NIST Structural Ceramics Database (SCD) Database

NIST Standard Reference Database 30

Last Update to Data Content: 2002

DOI: http://dx.doi.org/10.18434/T4F30D


SCD Citation Number: Z00045

Bibliographic Information

Reference:
"Burner Rig Hot Corrosion of Silicon Carbide and Silicon Nitride," D.S. Fox and J.L. Smialek, Journal of the American Ceramic Society, Vol. 73 [2], pp. 303-311 (1990), published by American Ceramic Society.
Language: English

General Materials Processing Notes

The materials used in this study were commercially available silicon carbide and silicon nitride materials.

Measurement Methods

Four-point bend test
Strengths were measured using a four-point bend fixture with an outer span of 1.9 cm and inner span of 0.95 cm. The loading rate was 0.05 cm/min. The nominal dimensions of the specimens were 2.50 cm x 0.55 cm by 0.27 cm for SiC, and 2.50 cm x 0.64 cm x 0.34 cm for Si3N4. Corroded specimens were polished flat on both tensile and compressive sides. Specimens were polished with 600-grit SiC paper, followed by polishing with 45-µm thick remained on these samples after polishing. The top faces with the largest amounts of corrosion products were used as the tensile surfaces in the bend tests. Specimens were corroded in a burner rig pressurized to 400 kPa using jet A fuel (0.05% S) burned at a fuel-to air ratio of 0.021±0.002 at a temperature of 1000 ± 10 °C. The ends of the specimens were held by grade A lava (aluminosilicate) holders. Specimens were positioned horizontally with thicknesses facing the gas flow. Temperatures were measured with two type R thermocouples placed in the gas stream between the specimens with specimen-to -thermocouple distances of about 3.8 cm. The gas speed was 94±3 m/s. The gas contained 2 ppm Na added by aspirating a solution of NaCl/H2O into the flame.

Index of Materials and Properties (Click on a selected Material Number to expand material properties menu)

Material Specification and Properties for SiC

Material number 1 of 7
in SCD Citation Number: Z00045
Chemical Class: Carbide
Chemical Family: Si-C
Formula: SiC
Informal Name: silicon carbide
Structure Type: Polycrystalline
Manufacturer: Carborundum Company
Commercial Name: Hexoloy SA
Process: Sintering

SiC

Material number 1 of 7
in SCD Citation Number: Z00045
Phase Composition
Phase
 
( no unit )
α-SiC
Measurement Method: Reported Formula
Evaluation Status: Unevaluated

SiC

Material number 1 of 7
in SCD Citation Number: Z00045
Elemental Composition
Amount of
Element
( formula units )
Element
 
( no unit )
1 Si
1 C
Measurement Method: Reported Formula
Evaluation Status: Unevaluated

SiC

Material number 1 of 7
in SCD Citation Number: Z00045
Sintering Aids
Sintering Aid
 
( no unit )
B
C
Measurement Method: Reported Formula
Evaluation Status: Unevaluated

SiC

Material number 1 of 7
in SCD Citation Number: Z00045
Flexural Strength
Temperature
 
( °C )
Corrosion
Time
( h )
Flexural
Strength
( MPa )
22 0 401 ± 55
22 40 308 ± 42
Measurement Method: Four-point bend test
Evaluation Status: Evaluated by acceptance criteria

Material Specification and Properties for SiC

Material number 2 of 7
in SCD Citation Number: Z00045
Chemical Class: Carbide
Chemical Family: Si-C
Formula: SiC
Informal Name: silicon carbide
Structure Type: Polycrystalline
Manufacturer: General Electric Company
Process: Sintering

SiC

Material number 2 of 7
in SCD Citation Number: Z00045
Phase Composition
Phase
 
( no unit )
β-SiC
Measurement Method: Reported Formula
Evaluation Status: Unevaluated

SiC

Material number 2 of 7
in SCD Citation Number: Z00045
Elemental Composition
Amount of
Element
( formula units )
Element
 
( no unit )
1 Si
1 C
Measurement Method: Reported Formula
Evaluation Status: Unevaluated

SiC

Material number 2 of 7
in SCD Citation Number: Z00045
Sintering Aids
Sintering Aid
 
( no unit )
B
C
Measurement Method: Reported Formula
Evaluation Status: Unevaluated

SiC

Material number 2 of 7
in SCD Citation Number: Z00045
Flexural Strength
Temperature
 
( °C )
Corrosion
Time
( h )
Flexural
Strength
( MPa )
22 0 406 ± 27
22 40 297 ± 50
Measurement Method: Four-point bend test
Evaluation Status: Evaluated by acceptance criteria

Material Specification and Properties for SiC

Material number 3 of 7
in SCD Citation Number: Z00045
Chemical Class: Carbide
Chemical Family: Si-C
Formula: SiC
Informal Name: silicon carbide
Structure Type: Polycrystalline
Manufacturer: Kyocera
Commercial Name: SC 201
Process: Sintering

SiC

Material number 3 of 7
in SCD Citation Number: Z00045
Phase Composition
Phase
 
( no unit )
α-SiC
Measurement Method: Reported Formula
Evaluation Status: Unevaluated

SiC

Material number 3 of 7
in SCD Citation Number: Z00045
Elemental Composition
Amount of
Element
( formula units )
Element
 
( no unit )
1 Si
1 C
Measurement Method: Reported Formula
Evaluation Status: Unevaluated

SiC

Material number 3 of 7
in SCD Citation Number: Z00045
Sintering Aids
Sintering Aid
 
( no unit )
B
Measurement Method: Reported Formula
Evaluation Status: Unevaluated

SiC

Material number 3 of 7
in SCD Citation Number: Z00045
Flexural Strength
Temperature
 
( °C )
Corrosion
Time
( h )
Flexural
Strength
( MPa )
22 0 451 ± 31
22 40 299 ± 40
Measurement Method: Four-point bend test
Evaluation Status: Evaluated by acceptance criteria

Material Specification and Properties for SiC

Material number 4 of 7
in SCD Citation Number: Z00045
Chemical Class: Carbide
Chemical Family: Si-C
Formula: SiC
Informal Name: silicon carbide
Structure Type: Polycrystalline
Manufacturer: Carborundum Company
Commercial Name: KX-01
Process: Sintering

SiC

Material number 4 of 7
in SCD Citation Number: Z00045
Phase Composition
Phase
 
( no unit )
SiC
Si
Measurement Method: Reported Formula
Evaluation Status: Unevaluated

SiC

Material number 4 of 7
in SCD Citation Number: Z00045
Elemental Composition
Amount of
Element
( formula units )
Element
 
( no unit )
1 Si
1 C
Measurement Method: Reported Formula
Evaluation Status: Unevaluated

SiC

Material number 4 of 7
in SCD Citation Number: Z00045
Flexural Strength
Temperature
 
( °C )
Corrosion
Time
( h )
Flexural
Strength
( MPa )
22 0 431 ± 61
22 40 206 ± 94
Measurement Method: Four-point bend test
Evaluation Status: Evaluated by acceptance criteria

Material Specification and Properties for Si3N4

Material number 5 of 7
in SCD Citation Number: Z00045
Chemical Class: Nitride
Chemical Family: Si-N
Formula: Si3N4
Informal Name: silicon nitride
Structure Type: Polycrystalline
Manufacturer: GTE
Commercial Name: AY6
Process: Sintering

Si3N4

Material number 5 of 7
in SCD Citation Number: Z00045
Elemental Composition
Amount of
Element
( formula units )
Element
 
( no unit )
3 Si
4 N
Measurement Method: Reported Formula
Evaluation Status: Unevaluated

Si3N4

Material number 5 of 7
in SCD Citation Number: Z00045
Flexural Strength
Temperature
 
( °C )
Corrosion
Time
( h )
Flexural
Strength
( MPa )
22 0 668 ± 36
22 40 509 ± 78
Measurement Method: Four-point bend test
Evaluation Status: Evaluated by acceptance criteria

Material Specification and Properties for Si3N4

Material number 6 of 7
in SCD Citation Number: Z00045
Chemical Class: Nitride
Chemical Family: Si-N
Formula: Si3N4
Informal Name: silicon nitride
Manufacturer: Toshiba
Commercial Name: SSN
Process:

Si3N4

Material number 6 of 7
in SCD Citation Number: Z00045
Elemental Composition
Amount of
Element
( formula units )
Element
 
( no unit )
3 Si
4 N
Measurement Method: Reported Formula
Evaluation Status: Unevaluated

Si3N4

Material number 6 of 7
in SCD Citation Number: Z00045
Flexural Strength
Temperature
 
( °C )
Corrosion
Time
( h )
Flexural
Strength
( MPa )
22 0 872 ± 67
22 40 627 ± 103

Measurement Method: Four-point bend test
Evaluation Status: Evaluated by acceptance criteria

Material Specification and Properties for Si3N4

Material number 7 of 7
in SCD Citation Number: Z00045
Chemical Class: Nitride
Chemical Family: Si-N
Formula: Si3N4
Informal Name: silicon nitride
Manufacturer: NGK
Commercial Name: SN50 SSN
Process:

Si3N4

Material number 7 of 7
in SCD Citation Number: Z00045
Elemental Composition
Amount of
Element
( formula units )
Element
 
( no unit )
3 Si
4 N
Measurement Method: Reported Formula
Evaluation Status: Unevaluated

Si3N4

Material number 7 of 7
in SCD Citation Number: Z00045
Flexural Strength
Temperature
 
( °C )
Corrosion
Time
( h )
Flexural
Strength
( MPa )
22 0 814 ± 55
22 40 547 ± 116

Measurement Method: Four-point bend test
Evaluation Status: Evaluated by acceptance criteria