NIST Standard Reference Database 30
Last Update to Data Content: 2002
"Thermal Expansion and Molar Volume of MgO, Periclase, from 5 K to 2900 K," R.R. Reeber, K. Goessel, and K. Wang, European Journal of Mineralogy, Vol. 7, pp. 1039-1047 (1995), published by E. Schweizerbart'sche Verlagsbuchhandlung.Language: English
"The MgO, a less than 325 mesh powder, was obtained from CERAC, Inc. (M-1017 lot X13427-3). Aluminum 0.01%, silicon 0.01% and zinc 0.02% were the principal impurities."
"The existing literature for periclase is evaluated within the constraints of the modified quasi-harmonic model (MQHM) and x-ray measurements at room temperature. At very high temperatures where experimental data is not available the MQHM provides a method to estimate high temperature thermal expansion."X-ray diffraction
"Additional Debye Scherrer x-ray determinations (11.46 cm diameter camera with calibrated knife edges) were carried out on as received high purity MgO samples (99.95%), which were sealed in thin walled glass ampoules immediately after a 950 °C anneal in air. ... Lattice parameters were measured with Cu Kα radiation lambda = 1.54050 Å and calculated with the self-consistent radius method (Reeber, 1970) and Cohen's least squares from the nine to eleven diffraction lines greater than theta equals 52°. Temperatures were monitored with a laboratory thermometer attached to the x-ray camera and varied less than 1.5 degrees during each exposure."
| Axis | Temperature ( K ) | Axis Length ( Å ) |
|---|---|---|
| a | 298 | 4.21154(30) |
"... annealing temperature, oxygen fugacity, trace impurities and moisture can significantly affect the lattice parameter."
| Temperature ( K ) | Molar Volume ( cm3/mol ) | Thermal Expansion ( 10-6 K-1 ) |
|---|---|---|
| 5 | 11.199 | 0 |
| 100 | 11.201 | 1.86 |
| 200 | 11.217 | 7.35 |
| 300 | 11.247 | 10.2 |
| 400 | 11.284 | 11.8 |
| 500 | 11.326 | 12.8 |
| 600 | 11.371 | 13.4 |
| 700 | 11.418 | 13.9 |
| 800 | 11.466 | 14.2 |
| 900 | 11.516 | 14.5 |
| 1000 | 11.566 | 14.6 |
| 1100 | 11.618 | 15.0 |
| 1200 | 11.671 | 15.5 |
| 1300 | 11.727 | 16.0 |
| 1400 | 11.784 | 16.4 |
| 1500 | 11.843 | 16.8 |
| 1600 | 11.904 | 17.2 |
| 1700 | 11.966 | 17.6 |
| 1800 | 12.030 | 18.0 |
| 1900 | 12.096 | 18.4 |
| 2000 | 12.163 | 18.7 |
| 2100 | 12.232 | 19.1 |
| 2200 | 12.303 | 19.4 |
| 2300 | 12.376 | 19.8 |
| 2400 | 12.450 | 20.1 |
| 2500 | 12.526 | 20.5 |
| 2600 | 12.604 | 20.8 |
| 2700 | 12.683 | 21.1 |
| 2800 | 12.765 | 21.5 |
| 2900 | 12.848 | 21.8 |
Values are given for the thermodynamic coefficient of thermal expansion, α = (1/L) (dL/dT), where L is the length dimension at temperature T.