NIST Standard Reference Database 30
Last Update to Data Content: 2002
"Elastic Properties and Microcracking Behavior of Particulate Titanium Diboride-Silicon Carbide Composites," M.J. Pan, P.A. Hoffman, D.J. Green, and J.R. Hellmann, Journal of the American Ceramic Society, Vol. 80 [3], pp. 692-698 (1997), published by American Ceramic Society.Language: English
"A 15 vol% TiB2/SiC composite, or Hexoloy ST (Carborundum Co., Niagara Falls, NY) (hereafter referred to as ST), was procured. According to the Carborundum Co., ST was pressureless sintered at temperatures betwen 1900 °C and 2200 °C in an argon atmosphere. ... In addition to ST, composite materials with different TiB2 volume fractions, namely 10, 15, 20, and 30 vol%, were hot pressed... These materials were hot pressed at 1978 °C and 17 MPa (2500 psi) for 2 h in an argon atmosphere. Single phase components of SiC and TiB2 were also obtained. ... Two different SiC monoliths were obtained: Hexoloy SA (Carborundum Co.) (referred to as SA), a pressureless sintered α-SiC, and a hot pressed SiC (referred to as HP-SiC). The processing parameters of SA were the same as those of ST and those of HP-SiC were consistent with the hot pressed composites. A hot pressed TiB2 was also obtained."
"Particle sizes were measured on a Zeiss interactive digital analysis system (ZIDAS) (Carl Zeiss Inc., Thornwood, NY)."Archimedes' method
"The density of candidate materials was measured at room temperature using Archimedes' technique. The theoretical densities for silicon carbide and titanium diboride, calculated from the JCPDS X-ray diffraction cards 29-1131 and 35-741, are 3.208 and 4.50 g/cm3, respectively. The theoretical densities of the composites were estimated by the rule-of-mixture based on the theoretical densities of the constituent materials. Subsequently, the porosity of each of the materials was determined from the difference between the measured and theoretical densities."Resonance method
"The Young's and shear moduli of the candidate materials were measured from room temperature to 1300 °C using a dynamic resonance method, as described in the ASTM standard (ASTM C1198-91)."
| VolumeFraction of TiB2 ( % ) |
Density ( g cm-3 ) |
|---|---|
| 0 | 3.16 |
| VolumeFraction of TiB2 ( % ) |
Temperature ( °C ) |
Elastic Modulus ( GPa ) |
|---|---|---|
| 0 | 25 | 430 |
| 0 | 100 | 429 |
| 0 | 200 | 427 |
| 0 | 300 | 425 |
| 0 | 400 | 425 |
| 0 | 500 | 424 |
| 0 | 600 | 424 |
| 0 | 700 | 422 |
| 0 | 800 | 417 |
| 0 | 900 | 415 |
| 0 | 1000 | 414 |
| 0 | 1100 | 414 |
| 0 | 1200 | 410 |
| 0 | 1300 | 409 |
The authors indicated that the values were corrected to zero porosity. Data were digitized from Fig. 4a of the reference.
| VolumeFraction of TiB2 ( % ) |
Component |
Grain Size ( µm ) |
|---|---|---|
| 0 | SiC | 5.9 |
| VolumeFraction of TiB2 ( % ) |
Porosity ( % ) |
|---|---|
| 0 | 1.6 |
| VolumeFraction of TiB2 ( % ) |
Temperature ( °C ) |
Shear Modulus ( GPa ) |
|---|---|---|
| 0 | 25 | 191 |
| 0 | 100 | 190 |
| 0 | 200 | 189 |
| 0 | 300 | 189 |
| 0 | 400 | 188 |
| 0 | 500 | 187 |
| 0 | 600 | 186 |
| 0 | 700 | 185 |
| 0 | 800 | 183 |
| 0 | 900 | 183 |
| 0 | 1000 | 182 |
| 0 | 1100 | 181 |
| 0 | 1200 | 180 |
| 0 | 1300 | 180 |
The authors indicated that the values were corrected to zero porosity. Data were digitized from Figs. 4b of the reference.
| VolumeFraction of TiB2 ( % ) |
Density ( g cm-3 ) |
|---|---|
| 15 | 3.36 |
| VolumeFraction of TiB2 ( % ) |
Temperature ( °C ) |
Elastic Modulus ( GPa ) |
|---|---|---|
| 15 | 25 | 413 |
| 15 | 100 | 412 |
| 15 | 200 | 410 |
| 15 | 300 | 408 |
| 15 | 400 | 407 |
| 15 | 500 | 404 |
| 15 | 600 | 402 |
| 15 | 700 | 399 |
| 15 | 800 | 396 |
| 15 | 900 | 394 |
| 15 | 1000 | 394 |
The authors indicated that the values were corrected to zero porosity. Data were digitized from Fig. 5a of the reference.
| VolumeFraction of TiB2 ( % ) |
Component |
Grain Size ( µm ) |
|---|---|---|
| 15 | SiC | 6.6 |
| 15 | TiB2 | 4.7 |
| VolumeFraction of TiB2 ( % ) |
Porosity ( % ) |
|---|---|
| 15 | 1.3 |
| VolumeFraction of TiB2 ( % ) |
Temperature ( °C ) |
Shear Modulus ( GPa ) |
|---|---|---|
| 15 | 25 | 186 |
| 15 | 100 | 186 |
| 15 | 200 | 185 |
| 15 | 300 | 184 |
| 15 | 400 | 183 |
| 15 | 500 | 182 |
| 15 | 600 | 181 |
| 15 | 700 | 180 |
| 15 | 800 | 178 |
| 15 | 900 | 178 |
| 15 | 1000 | 176 |
The authors indicated that the values were corrected to zero porosity. Data were digitized from Fig. 5b of the reference.
| VolumeFraction of TiB2 ( % ) |
Density ( g cm-3 ) |
|---|---|
| 0 | 3.19 |
| 10 | 3.18 |
| 15 | 3.31 |
| 20 | 3.43 |
| 30 | 3.59 |
| VolumeFraction of TiB2 ( % ) |
Temperature ( °C ) |
Elastic Modulus ( GPa ) |
|---|---|---|
| 0 | 25 | 440 |
| 0 | 100 | 438 |
| 0 | 200 | 434 |
| 0 | 300 | 433 |
| 0 | 400 | 431 |
| 0 | 500 | 428 |
| 0 | 600 | 426 |
| 0 | 700 | 422 |
| 0 | 800 | 419 |
| 0 | 900 | 415 |
| 0 | 1000 | 410 |
| 10 | 25 | 440 |
| 10 | 100 | 439 |
| 10 | 200 | 437 |
| 10 | 300 | 435 |
| 10 | 400 | 432 |
| 10 | 500 | 430 |
| 10 | 600 | 427 |
| 10 | 700 | 423 |
| 10 | 800 | 420 |
| 10 | 900 | 414 |
| 10 | 1000 | 412 |
| 15 | 25 | 457 |
| 15 | 100 | 454 |
| 15 | 200 | 454 |
| 15 | 300 | 451 |
| 15 | 400 | 449 |
| 15 | 500 | 446 |
| 15 | 600 | 443 |
| 15 | 700 | 441 |
| 15 | 800 | 438 |
| 15 | 900 | 434 |
| 15 | 1000 | 431 |
| 20 | 25 | 471 |
| 20 | 100 | 470 |
| 20 | 200 | 467 |
| 20 | 300 | 463 |
| 20 | 400 | 460 |
| 20 | 500 | 457 |
| 20 | 600 | 453 |
| 20 | 700 | 450 |
| 20 | 800 | 446 |
| 20 | 900 | 441 |
| 20 | 1000 | 438 |
| 30 | 25 | 472 |
| 30 | 100 | 470 |
| 30 | 200 | 470 |
| 30 | 300 | 466 |
| 30 | 400 | 462 |
| 30 | 500 | 459 |
| 30 | 600 | 456 |
| 30 | 700 | 453 |
| 30 | 800 | 450 |
| 30 | 900 | 441 |
| 30 | 1000 | 435 |
The authors indicated that the values were corrected to zero porosity. Data were digitized from Figs. 4a and 5a of the reference.
| VolumeFraction of TiB2 ( % ) |
Component |
Grain Size ( µm ) |
|---|---|---|
| 0 | SiC | 3.2 |
| 10 | SiC | 4.4 |
| 15 | SiC | 4.3 |
| 20 | SiC | 3.7 |
| 30 | SiC | 3.8 |
| 10 | TiB2 | 3.5 |
| 15 | TiB2 | 3.8 |
| 20 | TiB2 | 3.3 |
| 30 | TiB2 | 5.2 |
| VolumeFraction of TiB2 ( % ) |
Porosity ( % ) |
|---|---|
| 0 | 0.4 |
| 10 | 4.8 |
| 15 | 2.8 |
| 20 | 1.2 |
| 30 | 0.4 |
| VolumeFraction of TiB2 ( % ) |
Temperature ( °C ) |
Shear Modulus ( GPa ) |
|---|---|---|
| 0 | 25 | 196 |
| 0 | 100 | 194 |
| 0 | 200 | 191 |
| 0 | 300 | 191 |
| 0 | 400 | 189 |
| 0 | 500 | 189 |
| 0 | 600 | 188 |
| 0 | 700 | 187 |
| 0 | 800 | 185 |
| 0 | 900 | 183 |
| 0 | 1000 | 182 |
| 10 | 25 | 197 |
| 10 | 100 | 197 |
| 10 | 200 | 196 |
| 10 | 300 | 194 |
| 10 | 400 | 193 |
| 10 | 500 | 193 |
| 10 | 600 | 191 |
| 10 | 700 | 190 |
| 10 | 800 | 188 |
| 10 | 900 | 186 |
| 10 | 1000 | 185 |
| 15 | 25 | 203 |
| 15 | 100 | 203 |
| 15 | 200 | 202 |
| 15 | 300 | 201 |
| 15 | 400 | 199 |
| 15 | 500 | 198 |
| 15 | 600 | 197 |
| 15 | 700 | 195 |
| 15 | 800 | 194 |
| 15 | 900 | 191 |
| 15 | 1000 | 191 |
| 20 | 25 | 210 |
| 20 | 100 | 209 |
| 20 | 200 | 207 |
| 20 | 300 | 206 |
| 20 | 400 | 206 |
| 20 | 500 | 203 |
| 20 | 600 | 203 |
| 20 | 700 | 202 |
| 20 | 800 | 199 |
| 20 | 900 | 196 |
| 20 | 1000 | 195 |
| 30 | 25 | 210 |
| 30 | 100 | 209 |
| 30 | 200 | 207 |
| 30 | 300 | 207 |
| 30 | 400 | 206 |
| 30 | 500 | 205 |
| 30 | 600 | 204 |
| 30 | 700 | 204 |
| 30 | 800 | 202 |
| 30 | 900 | 200 |
| 30 | 1000 | 199 |
The authors indicated that the values were corrected to zero porosity. Data were digitized from Fig. 4b and 5b of the reference.
| VolumeFraction of TiB2 ( % ) |
Density ( g cm-3 ) |
|---|---|
| 100 | 4.45 |
| VolumeFraction of TiB2 ( % ) |
Temperature ( °C ) |
Elastic Modulus ( GPa ) |
|---|---|---|
| 100 | 25 | 568 |
| 100 | 100 | 566 |
| 100 | 200 | 561 |
| 100 | 300 | 555 |
| 100 | 400 | 552 |
| 100 | 500 | 545 |
| 100 | 600 | 539 |
| 100 | 700 | 536 |
| 100 | 800 | 530 |
| 100 | 900 | 525 |
| 100 | 1000 | 519 |
The authors indicated that the values were corrected to zero porosity. Data were digitized from Fig. 4a of the reference.
| VolumeFraction of TiB2 ( % ) |
Component |
Grain Size ( µm ) |
|---|---|---|
| 100 | TiB2 | 6.6 |
| VolumeFraction of TiB2 ( % ) |
Porosity ( % ) |
|---|---|
| 100 | 1.0 |
| VolumeFraction of TiB2 ( % ) |
Temperature ( °C ) |
Shear Modulus ( GPa ) |
|---|---|---|
| 100 | 25 | 259 |
| 100 | 100 | 258 |
| 100 | 200 | 257 |
| 100 | 300 | 255 |
| 100 | 400 | 254 |
| 100 | 500 | 253 |
| 100 | 600 | 250 |
| 100 | 700 | 250 |
| 100 | 800 | 249 |
| 100 | 900 | 246 |
| 100 | 1000 | 245 |
The authors indicated that the values were corrected to zero porosity. Data were digitized from Fig. 4b of the reference.