NIST Structural Ceramics Database (SCD) Database

NIST Standard Reference Database 30

Last Update to Data Content: 2002

DOI: http://dx.doi.org/10.18434/T4F30D


SCD Citation Number: Z00034

Bibliographic Information

Reference:
"Pressureless Sintering of Si3N4 with Y2O3 and Al2O3," T. Hayashi, H. Munakata, H. Suzuki, and H. Saito, Journal of Materials Science, Vol. 21, pp. 3501-3508 (1986), published by Chapman and Hall.
Language: English

General Materials Processing Notes

"Si3N4 powder was supplied by Herman C. Stark (Berlin); Y2O3 (99.99% pure) and Al2O3 (98.8% pure) were supplied by Wako Pure Chemical Industries (Osaka, Japan) and Kanto Chemical Co. (Tokyo, Japan) respectively. ... Si3N4, Y2O3, and Al2O3 were mixed in isopropyl alcohol in an automatic agate mortar for 2 h. ... The mixed powder was weighed out (about 3 g) and then uniaxially pressed at 147 MPa. The size of the green compacts was 40 mm x 8 mm x 4 mm. The green compacts were dried at 100 °C and 400 °C, and then sintered at 1750 °C in N2 atmosphere (for 15 h). Powder beds were used to suppress the decomposition of Si3N4 at high temperature."

Measurement Methods

SCD Citation Number: Z00034
Three-point bend test
"The size of specimens for bending tests was 25 mm x 5 mm x 3 mm and the specimens were finally polished using 0.05 µm Al2O3." No additional measurement details were noted.

Index of Materials and Properties

Material Number 1: Si3N4·xAl2O3·yY2O3

Material Specification and Properties for Si3N4·xAl2O3·yY2O3

Material number 1 of 1
in SCD Citation Number: Z00034
Chemical Class: Nitride
Chemical Family: Si-N:Al2O3,Y2O3
Formula: Si3N4·xAl2O3·yY2O3
Informal Name: silicon nitride
Structure Type: Polycrystalline
Manufacturer: In-House
Production Form: Bar
Process: Sintering

Si3N4·xAl2O3·yY2O3

Material number 1 of 1
in SCD Citation Number: Z00034
Elemental Composition
Amount of
Element
( formula units )
Element
 
( no unit )
3 Si
4 N

Measurement Method: Reported Formula
Evaluation Status: Unevaluated

Si3N4·xAl2O3·yY2O3

Material number 1 of 1
in SCD Citation Number: Z00034
Sintering Aids
Sintering Aid
 
( no unit )
Y2O3
Al2O3

Measurement Method: Reported Formula
Evaluation Status: Unevaluated

Si3N4·xAl2O3·yY2O3

Material number 1 of 1
in SCD Citation Number: Z00034
Density (mass)
Temperature
 
( °C )
Mass Fraction
of Al2O3
( % )
Mass Fraction
of Y2O3
( % )
Density
 
( g cm-3 )
22 1.9 8.2 2.43
22 3.7 16.3 2.98
22 5.0 15.0 3.11
22 6.2 13.8 3.18
22 4.3 5.7 2.62
22 8.6 11.4 3.10
22 11.0 9.0 3.09
22 13.5 6.5 3.00

Measurement Method: Unknown
Evaluation Status: Unevaluated Cautions:
No measurement details were noted.

Si3N4·xAl2O3·yY2O3

Material number 1 of 1
in SCD Citation Number: Z00034
Flexural Strength
Temperature
 
( °C )
Mass Fraction
of Al2O3
( % )
Mass Fraction
of Y2O3
( % )
Flexural
Strength
( MPa )
22 1.9 8.2 235
22 3.7 16.3 314
22 5.0 15.0 480
22 6.2 13.8 490
22 4.3 5.7 314
22 8.6 11.4 500
22 11.0 9.0 392
22 13.5 6.5 402

Measurement Method: Three-point bend test
Evaluation Status: Unevaluated