NIST Structural Ceramics Database (SCD) Database

NIST Standard Reference Database 30

Last Update to Data Content: 2002

DOI: http://dx.doi.org/10.18434/T4F30D


SCD Citation Number: Z00761

Bibliographic Information

Reference:
"The Heat Capacities of Yttrium Oxide (Y2O3), Lanthanum Oxide (La2O3) and Neodymium Oxide (Nd2O3) from 16 to 300°K," H.W. Goldstein, E.F. Neilson, P.N. Walsh, and D. White, Journal of Physical Chemistry, Vol. 63, pp. 1445-1449 (1959), published by American Chemical Society.
Language: English

General Materials Processing Notes

"The yttrium oxide, obtained from the Lindsay Chemical Company, West Chicago, Illinois, had a reported purity of greater than 99.9%. Analysis of the sample showed these impurities: Gd2O3, less than 0.01%; Dy2O3, less than 0.01%; and Ho2O3, less than 0.02%. A powder X-ray pattern of the heat treated material showed only the cubic Mn2O3 type, sesquioxide structure. The lanthanum oxide, obtained from the Lindsay Chemical Company, had a reported purity of 99.997%. Analysis of the sample showed only 1.5 p.p.m. of Fe2O3 as impurity. A powder X-ray pattern of the heat-treated material showed only the A-form sesquioxide structure. The neodymium oxide, obtained from the Lindsay Chemical Company, had a reported purity of 99.9%. Analysis of the sample showed as impurities: Pr6O11, less than 0.1%; Sm2O3, less than 0.1%. A powder X-ray pattern of the heat-treated material showed only the A-form sesquioxide structure."

Measurement Methods

Calorimetry
The authors cite H.L. Johnston et al., Journal of the American Chemical Society, Vol. 72, 4733 (1950), and summarize the procedure as follows. "For all the rare earth heat capacity measurements, calorimeter "No. 3" was used. It is one of a group of seven calorimeters of identical design in use in this Laboratory. Although the calorimeter had been calibrated, previously over the temperature range 16 K to 300 K, the calibration was rechecked, before and after use, over the entire temperature range. Immediately before filling the calorimeter, the samples were heated to constant weight in a platinum dish at 950 K in air, to decompose any hydroxide or carbonate present. The transfer of the sample to the calorimeter was carried out in a dry box with a helium atmosphere. After the heat capacity measurements were completed the calorimeter was emptied in the dry box. Portions of the sample were taken from the top, middle and bottom of the calorimeter and heated to determine whether any contamination occurred during handling. In all cases these samples showed no weight change upon being heated for 24 hours at 950 K in air. ... The heat capacity measurements were made using 60.8680 g (0.26952 mole) of yttrium oxide, 98.9526 g (0.30368 mole) of lanthanum oxide and 97.9633 g (0.29109 mole) of neodymium oxide. The molecular weights were taken as 225.84, 325.84 and 336.54, respectively."

Index of Materials and Properties (Click on a selected Material Number to expand material properties menu)

Material Specification and Properties for Y2O3

Material number 1 of 3
in SCD Citation Number: Z00761
Chemical Class: Oxide
Chemical Family: Y-O
Formula: Y2O3
Informal Name: yttria
Structure Type: Polycrystalline
Manufacturer: Lindsay Chemical Company
Process:

Y2O3

Material number 1 of 3
in SCD Citation Number: Z00761
Specific Heat
Temperature
 
( K )
Molar Heat
Capacity
( J mol-1 K-1 )
Specific
Heat
( J kg-1 K-1 )
15.96 1.443 6.392
18.37 1.536 6.799
20.45 1.678 7.429
21.63 1.895 8.393
23.87 2.205 9.764
26.01 2.439 10.80
30.85 3.351 14.84
33.86 4.594 20.34
36.67 5.929 26.25
40.93 7.761 34.37
44.34 8.975 39.74
47.86 10.51 46.54
52.15 12.26 54.30
56.33 14.79 65.51
65.78 19.89 88.06
70.75 22.56 99.88
76.13 25.15 111.4
80.83 27.84 123.3
81.81 28.38 125.6
91.08 33.53 148.5
93.81 34.73 153.8
97.02 36.81 163.0
100.06 38.40 170.1
102.83 39.94 176.9
106.21 41.48 183.7
108.42 42.80 189.5
112.44 44.94 199.0
118.75 48.41 214.4
125.23 51.59 228.4
131.89 54.48 241.2
138.96 57.95 256.6
146.21 61.25 271.2
153.27 64.39 285.1
160.92 67.49 298.8
166.50 69.62 308.3
173.02 72.30 320.1
176.95 73.30 324.6
184.37 76.19 337.4
186.58 77.03 341.1
193.37 79.12 350.3
200.19 81.67 361.6
207.07 83.55 370.0
212.86 84.81 375.5
214.27 84.94 376.1
219.22 86.32 382.2
225.62 87.57 387.8
232.05 89.08 394.4
238.41 90.67 401.5
240.33 91.13 403.5
246.77 92.47 409.4
253.61 94.06 416.5
263.59 96.48 427.2
266.48 96.44 427.0
276.56 98.62 436.7
279.94 99.70 441.5
283.31 99.87 442.2
292.36 102.1 452.2
298.26 102.4 453.5
Measurement Method: Calorimetry
Evaluation Status: Qualified by acceptance criteria

Material Specification and Properties for La2O3

Material number 2 of 3
in SCD Citation Number: Z00761
Chemical Class: Oxide
Chemical Family: La-O
Formula: La2O3
Informal Name: lanthanum oxide
Structure Type: Polycrystalline
Manufacturer: Lindsay Chemical Company
Process:

La2O3

Material number 2 of 3
in SCD Citation Number: Z00761
Specific Heat
Temperature
 
( K )
Molar Heat
Capacity
( J mol-1 K-1 )
Specific
Heat
( J kg-1 K-1 )
16.91 2.096 6.433
19.55 3.556 10.91
21.27 4.464 13.70
23.35 5.347 16.41
25.36 6.146 18.86
27.78 7.824 24.01
30.39 8.832 27.11
33.12 10.68 32.77
36.13 13.32 40.88
39.73 15.75 48.33
43.95 18.23 55.95
48.52 21.22 65.12
53.73 25.89 79.45
58.49 29.25 89.77
69.81 36.33 111.5
75.77 40.51 124.3
82.12 43.827 134.51
88.71 47.907 147.03
92.13 49.915 153.19
98.17 53.003 162.67
104.46 56.434 173.20
110.89 59.576 182.84
117.22 62.676 192.35
123.45 65.927 202.33
129.89 68.517 210.28
136.43 71.588 219.70
142.67 73.835 226.60
148.65 76.149 233.70
155.04 78.078 239.62
166.03 81.730 250.83
171.57 83.973 257.71
177.35 85.203 261.49
183.07 86.525 265.55
188.81 88.851 272.69
201.66 91.910 282.07
215.03 94.872 291.16
221.90 96.747 296.92
228.54 97.613 299.57
235.16 98.880 303.46
241.61 100.04 307.02
254.11 102.63 314.97
260.07 103.29 317.00
272.36 104.88 321.86
279.79 105.76 324.57
287.18 106.25 326.09
294.27 107.37 329.52
300.30 107.32 329.35

Measurement Method: Calorimetry
Evaluation Status: Qualified by acceptance criteria

Material Specification and Properties for Nd2O3

Material number 3 of 3
in SCD Citation Number: Z00761
Chemical Class: Oxide
Chemical Family: Nd-O
Formula: Nd2O3
Informal Name: neodymium oxide
Structure Type: Polycrystalline
Process:

Nd2O3

Material number 3 of 3
in SCD Citation Number: Z00761
Specific Heat
Temperature
 
( K )
Molar Heat
Capacity
( J mol-1 K-1 )
Specific
Heat
( J kg-1 K-1 )
18.26 9.242 27.46
20.28 10.13 30.11
22.34 11.18 33.23
24.27 12.09 35.91
26.05 13.00 38.61
27.78 13.84 41.12
29.43 14.82 44.03
31.37 15.71 46.68
33.43 17.00 50.52
35.71 18.34 54.50
36.94 19.62 58.29
37.70 20.02 59.48
39.43 21.36 63.46
40.25 21.92 65.12
42.46 23.37 69.44
42.86 23.61 70.16
45.58 24.81 73.70
48.91 26.87 79.82
52.63 29.44 87.46
55.47 31.55 93.74
56.72 32.43 96.34
60.47 34.40 102.2
60.97 34.94 103.8
65.67 37.67 111.9
72.70 42.187 125.34
78.53 45.191 134.26
84.78 48.999 145.58
90.89 52.823 156.94
96.86 55.237 164.11
103.38 59.103 175.60
109.57 62.266 184.99
115.67 65.312 194.04
121.88 68.592 203.79
128.14 71.120 211.30
134.41 73.592 218.64
141.00 76.224 226.46
147.30 78.739 233.93
161.32 83.751 248.82
167.68 85.521 254.08
173.97 87.592 260.24
180.27 89.345 265.44
186.97 91.487 271.81
193.54 93.370 277.40
200.02 94.517 280.81
206.45 96.261 285.99
212.45 97.496 289.66
222.88 99.337 295.13
229.88 101.23 300.76
236.50 102.37 304.14
243.29 103.46 307.39
250.12 103.91 308.70
263.43 106.28 315.75
277.60 108.41 322.08
284.76 109.64 325.75
291.49 110.42 328.05
298.13 110.46 328.18
Measurement Method: Calorimetry
Evaluation Status: Qualified by acceptance criteria