NIST Standard Reference Database 30
Last Update to Data Content: 2002
"The Heat Capacities of Yttrium Oxide (Y2O3), Lanthanum Oxide (La2O3) and Neodymium Oxide (Nd2O3) from 16 to 300°K," H.W. Goldstein, E.F. Neilson, P.N. Walsh, and D. White, Journal of Physical Chemistry, Vol. 63, pp. 1445-1449 (1959), published by American Chemical Society.Language: English
"The yttrium oxide, obtained from the Lindsay Chemical Company, West Chicago, Illinois, had a reported purity of greater than 99.9%. Analysis of the sample showed these impurities: Gd2O3, less than 0.01%; Dy2O3, less than 0.01%; and Ho2O3, less than 0.02%. A powder X-ray pattern of the heat treated material showed only the cubic Mn2O3 type, sesquioxide structure. The lanthanum oxide, obtained from the Lindsay Chemical Company, had a reported purity of 99.997%. Analysis of the sample showed only 1.5 p.p.m. of Fe2O3 as impurity. A powder X-ray pattern of the heat-treated material showed only the A-form sesquioxide structure. The neodymium oxide, obtained from the Lindsay Chemical Company, had a reported purity of 99.9%. Analysis of the sample showed as impurities: Pr6O11, less than 0.1%; Sm2O3, less than 0.1%. A powder X-ray pattern of the heat-treated material showed only the A-form sesquioxide structure."
The authors cite H.L. Johnston et al., Journal of the American Chemical Society, Vol. 72, 4733 (1950), and summarize the procedure as follows. "For all the rare earth heat capacity measurements, calorimeter "No. 3" was used. It is one of a group of seven calorimeters of identical design in use in this Laboratory. Although the calorimeter had been calibrated, previously over the temperature range 16 K to 300 K, the calibration was rechecked, before and after use, over the entire temperature range. Immediately before filling the calorimeter, the samples were heated to constant weight in a platinum dish at 950 K in air, to decompose any hydroxide or carbonate present. The transfer of the sample to the calorimeter was carried out in a dry box with a helium atmosphere. After the heat capacity measurements were completed the calorimeter was emptied in the dry box. Portions of the sample were taken from the top, middle and bottom of the calorimeter and heated to determine whether any contamination occurred during handling. In all cases these samples showed no weight change upon being heated for 24 hours at 950 K in air. ... The heat capacity measurements were made using 60.8680 g (0.26952 mole) of yttrium oxide, 98.9526 g (0.30368 mole) of lanthanum oxide and 97.9633 g (0.29109 mole) of neodymium oxide. The molecular weights were taken as 225.84, 325.84 and 336.54, respectively."
| Temperature ( K ) |
Molar Heat Capacity ( J mol-1 K-1 ) |
Specific Heat ( J kg-1 K-1 ) |
|---|---|---|
| 15.96 | 1.443 | 6.392 |
| 18.37 | 1.536 | 6.799 |
| 20.45 | 1.678 | 7.429 |
| 21.63 | 1.895 | 8.393 |
| 23.87 | 2.205 | 9.764 |
| 26.01 | 2.439 | 10.80 |
| 30.85 | 3.351 | 14.84 |
| 33.86 | 4.594 | 20.34 |
| 36.67 | 5.929 | 26.25 |
| 40.93 | 7.761 | 34.37 |
| 44.34 | 8.975 | 39.74 |
| 47.86 | 10.51 | 46.54 |
| 52.15 | 12.26 | 54.30 |
| 56.33 | 14.79 | 65.51 |
| 65.78 | 19.89 | 88.06 |
| 70.75 | 22.56 | 99.88 |
| 76.13 | 25.15 | 111.4 |
| 80.83 | 27.84 | 123.3 |
| 81.81 | 28.38 | 125.6 |
| 91.08 | 33.53 | 148.5 |
| 93.81 | 34.73 | 153.8 |
| 97.02 | 36.81 | 163.0 |
| 100.06 | 38.40 | 170.1 |
| 102.83 | 39.94 | 176.9 |
| 106.21 | 41.48 | 183.7 |
| 108.42 | 42.80 | 189.5 |
| 112.44 | 44.94 | 199.0 |
| 118.75 | 48.41 | 214.4 |
| 125.23 | 51.59 | 228.4 |
| 131.89 | 54.48 | 241.2 |
| 138.96 | 57.95 | 256.6 |
| 146.21 | 61.25 | 271.2 |
| 153.27 | 64.39 | 285.1 |
| 160.92 | 67.49 | 298.8 |
| 166.50 | 69.62 | 308.3 |
| 173.02 | 72.30 | 320.1 |
| 176.95 | 73.30 | 324.6 |
| 184.37 | 76.19 | 337.4 |
| 186.58 | 77.03 | 341.1 |
| 193.37 | 79.12 | 350.3 |
| 200.19 | 81.67 | 361.6 |
| 207.07 | 83.55 | 370.0 |
| 212.86 | 84.81 | 375.5 |
| 214.27 | 84.94 | 376.1 |
| 219.22 | 86.32 | 382.2 |
| 225.62 | 87.57 | 387.8 |
| 232.05 | 89.08 | 394.4 |
| 238.41 | 90.67 | 401.5 |
| 240.33 | 91.13 | 403.5 |
| 246.77 | 92.47 | 409.4 |
| 253.61 | 94.06 | 416.5 |
| 263.59 | 96.48 | 427.2 |
| 266.48 | 96.44 | 427.0 |
| 276.56 | 98.62 | 436.7 |
| 279.94 | 99.70 | 441.5 |
| 283.31 | 99.87 | 442.2 |
| 292.36 | 102.1 | 452.2 |
| 298.26 | 102.4 | 453.5 |
| Temperature ( K ) |
Molar Heat Capacity ( J mol-1 K-1 ) |
Specific Heat ( J kg-1 K-1 ) |
|---|---|---|
| 16.91 | 2.096 | 6.433 |
| 19.55 | 3.556 | 10.91 |
| 21.27 | 4.464 | 13.70 |
| 23.35 | 5.347 | 16.41 |
| 25.36 | 6.146 | 18.86 |
| 27.78 | 7.824 | 24.01 |
| 30.39 | 8.832 | 27.11 |
| 33.12 | 10.68 | 32.77 |
| 36.13 | 13.32 | 40.88 |
| 39.73 | 15.75 | 48.33 |
| 43.95 | 18.23 | 55.95 |
| 48.52 | 21.22 | 65.12 |
| 53.73 | 25.89 | 79.45 |
| 58.49 | 29.25 | 89.77 |
| 69.81 | 36.33 | 111.5 |
| 75.77 | 40.51 | 124.3 |
| 82.12 | 43.827 | 134.51 |
| 88.71 | 47.907 | 147.03 |
| 92.13 | 49.915 | 153.19 |
| 98.17 | 53.003 | 162.67 |
| 104.46 | 56.434 | 173.20 |
| 110.89 | 59.576 | 182.84 |
| 117.22 | 62.676 | 192.35 |
| 123.45 | 65.927 | 202.33 |
| 129.89 | 68.517 | 210.28 |
| 136.43 | 71.588 | 219.70 |
| 142.67 | 73.835 | 226.60 |
| 148.65 | 76.149 | 233.70 |
| 155.04 | 78.078 | 239.62 |
| 166.03 | 81.730 | 250.83 |
| 171.57 | 83.973 | 257.71 |
| 177.35 | 85.203 | 261.49 |
| 183.07 | 86.525 | 265.55 |
| 188.81 | 88.851 | 272.69 |
| 201.66 | 91.910 | 282.07 |
| 215.03 | 94.872 | 291.16 |
| 221.90 | 96.747 | 296.92 |
| 228.54 | 97.613 | 299.57 |
| 235.16 | 98.880 | 303.46 |
| 241.61 | 100.04 | 307.02 |
| 254.11 | 102.63 | 314.97 |
| 260.07 | 103.29 | 317.00 |
| 272.36 | 104.88 | 321.86 |
| 279.79 | 105.76 | 324.57 |
| 287.18 | 106.25 | 326.09 |
| 294.27 | 107.37 | 329.52 |
| 300.30 | 107.32 | 329.35 |
| Temperature ( K ) |
Molar Heat Capacity ( J mol-1 K-1 ) |
Specific Heat ( J kg-1 K-1 ) |
|---|---|---|
| 18.26 | 9.242 | 27.46 |
| 20.28 | 10.13 | 30.11 |
| 22.34 | 11.18 | 33.23 |
| 24.27 | 12.09 | 35.91 |
| 26.05 | 13.00 | 38.61 |
| 27.78 | 13.84 | 41.12 |
| 29.43 | 14.82 | 44.03 |
| 31.37 | 15.71 | 46.68 |
| 33.43 | 17.00 | 50.52 |
| 35.71 | 18.34 | 54.50 |
| 36.94 | 19.62 | 58.29 |
| 37.70 | 20.02 | 59.48 |
| 39.43 | 21.36 | 63.46 |
| 40.25 | 21.92 | 65.12 |
| 42.46 | 23.37 | 69.44 |
| 42.86 | 23.61 | 70.16 |
| 45.58 | 24.81 | 73.70 |
| 48.91 | 26.87 | 79.82 |
| 52.63 | 29.44 | 87.46 |
| 55.47 | 31.55 | 93.74 |
| 56.72 | 32.43 | 96.34 |
| 60.47 | 34.40 | 102.2 |
| 60.97 | 34.94 | 103.8 |
| 65.67 | 37.67 | 111.9 |
| 72.70 | 42.187 | 125.34 |
| 78.53 | 45.191 | 134.26 |
| 84.78 | 48.999 | 145.58 |
| 90.89 | 52.823 | 156.94 |
| 96.86 | 55.237 | 164.11 |
| 103.38 | 59.103 | 175.60 |
| 109.57 | 62.266 | 184.99 |
| 115.67 | 65.312 | 194.04 |
| 121.88 | 68.592 | 203.79 |
| 128.14 | 71.120 | 211.30 |
| 134.41 | 73.592 | 218.64 |
| 141.00 | 76.224 | 226.46 |
| 147.30 | 78.739 | 233.93 |
| 161.32 | 83.751 | 248.82 |
| 167.68 | 85.521 | 254.08 |
| 173.97 | 87.592 | 260.24 |
| 180.27 | 89.345 | 265.44 |
| 186.97 | 91.487 | 271.81 |
| 193.54 | 93.370 | 277.40 |
| 200.02 | 94.517 | 280.81 |
| 206.45 | 96.261 | 285.99 |
| 212.45 | 97.496 | 289.66 |
| 222.88 | 99.337 | 295.13 |
| 229.88 | 101.23 | 300.76 |
| 236.50 | 102.37 | 304.14 |
| 243.29 | 103.46 | 307.39 |
| 250.12 | 103.91 | 308.70 |
| 263.43 | 106.28 | 315.75 |
| 277.60 | 108.41 | 322.08 |
| 284.76 | 109.64 | 325.75 |
| 291.49 | 110.42 | 328.05 |
| 298.13 | 110.46 | 328.18 |