D.M. Kotchick, and D. Petrak, ORNL Report Number: ORNL/TM-9677, pp. 1-61 (1985), published by Oak Ridge National Laboratory.
Language: English

General Materials Processing Notes

"The...materials (were)...commercially available SiC ceramics....The specimens were mostly tubes measuring nominally 25mm or 89 mm outer diameter (1 or 3.5 in.) and 25cm to 30 cm long (10 to 12 in.). ... The corrosion testing program involved installation of tubular specimens... in... industrial furnaces for exposure to high temperature combustion environments. Although all furnaces burned natural gas, the composition of the flue gases depended on the type of furnace operation... and, possibly, on specific location within the flue. The exposures occurred during typical furnace operations involving feed materials, heating and cooling cycles, maximum temperatures, fluxes, and air-fuel mixtures. The aluminum remelt furnaces were charged with NaCl-KC1-Na3AlF6 flux along with metal to be melted. In addition, the molten aluminum in furnace No. 2 was sparged with chlorine gas during a portion of each normal cycle. ... Steel billets in the soaking pits were covered with topping compounds, which is standard industry practice to minimize oxidation. Although flue gases in the furnaces were not analyzed, analysis of material that deposited on some specimens revealed significant quantities of metals. Gaseous species in the fuel combustion products... included N2, O2, CO2, and H2O."

Measurement Methods

Corrosion test
"The outer diameters of exposed specimens were measured to determine changes indicative of corrosion. Measurements were made with a micrometer on apparently clean specimens, i.e., those from the forge, steel reheat, and steel soaking pit furnaces. Specimens from the aluminum remelt furnaces ... had deposits on the surfaces, which required that their diameters be measured with a microscope on samples prepared for ceramographic examination. In either case, three or four measurements were made at approximately equal intervals around the circumference."
C-ring test
"C-ring specimens cut from tubes... Tubes were cut into 5 mm wide rings using a cutoff wheel impregnated with 75 µm diamonds. C-rings were made by cutting approximately 5 mm long arcs from the rings. The final thickness of the rings was obtained by grinding both sides with 75 µm diamond abrasive. The outer edges of specimens were beveled with a 30 µm diamond lapping wheel. The specimens were loaded so that a tensile stress was applied to the outer surface at a point opposite the open part of the ring. Specimens were heated to 1100 °C in air, then the loading ram was advanced at 8.5 µm/s ... until fracture occurred."

Index of Materials and Properties (Click on a selected Material Number to expand material properties menu)

Material Specification and Properties for SiC

Material number 1 of 3
in SCD Citation Number: Z00023
Chemical Class: Carbide
Chemical Family: Si-C
Formula: SiC
Informal Name: silicon carbide
Structure Type: Polycrystalline
Manufacturer: Carborundum Company
Commercial Name: Hexoloy SA
Production Form: Tube
Process: Sintering

SiC

Material number 1 of 3
in SCD Citation Number: Z00023
Elemental Composition
Amount of
Element
( formula units )
Element
 
( no unit )
1 Si
1 C
Measurement Method: Reported Formula
Evaluation Status: Unevaluated

SiC

Material number 1 of 3
in SCD Citation Number: Z00023
Corrosion Rate
Exposure
Time
( h )
Maximum
Temperature
( °C )
Furnace
 
 
Corrosion Rate
 
( mg cm-2 h-1 )
5545 1040 Al Remelt1 - 36
4440 1175 Forge + 7
1455 1100 Reheat - 7
2280 925 Soak Pit 1 - 7
3460 1250 Soak Pit 2 -468
Measurement Method: Corrosion test
Evaluation Status: Evaluated by acceptance criteria
Cautions:
Surface recession rates were converted to corrosion rates.

SiC

Material number 1 of 3
in SCD Citation Number: Z00023
Flexural Strength
C-ring Test
Temperature
( °C )
Pre-Test
Furnace
 
Flexural
Strength
( MPa )
1100 Al Remelt1 204
1100 Forge 238
1100 Reheat 231
1100 Soak Pit1 233
Measurement Method: C-ring test
Evaluation Status: Evaluated by acceptance criteria

Material Specification and Properties for SiC

Material number 2 of 3
in SCD Citation Number: Z00023
Chemical Class: Carbide
Chemical Family: Si-C
Formula: SiC
Informal Name: silicon carbide
Structure Type: Polycrystalline
Manufacturer: Norton Company
Commercial Name: NC-430
Production Form: Tube
Process: Sintering

SiC

Material number 2 of 3
in SCD Citation Number: Z00023
Elemental Composition
Amount of
Element
( formula units )
Element
 
( no unit )
1 Si
1 C
Measurement Method: Reported Formula
Evaluation Status: Unevaluated

SiC

Material number 2 of 3
in SCD Citation Number: Z00023
Corrosion Rate
Exposure
Time
( h )
Maximum
Temperature
( °C )
Furnace
 
 
Corrosion Rate
 
( mg cm-2 h-1 )
5545 1040 Al Remelt1 - 54
530 1150 Al Remelt2 -241
4440 1175 Forge - 14
1455 1100 Reheat - 90
2280 925 Soak Pit 1 - 22
3460 1250 Soak Pit 2 -540
Measurement Method: Corrosion test
Evaluation Status: Evaluated by acceptance criteria
Cautions:
Surface recession rates were converted to corrosion rates.

SiC

Material number 2 of 3
in SCD Citation Number: Z00023
Flexural Strength
C-ring Test
Temperature
( °C )
Pre-Test
Furnace
 
Flexural
Strength
( MPa )
1100 Al Remelt1 184
1100 Al Remelt2 220
1100 Reheat 325
1100 Soak Pit 1 162
Measurement Method: C-ring test
Evaluation Status: Evaluated by acceptance criteria

Material Specification and Properties for SiC

Material number 3 of 3
in SCD Citation Number: Z00023
Chemical Class: Carbide
Chemical Family: Si-C
Formula: SiC
Informal Name: silicon carbide
Structure Type: Polycrystalline
Manufacturer: Carborundum Company
Commercial Name: KT
Production Form: Tube
Process: Reaction Sintering

SiC

Material number 3 of 3
in SCD Citation Number: Z00023
Elemental Composition
Amount of
Element
( formula units )
Element
 
( no unit )
1 Si
1 C
Measurement Method: Reported Formula
Evaluation Status: Unevaluated

SiC

Material number 3 of 3
in SCD Citation Number: Z00023
Corrosion Rate
Exposure
Time
( h )
Maximum
Temperature
( °C )
Furnace
 
 
Corrosion Rate
 
( mg cm-2 h-1 )
3460 1250 Soak Pit 2 -540
Measurement Method: Corrosion test
Evaluation Status: Evaluated by acceptance criteria
Cautions:
Surface recession rates were converted to corrosion rates.