NIST Structural Ceramics Database (SCD) Database

NIST Standard Reference Database 30

Last Update to Data Content: 2002

DOI: http://dx.doi.org/10.18434/T4F30D


SCD Citation Number: Z00631

Bibliographic Information

Reference:
"Thermal Expansion and Molar Volume of MgO, Periclase, from 5 K to 2900 K," R.R. Reeber, K. Goessel, and K. Wang, European Journal of Mineralogy, Vol. 7, pp. 1039-1047 (1995), published by E. Schweizerbart'sche Verlagsbuchhandlung.
Language: English

General Materials Processing Notes

"The MgO, a less than 325 mesh powder, was obtained from CERAC, Inc. (M-1017 lot X13427-3). Aluminum 0.01%, silicon 0.01% and zinc 0.02% were the principal impurities."

Measurement Methods

Analysis
"The existing literature for periclase is evaluated within the constraints of the modified quasi-harmonic model (MQHM) and x-ray measurements at room temperature. At very high temperatures where experimental data is not available the MQHM provides a method to estimate high temperature thermal expansion."
X-ray diffraction
"Additional Debye Scherrer x-ray determinations (11.46 cm diameter camera with calibrated knife edges) were carried out on as received high purity MgO samples (99.95%), which were sealed in thin walled glass ampoules immediately after a 950 °C anneal in air. ... Lattice parameters were measured with Cu Kα radiation lambda = 1.54050 Å and calculated with the self-consistent radius method (Reeber, 1970) and Cohen's least squares from the nine to eleven diffraction lines greater than theta equals 52°. Temperatures were monitored with a laboratory thermometer attached to the x-ray camera and varied less than 1.5 degrees during each exposure."

Index of Materials and Properties

Material Number 1: MgO

Material Specification and Properties for MgO

Material number 1 of 1
in SCD Citation Number: Z00631
Chemical Class: Oxide
Chemical Family: Mg-O
Formula: MgO
Informal Name: magnesia
Structure Type: Single Crystal
Manufacturer: Typical
Process: Crystal Growth

MgO

Material number 1 of 1
in SCD Citation Number: Z00631
Crystal Cell Axes
Axis
 
 
Temperature
 
( K )
Axis Length
 
( Å )
a 298 4.21154(30)

Measurement Method: X-ray diffraction
Evaluation Status: Evaluated by acceptance criteria
Cautions:
"... annealing temperature, oxygen fugacity, trace impurities and moisture can significantly affect the lattice parameter."

MgO

Material number 1 of 1
in SCD Citation Number: Z00631
Thermal Expansion
Temperature
 
( K )
Molar
Volume
( cm3/mol )
Thermal
Expansion
( 10-6 K-1 )
5 11.199 0
100 11.201 1.86
200 11.217 7.35
300 11.247 10.2
400 11.284 11.8
500 11.326 12.8
600 11.371 13.4
700 11.418 13.9
800 11.466 14.2
900 11.516 14.5
1000 11.566 14.6
1100 11.618 15.0
1200 11.671 15.5
1300 11.727 16.0
1400 11.784 16.4
1500 11.843 16.8
1600 11.904 17.2
1700 11.966 17.6
1800 12.030 18.0
1900 12.096 18.4
2000 12.163 18.7
2100 12.232 19.1
2200 12.303 19.4
2300 12.376 19.8
2400 12.450 20.1
2500 12.526 20.5
2600 12.604 20.8
2700 12.683 21.1
2800 12.765 21.5
2900 12.848 21.8

Measurement Method: Analysis
Evaluation Status: Evaluated by acceptance criteria
Cautions:
Values are given for the thermodynamic coefficient of thermal expansion, α = (1/L) (dL/dT), where L is the length dimension at temperature T.