NIST Structural Ceramics Database (SCD) Database

NIST Standard Reference Database 30

Last Update to Data Content: 2002

DOI: http://dx.doi.org/10.18434/T4F30D


SCD Citation Number: Z00721

Bibliographic Information

Reference:
"Physical Properties and Structure of Silica-Alumina-Europium Oxide Glasses," S. Tanabe, N. Soga, K. Hirao, and T. Hanada, Journal of the American Ceramic Society, Vol. 73 [6], pp. 1733-1736 (1990), published by American Ceramic Society.
Language: English

General Materials Processing Notes

"An image furnace apparatus... was used to obtain the glass samples. Reagent-grade powders of SiO2, Al2O3, and Eu2O3 were used to prepare batch compositions of 50SiO2·(50 - x)Al2O3·xEu2O3, where x is 10, 15, 18.75, 20, 25, 30, 35 and 40 mol%; the powders were thoroughly mixed in an alumina mortar for about 50 min, and the mixtures were pressed into sticks with a rubber press. A pressed compact was sintered at 1200 °C for 15 h and the sintered specimen was melted at the focus point of a biofocal gold mirror by a xenon lamp which was placed at the other focus point. The melt was quenched by a twin roller rotating at about 1000 rpm or air cooled on stainless steel to examine the glass-forming technology. ... an amorphous 50SiO2·50Al2O3 (x = 0) thin film was prepared by radio-frequency sputtering."

Measurement Methods

Resonance method
The authors cite T. Goto et al., Yogyo Kyokaishi, Vo1. 91, 34-41(1983), and summarize the procedure as follows. "After cutting the bulk sample precisely into a 3 mm cube, the sound velocities of shear and longitudinal waves were measured by the cube resonance technique."
Archimedes' method
"The density p was measured by the Archimedes method using kerosine as a medium and silica glass as a standard. The molar volume was calculated by the measured density and the molar weight."

Index of Materials and Properties

Material Number 1: 0.5SiO2·(0.5-x)Al2O3·xEu2O3

Material Specification and Properties for 0.5SiO2·(0.5-x)Al2O3·xEu2O3

Material number 1 of 1
in SCD Citation Number: Z00721
Chemical Class: Oxide
Chemical Family: Al-Si-O:Eu2O3
Formula: 0.5SiO2·(0.5-x)Al2O3·xEu2O3
Informal Name: silica composite
Structure Type: Noncrystalline
Manufacturer: In-House
Process: Melt Processing

0.5SiO2·(0.5-x)Al2O3·xEu2O3

Material number 1 of 1
in SCD Citation Number: Z00721
Bulk Modulus
Mole Fraction
of Eu2O3
 
Density
 
( g/cm3 )
Bulk
Modulus
( GPa )
0.15 3.89 90.2
0.19 4.16 89.6
0.20 4.35 93.7
0.25 4.59 94.6
0.30 5.02 98.6

Measurement Method: Resonance method
Evaluation Status: Qualified by acceptance criteria
Cautions:
Data were digitized from Fig. 6 of the reference.

0.5SiO2·(0.5-x)Al2O3·xEu2O3

Material number 1 of 1
in SCD Citation Number: Z00721
Density (mass)
Mole Fraction
of Eu2O3
 
Molar
Volume
( cm3/mol )
Density
 
( g cm-3 )
0.10 30.1 3.52
0.15 30.8 3.89
0.19 31.0 4.16
0.20 30.4 4.35
0.25 31.3 4.59
0.30 31.2 5.02
0.35 31.5 5.39

Measurement Method: Archimedes' method
Evaluation Status: Validated by models
Cautions:
Data were digitized from Figs. 3 and 10 of the reference.

0.5SiO2·(0.5-x)Al2O3·xEu2O3

Material number 1 of 1
in SCD Citation Number: Z00721
Elastic Modulus
Mole Fraction
of Eu2O3
 
Density
 
( g/cm3 )
Elastic
Modulus
( GPa )
0.15 3.89 118
0.19 4.16 117
0.20 4.35 121
0.25 4.59 118
0.30 5.02 125

Measurement Method: Resonance method
Evaluation Status: Qualified by acceptance criteria
Cautions:
Data were digitized from Fig. 5 of the reference.

0.5SiO2·(0.5-x)Al2O3·xEu2O3

Material number 1 of 1
in SCD Citation Number: Z00721
Sound Velocity
Mode
 
 
Mole Fraction
of Eu2O3
 
Density
 
( g/cm3 )
Sound
Velocity
( km/s )
Longitudinal 0.15 3.89 6.26
Longitudinal 0.19 4.16 6.05
Longitudinal 0.20 4.35 6.05
Longitudinal 0.25 4.59 5.84
Longitudinal 0.30 5.02 5.71
Shear 0.15 3.89 3.47
Shear 0.19 4.16 3.34
Shear 0.20 4.35 3.32
Shear 0.25 4.59 3.16
Shear 0.30 5.02 3.11

Measurement Method: Resonance method
Evaluation Status: Qualified by acceptance criteria
Cautions:
Data were digitized from Fig. 4 of the reference.