NIST Standard Reference Database 30
Last Update to Data Content: 2002
"Pressureless Sintering of Si3N4 with Y2O3 and Al2O3," T. Hayashi, H. Munakata, H. Suzuki, and H. Saito, Journal of Materials Science, Vol. 21, pp. 3501-3508 (1986), published by Chapman and Hall.Language: English
"Si3N4 powder was supplied by Herman C. Stark (Berlin); Y2O3 (99.99% pure) and Al2O3 (98.8% pure) were supplied by Wako Pure Chemical Industries (Osaka, Japan) and Kanto Chemical Co. (Tokyo, Japan) respectively. ... Si3N4, Y2O3, and Al2O3 were mixed in isopropyl alcohol in an automatic agate mortar for 2 h. ... The mixed powder was weighed out (about 3 g) and then uniaxially pressed at 147 MPa. The size of the green compacts was 40 mm x 8 mm x 4 mm. The green compacts were dried at 100 °C and 400 °C, and then sintered at 1750 °C in N2 atmosphere (for 15 h). Powder beds were used to suppress the decomposition of Si3N4 at high temperature."
"The size of specimens for bending tests was 25 mm x 5 mm x 3 mm and the specimens were finally polished using 0.05 µm Al2O3." No additional measurement details were noted.
| Amount of Element ( formula units ) | Element ( no unit ) |
|---|---|
| 3 | Si |
| 4 | N |
| Sintering Aid ( no unit ) |
|---|
| Y2O3 |
| Al2O3 |
| Temperature ( °C ) | Mass Fraction of Al2O3 ( % ) | Mass Fraction of Y2O3 ( % ) | Density ( g cm-3 ) |
|---|---|---|---|
| 22 | 1.9 | 8.2 | 2.43 |
| 22 | 3.7 | 16.3 | 2.98 |
| 22 | 5.0 | 15.0 | 3.11 |
| 22 | 6.2 | 13.8 | 3.18 |
| 22 | 4.3 | 5.7 | 2.62 |
| 22 | 8.6 | 11.4 | 3.10 |
| 22 | 11.0 | 9.0 | 3.09 |
| 22 | 13.5 | 6.5 | 3.00 |
No measurement details were noted.
| Temperature ( °C ) | Mass Fraction of Al2O3 ( % ) | Mass Fraction of Y2O3 ( % ) | Flexural Strength ( MPa ) |
|---|---|---|---|
| 22 | 1.9 | 8.2 | 235 |
| 22 | 3.7 | 16.3 | 314 |
| 22 | 5.0 | 15.0 | 480 |
| 22 | 6.2 | 13.8 | 490 |
| 22 | 4.3 | 5.7 | 314 |
| 22 | 8.6 | 11.4 | 500 |
| 22 | 11.0 | 9.0 | 392 |
| 22 | 13.5 | 6.5 | 402 |