NIST Structural Ceramics Database (SCD) Database

NIST Standard Reference Database 30

Last Update to Data Content: 2002

DOI: http://dx.doi.org/10.18434/T4F30D


SCD Citation Number: Z00592

Bibliographic Information

Reference:
"Hot Isostatic Pressing of TiB2-ZrO2(2 Mol % Y2O3) Composite Powders," Y. Muraoka, M. Yoshinaka, K. Hirota, and O. Yamaguchi, Materials Research Bulletin, Vol. 31 [7], pp. 787-792 (1996), published by Elsevier Science Ltd..
Language: English

General Materials Processing Notes

"Powders of ZrO2 containing 2 mol% Y2O2 (Sumitomo Osaka Cement Co., Ltd.) and TiB2 (Japan New Metals Co., Ltd.) were used as starting materials. The former was of high purity and had an average particle size of 0.023 µm. The average particle size of the latter was 1.75 µm. ... powders... were mixed for 20 h by wet ball milling with zirconia balls and ethanol in a polyethylene pot and then dried at 80 °C under pressure. Densification was performed by hot isostatic pressing (HIPing) under argon gas as the pressure transmitting medium. Before HIPing, the mixed powders without calcining were pressed into pellets at 196 MPa and then cold isostatically pressed at 392 MPa. The green compacts, covered with boron nitride powders, were sealed in a Pyrex glass tube under vacuum. HIPing conditions were as follows: heating rate of 400 °C/h; increasing pressure rate of = 180 MPa/h above 800 °C; and sintering for 2 h at 1500 °C under 196 MPa."

Measurement Methods

Archimedes' method
"Bulk densities, after lapping with a diamond powder, were measured by the Archimedes method."
Three-point bend test
"Test samples (3 mm x 3 mm x 20 mm) for mechanical measurements were cut from the composites with a diamond saw; then they were lapped with a diamond powder (nominal size 1 µm to 2 µm). ... Three-point bending strength was measured with a 16 mm span and a crosshead speed of 0.5 mm/min."
Vickers indentation
The authors cite K. Niihara et al., J. Am. Ceram. Soc., Vol. 67, C-13 (1984), and summarize the procedure as follows. "... fracture toughness (KIc) measurements were made by the microindentation technique with a 300 N load.

Index of Materials and Properties

Material Number 1: TiB2·xZrO2

Material Specification and Properties for TiB2·xZrO2

Material number 1 of 1
in SCD Citation Number: Z00592
Chemical Class: Boride
Chemical Family: Ti-B
Formula: TiB2·xZrO2
Informal Name: titanium diboride
Structure Type: Polycrystalline
Manufacturer: In-House
Process: Hot Isostatic Pressing

TiB2·xZrO2

Material number 1 of 1
in SCD Citation Number: Z00592
Density (mass)
Mole Fraction
of TiB2
( % )
Mole Fraction
of ZrO2 (2Y)
( % )
Relative
Density
( % )
Density
 
( g cm-3 )
100 0 97.6 4.41
90 10 98.1 4.61
80 20 98.6 4.79
70 30 98.4 4.93
60 40 96.4 4.97
50 50 94.1 4.98

Measurement Method: Archimedes' method
Evaluation Status: Evaluated by acceptance criteria

TiB2·xZrO2

Material number 1 of 1
in SCD Citation Number: Z00592
Flexural Strength
Mole Fraction
of ZrO2 (2Y)
( % )
Flexural
Strength
( MPa )
0 654
10 806
20 912
30 682
40 552
50 478

Measurement Method: Three-point bend test
Evaluation Status: Evaluated by acceptance criteria
Cautions:
Data were digitized from Fig. 3 of the reference.

TiB2·xZrO2

Material number 1 of 1
in SCD Citation Number: Z00592
Fracture Toughness
Mole Fraction
of ZrO2 (2Y)
( % )
Fracture
Toughness
( MPa m1/2 )
0 3.7
10 5.8
20 7.2
30 11.3
40 7.0
50 6.0

Measurement Method: Vickers indentation
Evaluation Status: Evaluated by acceptance criteria
Cautions:
Data were digitized from Fig. 3 of the reference.