NIST Structural Ceramics Database (SCD) Database

NIST Standard Reference Database 30

Last Update to Data Content: 2002

DOI: http://dx.doi.org/10.18434/T4F30D


SCD Citation Number: Z00160

Bibliographic Information

Reference:
"Thermal Expansion Behavior of Single-Crystal Zirconia," J.W. Adams, H.H. Nakamura, R.P. Ingel, and R.W. Rice, Journal of the American Ceramic Society, Vol. 68 [9], pp. C-228-C-231 (1985), published by American Ceramic Society.
Language: English

General Materials Processing Notes

The authors cite V.I. Aleksandrov et al.; pp. 421-480 in Current Topics in Material Science, Vol. 1, Edited by E. Kaldis, North-Holland Publishing, Amsterdam (1978), and summarize the procedure as follows. "The single crystals of both fully and partially stabilized ZrO2 were produced by directional solidification from the melt, known as skull melting."

Measurement Methods

Dilatometry
"Expansion samples consisted of single crystals of irregular cross-section dimensions (nominally 7-mm diameter) and (about) 26 mm long. Sample ends were ground flat and parallel and the thermal expansion was measured in the crystal growth direction, i.e., the cubic <110> direction. Samples which were shorter than 26 mm were stacked end to end in the test cell. Samples were cycled in air from room temperature to 1500 °C at 1 °C/min to minimize thermal delay effects in these low-conductivity samples. The linear coefficient of thermal expansion was derived from a continuous recording of the sample length throughout the heating and cooling cycles using a precision LVDT system with 0.1 µm resolution."

Index of Materials and Properties (Click on a selected Material Number to expand material properties menu)

Material Specification and Properties for ZrO2·xY2O3

Material number 1 of 3
in SCD Citation Number: Z00160
Chemical Class: Oxide
Chemical Family: Zr-O:Y2O3
Formula: ZrO2·xY2O3
Informal Name: zirconia (PSZ)
Structure Type: Single Crystal
Manufacturer: In-House
Process: Crystal Growth

ZrO2·xY2O3

Material number 1 of 3
in SCD Citation Number: Z00160
Elemental Composition
Amount of
Element
( formula units )
Element
 
( no unit )
1 Zr
2 O
Measurement Method: Reported Formula
Evaluation Status: Unevaluated

ZrO2·xY2O3

Material number 1 of 3
in SCD Citation Number: Z00160
Sintering Aids
Sintering Aid
 
( no unit )
Y2O3
Measurement Method: Reported Formula
Evaluation Status: Unevaluated

ZrO2·xY2O3

Material number 1 of 3
in SCD Citation Number: Z00160
Thermal Expansion
Temperature
Range
( °C )
Mass Fraction
of Dopant
( % )
Dopant
 
 
Thermal
Expansion
( 10-6 K-1 )
640-1500 3 Y2O3 9.33
560-1500 4 Y2O3 11.38
20-1500 5 Y2O3 10.99
20-1500 6 Y2O3 10.68
20-1500 7 Y2O3 10.69
20-1500 8 Y2O3 10.92
20-1500 12 Y2O3 10.23
20-1500 20 Y2O3 11.08
20-1170 -- none 8.66
20-1180 -- none 8.12
1190-1500 -- none 9.93
1190-1500 -- none 10.04
Measurement Method: Dilatometry
Evaluation Status: Evaluated by acceptance criteria

Material Specification and Properties for ZrO2·xMgO

Material number 2 of 3
in SCD Citation Number: Z00160
Chemical Class: Oxide
Chemical Family: Zr-O:MgO
Formula: ZrO2·xMgO
Informal Name: zirconia (PSZ)
Structure Type: Single Crystal
Manufacturer: In-House
Process: Crystal Growth

ZrO2·xMgO

Material number 2 of 3
in SCD Citation Number: Z00160
Elemental Composition
Amount of
Element
( formula units )
Element
 
( no unit )
1 Zr
2 O
Measurement Method: Reported Formula
Evaluation Status: Unevaluated

ZrO2·xMgO

Material number 2 of 3
in SCD Citation Number: Z00160
Sintering Aids
Sintering Aid
 
( no unit )
MgO
Measurement Method: Reported Formula
Evaluation Status: Unevaluated

ZrO2·xMgO

Material number 2 of 3
in SCD Citation Number: Z00160
Thermal Expansion
Temperature
Range
( °C )
Mass Fraction
of Dopant
( % )
Dopant
 
 
Thermal
Expansion
( 10-6 K-1 )
800-1500 2.8 MgO 10.18
Measurement Method: Dilatometry
Evaluation Status: Evaluated by acceptance criteria

Material Specification and Properties for ZrO2·xCaO

Material number 3 of 3
in SCD Citation Number: Z00160
Chemical Class: Oxide
Chemical Family: Zr-O:CaO
Formula: ZrO2·xCaO
Informal Name: zirconia (PSZ)
Structure Type: Single Crystal
Manufacturer: In-House
Process: Crystal Growth

ZrO2·xCaO

Material number 3 of 3
in SCD Citation Number: Z00160
Elemental Composition
Amount of
Element
( formula units )
Element
 
( no unit )
1 Zr
2 O
Measurement Method: Reported Formula
Evaluation Status: Unevaluated

ZrO2·xCaO

Material number 3 of 3
in SCD Citation Number: Z00160
Sintering Aids
Sintering Aid
 
( no unit )
CaO
Measurement Method: Reported Formula
Evaluation Status: Unevaluated

ZrO2·xCaO

Material number 3 of 3
in SCD Citation Number: Z00160
Thermal Expansion
Temperature
Range
( °C )
Mass Fraction
of Dopant
( % )
Dopant
 
 
Thermal
Expansion
( 10-6 K-1 )
20-1500 4 CaO 10.08
825-1500 4 CaO 11.05
1170-1500 4 CaO 13.44
Measurement Method: Dilatometry
Evaluation Status: Evaluated by acceptance criteria