NIST Structural Ceramics Database (SCD) Database

NIST Standard Reference Database 30

Last Update to Data Content: 2002

DOI: http://dx.doi.org/10.18434/T4F30D


SCD Citation Number: Z00595

Bibliographic Information

Reference:
"Elastic Properties and Microcracking Behavior of Particulate Titanium Diboride-Silicon Carbide Composites," M.J. Pan, P.A. Hoffman, D.J. Green, and J.R. Hellmann, Journal of the American Ceramic Society, Vol. 80 [3], pp. 692-698 (1997), published by American Ceramic Society.
Language: English

General Materials Processing Notes

"A 15 vol% TiB2/SiC composite, or Hexoloy ST (Carborundum Co., Niagara Falls, NY) (hereafter referred to as ST), was procured. According to the Carborundum Co., ST was pressureless sintered at temperatures betwen 1900 °C and 2200 °C in an argon atmosphere. ... In addition to ST, composite materials with different TiB2 volume fractions, namely 10, 15, 20, and 30 vol%, were hot pressed... These materials were hot pressed at 1978 °C and 17 MPa (2500 psi) for 2 h in an argon atmosphere. Single phase components of SiC and TiB2 were also obtained. ... Two different SiC monoliths were obtained: Hexoloy SA (Carborundum Co.) (referred to as SA), a pressureless sintered α-SiC, and a hot pressed SiC (referred to as HP-SiC). The processing parameters of SA were the same as those of ST and those of HP-SiC were consistent with the hot pressed composites. A hot pressed TiB2 was also obtained."

Measurement Methods

Optical microscopy
"Particle sizes were measured on a Zeiss interactive digital analysis system (ZIDAS) (Carl Zeiss Inc., Thornwood, NY)."
Archimedes' method
"The density of candidate materials was measured at room temperature using Archimedes' technique. The theoretical densities for silicon carbide and titanium diboride, calculated from the JCPDS X-ray diffraction cards 29-1131 and 35-741, are 3.208 and 4.50 g/cm3, respectively. The theoretical densities of the composites were estimated by the rule-of-mixture based on the theoretical densities of the constituent materials. Subsequently, the porosity of each of the materials was determined from the difference between the measured and theoretical densities."
Resonance method
"The Young's and shear moduli of the candidate materials were measured from room temperature to 1300 °C using a dynamic resonance method, as described in the ASTM standard (ASTM C1198-91)."

Index of Materials and Properties (Click on a selected Material Number to expand material properties menu)

Material Specification and Properties for SiC

Material number 1 of 4
in SCD Citation Number: Z00595
Chemical Class: Carbide
Chemical Family: Si-C
Formula: SiC
Informal Name: silicon carbide
Structure Type: Polycrystalline
Manufacturer: Carborundum Company
Commercial Name: Hexoloy SA
Process: Sintering

SiC

Material number 1 of 4
in SCD Citation Number: Z00595
Density (mass)
VolumeFraction
of TiB2
( % )
Density
 
( g cm-3 )
0 3.16
Measurement Method: Archimedes' method
Evaluation Status: Evaluated by acceptance criteria

SiC

Material number 1 of 4
in SCD Citation Number: Z00595
Elastic Modulus
VolumeFraction
of TiB2
( % )
Temperature
 
( °C )
Elastic
Modulus
( GPa )
0 25 430
0 100 429
0 200 427
0 300 425
0 400 425
0 500 424
0 600 424
0 700 422
0 800 417
0 900 415
0 1000 414
0 1100 414
0 1200 410
0 1300 409
Measurement Method: Resonance method
Evaluation Status: Evaluated by acceptance criteria
Cautions:
The authors indicated that the values were corrected to zero porosity. Data were digitized from Fig. 4a of the reference.

SiC

Material number 1 of 4
in SCD Citation Number: Z00595
Grain Size
VolumeFraction
of TiB2
( % )
Component
 
 
Grain Size
 
( µm )
0 SiC 5.9
Measurement Method: Optical microscopy
Evaluation Status: Evaluated by acceptance criteria

SiC

Material number 1 of 4
in SCD Citation Number: Z00595
Porosity
VolumeFraction
of TiB2
( % )
Porosity
 
( % )
0 1.6
Measurement Method: Archimedes' method
Evaluation Status: Evaluated by acceptance criteria

SiC

Material number 1 of 4
in SCD Citation Number: Z00595
Shear Modulus
VolumeFraction
of TiB2
( % )
Temperature
 
( °C )
Shear
Modulus
( GPa )
0 25 191
0 100 190
0 200 189
0 300 189
0 400 188
0 500 187
0 600 186
0 700 185
0 800 183
0 900 183
0 1000 182
0 1100 181
0 1200 180
0 1300 180
Measurement Method: Resonance method
Evaluation Status: Evaluated by acceptance criteria Cautions:
The authors indicated that the values were corrected to zero porosity. Data were digitized from Figs. 4b of the reference.

Material Specification and Properties for SiC·xTiB2

Material number 2 of 4
in SCD Citation Number: Z00595
Chemical Class: Carbide
Chemical Family: Si-C:TiB2
Formula: SiC·xTiB2
Informal Name: silicon carbide composite
Structure Type: Polycrystalline
Manufacturer: Carborundum Company
Commercial Name: Hexoloy ST
Process: Sintering

SiC·xTiB2

Material number 2 of 4
in SCD Citation Number: Z00595
Density (mass)
VolumeFraction
of TiB2
( % )
Density
 
( g cm-3 )
15 3.36
Measurement Method: Archimedes' method
Evaluation Status: Evaluated by acceptance criteria

SiC·xTiB2

Material number 2 of 4
in SCD Citation Number: Z00595
Elastic Modulus
VolumeFraction
of TiB2
( % )
Temperature
 
( °C )
Elastic
Modulus
( GPa )
15 25 413
15 100 412
15 200 410
15 300 408
15 400 407
15 500 404
15 600 402
15 700 399
15 800 396
15 900 394
15 1000 394
Measurement Method: Resonance method
Evaluation Status: Evaluated by acceptance criteria
Cautions:
The authors indicated that the values were corrected to zero porosity. Data were digitized from Fig. 5a of the reference.

SiC·xTiB2

Material number 2 of 4
in SCD Citation Number: Z00595
Grain Size
VolumeFraction
of TiB2
( % )
Component
 
 
Grain Size
 
( µm )
15 SiC 6.6
15 TiB2 4.7
Measurement Method: Optical microscopy
Evaluation Status: Evaluated by acceptance criteria

SiC·xTiB2

Material number 2 of 4
in SCD Citation Number: Z00595
Porosity
VolumeFraction
of TiB2
( % )
Porosity
 
( % )
15 1.3
Measurement Method: Archimedes' method
Evaluation Status: Evaluated by acceptance criteria

SiC·xTiB2

Material number 2 of 4
in SCD Citation Number: Z00595
Shear Modulus
VolumeFraction
of TiB2
( % )
Temperature
 
( °C )
Shear
Modulus
( GPa )
15 25 186
15 100 186
15 200 185
15 300 184
15 400 183
15 500 182
15 600 181
15 700 180
15 800 178
15 900 178
15 1000 176
Measurement Method: Resonance method
Evaluation Status: Evaluated by acceptance criteria
Cautions:
The authors indicated that the values were corrected to zero porosity. Data were digitized from Fig. 5b of the reference.

Material Specification and Properties for SiC·xTiB2

Material number 3 of 4
in SCD Citation Number: Z00595
Chemical Class: Carbide
Chemical Family: Si-C:TiB2
Formula: SiC·xTiB2
Informal Name: silicon carbide composite
Structure Type: Polycrystalline
Manufacturer: In-House
Process: Hot Pressing

SiC·xTiB2

Material number 3 of 4
in SCD Citation Number: Z00595
Density (mass)
VolumeFraction
of TiB2
( % )
Density
 
( g cm-3 )
0 3.19
10 3.18
15 3.31
20 3.43
30 3.59
Measurement Method: Archimedes' method
Evaluation Status: Evaluated by acceptance criteria

SiC·xTiB2

Material number 3 of 4
in SCD Citation Number: Z00595
Elastic Modulus
VolumeFraction
of TiB2
( % )
Temperature
 
( °C )
Elastic
Modulus
( GPa )
0 25 440
0 100 438
0 200 434
0 300 433
0 400 431
0 500 428
0 600 426
0 700 422
0 800 419
0 900 415
0 1000 410
10 25 440
10 100 439
10 200 437
10 300 435
10 400 432
10 500 430
10 600 427
10 700 423
10 800 420
10 900 414
10 1000 412
15 25 457
15 100 454
15 200 454
15 300 451
15 400 449
15 500 446
15 600 443
15 700 441
15 800 438
15 900 434
15 1000 431
20 25 471
20 100 470
20 200 467
20 300 463
20 400 460
20 500 457
20 600 453
20 700 450
20 800 446
20 900 441
20 1000 438
30 25 472
30 100 470
30 200 470
30 300 466
30 400 462
30 500 459
30 600 456
30 700 453
30 800 450
30 900 441
30 1000 435
Measurement Method: Resonance method
Evaluation Status: Evaluated by acceptance criteria
Cautions:
The authors indicated that the values were corrected to zero porosity. Data were digitized from Figs. 4a and 5a of the reference.

SiC·xTiB2

Material number 3 of 4
in SCD Citation Number: Z00595
Grain Size
VolumeFraction
of TiB2
( % )
Component
 
 
Grain Size
 
( µm )
0 SiC 3.2
10 SiC 4.4
15 SiC 4.3
20 SiC 3.7
30 SiC 3.8
10 TiB2 3.5
15 TiB2 3.8
20 TiB2 3.3
30 TiB2 5.2
Measurement Method: Optical microscopy
Evaluation Status: Evaluated by acceptance criteria

SiC·xTiB2

Material number 3 of 4
in SCD Citation Number: Z00595
Porosity
VolumeFraction
of TiB2
( % )
Porosity
 
( % )
0 0.4
10 4.8
15 2.8
20 1.2
30 0.4
Measurement Method: Archimedes' method
Evaluation Status: Evaluated by acceptance criteria

SiC·xTiB2

Material number 3 of 4
in SCD Citation Number: Z00595
Shear Modulus
VolumeFraction
of TiB2
( % )
Temperature
 
( °C )
Shear
Modulus
( GPa )
0 25 196
0 100 194
0 200 191
0 300 191
0 400 189
0 500 189
0 600 188
0 700 187
0 800 185
0 900 183
0 1000 182
10 25 197
10 100 197
10 200 196
10 300 194
10 400 193
10 500 193
10 600 191
10 700 190
10 800 188
10 900 186
10 1000 185
15 25 203
15 100 203
15 200 202
15 300 201
15 400 199
15 500 198
15 600 197
15 700 195
15 800 194
15 900 191
15 1000 191
20 25 210
20 100 209
20 200 207
20 300 206
20 400 206
20 500 203
20 600 203
20 700 202
20 800 199
20 900 196
20 1000 195
30 25 210
30 100 209
30 200 207
30 300 207
30 400 206
30 500 205
30 600 204
30 700 204
30 800 202
30 900 200
30 1000 199
Measurement Method: Resonance method
Evaluation Status: Evaluated by acceptance criteria
Cautions:
The authors indicated that the values were corrected to zero porosity. Data were digitized from Fig. 4b and 5b of the reference.

Material Specification and Properties for TiB2

Material number 4 of 4
in SCD Citation Number: Z00595
Chemical Class: Boride
Chemical Family: Ti-B
Formula: TiB2
Informal Name: titanium diboride
Structure Type: Polycrystalline
Manufacturer: In-House
Process: Hot Pressing

TiB2

Material number 4 of 4
in SCD Citation Number: Z00595
Density (mass)
VolumeFraction
of TiB2
( % )
Density
 
( g cm-3 )
100 4.45
Measurement Method: Archimedes' method
Evaluation Status: Evaluated by acceptance criteria

TiB2

Material number 4 of 4
in SCD Citation Number: Z00595
Elastic Modulus
VolumeFraction
of TiB2
( % )
Temperature
 
( °C )
Elastic
Modulus
( GPa )
100 25 568
100 100 566
100 200 561
100 300 555
100 400 552
100 500 545
100 600 539
100 700 536
100 800 530
100 900 525
100 1000 519
Measurement Method: Resonance method
Evaluation Status: Evaluated by acceptance criteria
Cautions:
The authors indicated that the values were corrected to zero porosity. Data were digitized from Fig. 4a of the reference.

TiB2

Material number 4 of 4
in SCD Citation Number: Z00595
Grain Size
VolumeFraction
of TiB2
( % )
Component
 
 
Grain Size
 
( µm )
100 TiB2 6.6
Measurement Method: Optical microscopy
Evaluation Status: Evaluated by acceptance criteria

TiB2

Material number 4 of 4
in SCD Citation Number: Z00595
Porosity
VolumeFraction
of TiB2
( % )
Porosity
 
( % )
100 1.0
Measurement Method: Archimedes' method
Evaluation Status: Evaluated by acceptance criteria

TiB2

Material number 4 of 4
in SCD Citation Number: Z00595
Shear Modulus
VolumeFraction
of TiB2
( % )
Temperature
 
( °C )
Shear
Modulus
( GPa )
100 25 259
100 100 258
100 200 257
100 300 255
100 400 254
100 500 253
100 600 250
100 700 250
100 800 249
100 900 246
100 1000 245

Measurement Method: Resonance method
Evaluation Status: Evaluated by acceptance criteria
Cautions:
The authors indicated that the values were corrected to zero porosity. Data were digitized from Fig. 4b of the reference.