NIST Structural Ceramics Database (SCD) Database

NIST Standard Reference Database 30

Last Update to Data Content: 2002

DOI: http://dx.doi.org/10.18434/T4F30D


SCD Citation Number: Z00618

Bibliographic Information

Reference:
"Effect of Load on the Hardness of Hot Isostatically Pressed Silicon Nitride," R. Berriche and R.T. Holt, Journal of the American Ceramic Society, Vol. 76 [6], pp. 1602-1604 (1993), published by American Ceramic Society.
Language: English

General Materials Processing Notes

SCD Citation Number: Z00618
"Specimens EB4, EB9, EB11, and EB14 were prepared by hot isostatic pressing (HIPing) silicon nitride powder (Grade LC 12, H. C. Starck, Inc., New York) at a temperature of 1950 °C and a pressure of 210 MPa. For the first two samples the holding time at the maximum temperature and pressure was a few minutes, whereas the hold period was 5 h for EB11 and EB14. ... NT154, a commercially HIPed silicon nitride was purchased in the form of finished bend test bars (Norton/TRW Ceramics, Worcester, MA)."
     ------------------------------------------------------------
     Material  Specimen    Mass Fractions   Relative Density
        #       Label      of Additives        (%)
        1        EB4        2% YO              81.8
        2        EB9        2% YO + 1% AO      84.0
        3        EB11       None               99.7
        4        EB14       2% YO + 1% AO      99.5
        5        NT154      4% YO              99.7
     ------------------
     Key to Table:
        YO = Y2O3
        AO = Al2O3
        Relative Density = d/dtheoretical
     ------------------------------------------------------------
 

Measurement Methods

Vickers indentation
"... specimens were mounted in bakelite, ground flat using 500 and 600 grit paper, and polished with diamond paste (5 µm, 1 µm, and 0.25 µm). The hardness measurements in the load range 1 N to 5 N were made with a microhardness tester (Leitz Wetzlar, Rockleigh, NJ) using a Vickers diamond indenter tip. Tests at higher loads were performed on a servohydraulic machine (MTS Systems Corp., Minneapolis, MN) using the same Vickers tip. Optical microscopy (OM) and scanning electron microscopy (SEM) were used to examine the indentation impressions.
                    Hv = 1854 P/d2
where P is the load in grams and d is the length of the diagonal in micrometers. ... Each of the data points represents an average of measurements from five tests at each load in the range 1 N to 5 N and three tests at each load for loads above 5 N."

Index of Materials and Properties (Click on a selected Material Number to expand material properties menu)

Material Specification and Properties for Si3N4

Material number 1 of 5
in SCD Citation Number: Z00618
Chemical Class: Nitride
Chemical Family: Si-N:Y2O3
Formula: Si3N4
Informal Name: silicon nitride
Structure Type: Polycrystalline
Manufacturer: In-House
Process: Hot Isostatic Pressing

Si3N4

Material number 1 of 5
in SCD Citation Number: Z00618
Hardness
Load
 
( N )
Diagonal
Length
( µm )
Hardness
 
( GPa )
1 17 6.6
2 24 6.8
3 29 6.6
5 38 6.4
50 140 5.1
100 190 5.3
150 230 5.6
200 --- 5.2
Measurement Method: Vickers indentation
Evaluation Status: Evaluated by acceptance criteria
Cautions:
Data were digitized from Figs. 1 and 2 of the reference.

Material Specification and Properties for Si3N4

Material number 2 of 5
in SCD Citation Number: Z00618
Chemical Class: Nitride
Chemical Family: Si-N:Al2O3,Y2O3
Formula: Si3N4
Informal Name: silicon nitride
Structure Type: Polycrystalline
Manufacturer: In-House
Process: Hot Isostatic Pressing

Si3N4

Material number 2 of 5
in SCD Citation Number: Z00618
Hardness
Load
 
( N )
Diagonal
Length
( µm )
Hardness
 
( GPa )
1 13 11.9
2 20 10.0
3 25 9.0
5 32 9.6
50 110 7.5
100 160 7.6
150 200 7.5
200 230 7.6
Measurement Method: Vickers indentation
Evaluation Status: Evaluated by acceptance criteria
Cautions:
Data were digitized from Figs. 1 and 2 of the reference.

Material Specification and Properties for Si3N4

Material number 3 of 5
in SCD Citation Number: Z00618
Chemical Class: Nitride
Chemical Family: Si-N
Formula: Si3N4
Informal Name: silicon nitride
Structure Type: Polycrystalline
Manufacturer: In-House
Process: Hot Isostatic Pressing

Si3N4

Material number 3 of 5
in SCD Citation Number: Z00618
Hardness
Load
 
( N )
Diagonal
Length
( µm )
Hardness
 
( GPa )
1 7.9 29.1
2 13 23.6
3 16 21.4
5 22 18.5
50 77 15.8
100 110 14.8
150 130 17.3
Measurement Method: Vickers indentation
Evaluation Status: Evaluated by acceptance criteria
Cautions:
Data were digitized from Figs. 1 and 2 of the reference.

Material Specification and Properties for Si3N4

Material number 4 of 5
in SCD Citation Number: Z00618
Chemical Class: Nitride
Chemical Family: Si-N:Al2O3,Y2O3
Formula: Si3N4
Informal Name: silicon nitride
Structure Type: Polycrystalline
Manufacturer: In-House
Process: Hot Isostatic Pressing

Si3N4

Material number 4 of 5
in SCD Citation Number: Z00618
Hardness
Load
 
( N )
Diagonal
Length
( µm )
Hardness
 
( GPa )
1 8.3 25.8
2 13 20.9
3 17 18.5
5 23 17.3
50 82 14.0
100 110 15.5
150 130 16.0
200 160 15.3
Measurement Method: Vickers indentation
Evaluation Status: Evaluated by acceptance criteria
Cautions:
Data were digitized from Figs. 1 and 2 of the reference.

Material Specification and Properties for Si3N4

Material number 5 of 5
in SCD Citation Number: Z00618
Chemical Class: Nitride
Chemical Family: Si-N:Y2O3
Formula: Si3N4
Informal Name: silicon nitride
Structure Type: Polycrystalline
Manufacturer: Norton/TRW
Commercial Name: NT-154
Process: Hot Isostatic Pressing

Si3N4

Material number 5 of 5
in SCD Citation Number: Z00618
Hardness
Load
 
( N )
Diagonal
Length
( µm )
Hardness
 
( GPa )
1 7.5 32.1
2 13 24.3
3 17 20.0
5 22 17.8
8.9 32 16.6
21 51 15.5
44 69 16.7
50 79 14.6
100 110 15.3
110 110 16.3
150 130 15.3
200 150 16.1
Measurement Method: Vickers indentation
Evaluation Status: Evaluated by acceptance criteria
Cautions:
Data were digitized from Figs. 1 and 2 of the reference.