NIST Standard Reference Database 30
Last Update to Data Content: 2002
"Physical Properties and Structure of Silica-Alumina-Europium Oxide Glasses," S. Tanabe, N. Soga, K. Hirao, and T. Hanada, Journal of the American Ceramic Society, Vol. 73 [6], pp. 1733-1736 (1990), published by American Ceramic Society.Language: English
"An image furnace apparatus... was used to obtain the glass samples. Reagent-grade powders of SiO2, Al2O3, and Eu2O3 were used to prepare batch compositions of 50SiO2·(50 - x)Al2O3·xEu2O3, where x is 10, 15, 18.75, 20, 25, 30, 35 and 40 mol%; the powders were thoroughly mixed in an alumina mortar for about 50 min, and the mixtures were pressed into sticks with a rubber press. A pressed compact was sintered at 1200 °C for 15 h and the sintered specimen was melted at the focus point of a biofocal gold mirror by a xenon lamp which was placed at the other focus point. The melt was quenched by a twin roller rotating at about 1000 rpm or air cooled on stainless steel to examine the glass-forming technology. ... an amorphous 50SiO2·50Al2O3 (x = 0) thin film was prepared by radio-frequency sputtering."
The authors cite T. Goto et al., Yogyo Kyokaishi, Vo1. 91, 34-41(1983), and summarize the procedure as follows. "After cutting the bulk sample precisely into a 3 mm cube, the sound velocities of shear and longitudinal waves were measured by the cube resonance technique."Archimedes' method
"The density p was measured by the Archimedes method using kerosine as a medium and silica glass as a standard. The molar volume was calculated by the measured density and the molar weight."
| Mole Fraction of Eu2O3 | Density ( g/cm3 ) | Bulk Modulus ( GPa ) |
|---|---|---|
| 0.15 | 3.89 | 90.2 |
| 0.19 | 4.16 | 89.6 |
| 0.20 | 4.35 | 93.7 |
| 0.25 | 4.59 | 94.6 |
| 0.30 | 5.02 | 98.6 |
Data were digitized from Fig. 6 of the reference.
| Mole Fraction of Eu2O3 | Molar Volume ( cm3/mol ) | Density ( g cm-3 ) |
|---|---|---|
| 0.10 | 30.1 | 3.52 |
| 0.15 | 30.8 | 3.89 |
| 0.19 | 31.0 | 4.16 |
| 0.20 | 30.4 | 4.35 |
| 0.25 | 31.3 | 4.59 |
| 0.30 | 31.2 | 5.02 |
| 0.35 | 31.5 | 5.39 |
Data were digitized from Figs. 3 and 10 of the reference.
| Mole Fraction of Eu2O3 | Density ( g/cm3 ) | Elastic Modulus ( GPa ) |
|---|---|---|
| 0.15 | 3.89 | 118 |
| 0.19 | 4.16 | 117 |
| 0.20 | 4.35 | 121 |
| 0.25 | 4.59 | 118 |
| 0.30 | 5.02 | 125 |
Data were digitized from Fig. 5 of the reference.
| Mode | Mole Fraction of Eu2O3 | Density ( g/cm3 ) | Sound Velocity ( km/s ) |
|---|---|---|---|
| Longitudinal | 0.15 | 3.89 | 6.26 |
| Longitudinal | 0.19 | 4.16 | 6.05 |
| Longitudinal | 0.20 | 4.35 | 6.05 |
| Longitudinal | 0.25 | 4.59 | 5.84 |
| Longitudinal | 0.30 | 5.02 | 5.71 |
| Shear | 0.15 | 3.89 | 3.47 |
| Shear | 0.19 | 4.16 | 3.34 |
| Shear | 0.20 | 4.35 | 3.32 |
| Shear | 0.25 | 4.59 | 3.16 |
| Shear | 0.30 | 5.02 | 3.11 |
Data were digitized from Fig. 4 of the reference.