NIST Structural Ceramics Database (SCD) Database

NIST Standard Reference Database 30

Last Update to Data Content: 2002

DOI: http://dx.doi.org/10.18434/T4F30D


SCD Citation Number: Z00795

Bibliographic Information

Reference:
"High-Temperature Thermodynamic Properties of Some Refractory Borides," R. Mezaki, E.W. Tilleux, D.W. Barnes, and J.L. Margrave, Thermodynamics of Nuclear Materials, pp. 775-788 (1962), published by International Atomic Energy Agency, Vienna.
Language: English
Notes: Proceedings Series

General Materials Processing Notes

"The various samples studied were generously supplied by the American Potash and Chemical Company, the Carborundum Company and the Norton Company. Spectrographic analyses showed only trace impurities. In all cases, the samples were contained in pure gold containers and were X-rayed before and after the runs. No reactions were noted from a visual inspection and no new phases were apparent for the X-ray patterns. It should be realized, however, that probably 2% - 5% of a well-developed crystalline phase was the minimum needed for detection so that 1% - 2% of crystalline impurities or even larger amounts of amorphous impurities probably could not have been detected. Normal procedures included the weighing of the sample plus its container after each run so that changes due to leakage of air into the capsule and susbsequent oxidation or evaporation could be detected and were avoided in selection of the final data."

Measurement Methods

Calorimetry
The authors cite Grimley et al., J. Phys. Chem., Vol. 64, 1763 (1960), and summarize the procedure as follows. "The apparatus has been calibrated electrically and, in addition, samples of synthetic sapphire from the National Bureau of Standards have been run for comparison purposes. The accuracy of the calorimeter is ±0.5% while the reproducibility of a given measurement is slightly better. Several drops were also made with empty pure gold capsules at various temperatures since the heat content must be corrected for the containing capsule. ... Data for the calorimeter were processed on an IBM-650 (later a CDC-1604) computer... and the experimental data provided the smoothed thermodynamic functions..."

Index of Materials and Properties (Click on a selected Material Number to expand material properties menu)

Material Specification and Properties for BN

Material number 1 of 15
in SCD Citation Number: Z00795
Chemical Class: Nitride
Chemical Family: B-N
Formula: BN
Informal Name: boron nitride
Structure Type: Polycrystalline
Process:

BN

Material number 1 of 15
in SCD Citation Number: Z00795
Specific Heat
Temperature
 
( K )
Molar Heat
Capacity
( J mol-1 K-1 )
Specific
Heat
( J kg-1 K-1 )
298.16 12.3 497
300 12.7 513
400 25.4 1023
500 32.0 1291
600 36.4 1465
700 39.5 1591
800 42.09 1696
900 44.31 1785
1000 46.32 1866
1100 48.20 1942
1200 49.96 2013
Measurement Method: Calorimetry
Evaluation Status: Evaluated by acceptance criteria

Material Specification and Properties for CrB

Material number 2 of 15
in SCD Citation Number: Z00795
Chemical Class: Boride
Chemical Family: Cr-B
Formula: CrB
Informal Name: chromium boride
Structure Type: Polycrystalline
Process:

CrB

Material number 2 of 15
in SCD Citation Number: Z00795
Specific Heat
Temperature
 
( K )
Molar Heat
Capacity
( J mol-1 K-1 )
Specific
Heat
( J kg-1 K-1 )
298.16 35.90 571
300 36.0 574
400 42.51 677
500 46.36 738
600 49.20 783
700 51.55 821
800 53.60 853
900 55.52 884
1000 57.36 913
1100 59.12 941
1200 60.84 969
Measurement Method: Calorimetry
Evaluation Status: Evaluated by acceptance criteria

Material Specification and Properties for MoB

Material number 3 of 15
in SCD Citation Number: Z00795
Chemical Class: Boride
Chemical Family: Mo-B
Formula: MoB
Informal Name: molybdenum boride
Structure Type: Polycrystalline
Process:

MoB

Material number 3 of 15
in SCD Citation Number: Z00795
Specific Heat
Temperature
 
( K )
Molar Heat
Capacity
( J mol-1 K-1 )
Specific
Heat
( J kg-1 K-1 )
298.16 39.4 369
300 39.5 370
400 43.10 404
500 45.44 426
600 47.32 443
700 48.91 458
800 50.42 472
900 51.88 486
1000 53.26 499
1100 54.60 511
1200 55.94 524
Measurement Method: Calorimetry
Evaluation Status: Evaluated by acceptance criteria

Material Specification and Properties for TaB

Material number 4 of 15
in SCD Citation Number: Z00795
Chemical Class: Boride
Chemical Family: Ta-B
Formula: TaB
Informal Name: tantalum boride
Structure Type: Polycrystalline
Process:

TaB

Material number 4 of 15
in SCD Citation Number: Z00795
Specific Heat
Temperature
 
( K )
Molar Heat
Capacity
( J mol-1 K-1 )
Specific
Heat
( J kg-1 K-1 )
298.16 47.28 247
300 47.32 247
400 45.15 235
500 45.69 238
600 47.28 247
700 49.37 257
800 51.71 270
900 54.22 283
1000 56.82 296
1100 59.50 310
1200 62.22 324
Measurement Method: Calorimetry
Evaluation Status: Evaluated by acceptance criteria

Material Specification and Properties for WB

Material number 5 of 15
in SCD Citation Number: Z00795
Chemical Class: Boride
Chemical Family: W-B
Formula: WB
Informal Name: tungsten boride
Structure Type: Polycrystalline
Process:

WB

Material number 5 of 15
in SCD Citation Number: Z00795
Specific Heat
Temperature
 
( K )
Molar Heat
Capacity
( J mol-1 K-1 )
Specific
Heat
( J kg-1 K-1 )
298.16 33.5 172
300 33.8 174
400 43.68 224
500 48.07 247
600 50.33 259
700 51.55 265
800 52.26 268
900 52.59 270
1000 52.76 271
1100 52.84 271
1200 52.80 271
Measurement Method: Calorimetry
Evaluation Status: Evaluated by acceptance criteria

Material Specification and Properties for Mo2B

Material number 6 of 15
in SCD Citation Number: Z00795
Chemical Class: Boride
Chemical Family: Mo-B
Formula: Mo2B
Informal Name: dimolybdenum boride
Structure Type: Polycrystalline
Process:

Mo2B

Material number 6 of 15
in SCD Citation Number: Z00795
Specific Heat
Temperature
 
( K )
Molar Heat
Capacity
( J mol-1 K-1 )
Specific
Heat
( J kg-1 K-1 )
298.16 78.62 388
300 78.70 388
400 79.24 391
500 79.79 394
600 80.29 396
700 80.83 399
800 81.38 401
Measurement Method: Calorimetry
Evaluation Status: Evaluated by acceptance criteria

Material Specification and Properties for W2B

Material number 7 of 15
in SCD Citation Number: Z00795
Chemical Class: Boride
Chemical Family: W-B
Formula: W2B
Informal Name: ditungsten boride
Structure Type: Polycrystalline
Process:

W2B

Material number 7 of 15
in SCD Citation Number: Z00795
Specific Heat
Temperature
 
( K )
Molar Heat
Capacity
( J mol-1 K-1 )
Specific
Heat
( J kg-1 K-1 )
298.16 64.27 170
300 64.48 170
400 71.46 189
500 75.02 198
600 77.19 204
700 78.78 208
800 80.00 211
900 81.04 214
1000 81.96 217
1100 82.80 219
1200 83.60 221
Measurement Method: Calorimetry
Evaluation Status: Evaluated by acceptance criteria

Material Specification and Properties for CrB2

Material number 8 of 15
in SCD Citation Number: Z00795
Chemical Class: Boride
Chemical Family: Cr-B
Formula: CrB2
Informal Name: chromium diboride
Structure Type: Polycrystalline
Process:

CrB2

Material number 8 of 15
in SCD Citation Number: Z00795
Specific Heat
Temperature
 
( K )
Molar Heat
Capacity
( J mol-1 K-1 )
Specific
Heat
( J kg-1 K-1 )
298.16 53.56 727
300 53.68 729
400 58.16 790
500 62.63 851
600 67.11 912
700 71.63 973
800 76.11 1034
900 80.58 1095
1000 85.06 1155
1100 89.54 1216
1200 94.06 1278
Measurement Method: Calorimetry
Evaluation Status: Evaluated by acceptance criteria

Material Specification and Properties for HfB2

Material number 9 of 15
in SCD Citation Number: Z00795
Chemical Class: Boride
Chemical Family: Hf-B
Formula: HfB2
Informal Name: hafnium diboride
Structure Type: Polycrystalline
Process:

HfB2

Material number 9 of 15
in SCD Citation Number: Z00795
Specific Heat
Temperature
 
( K )
Molar Heat
Capacity
( J mol-1 K-1 )
Specific
Heat
( J kg-1 K-1 )
298.16 59.54 298
300 59.62 298
400 62.89 314
500 66.19 331
600 69.45 347
700 72.76 364
800 76.02 380
900 79.33 396
1000 82.59 413
1100 85.90 429
1200 89.16 446
Measurement Method: Calorimetry
Evaluation Status: Evaluated by acceptance criteria

Material Specification and Properties for MoB2

Material number 10 of 15
in SCD Citation Number: Z00795
Chemical Class: Boride
Chemical Family: Mo-B
Formula: MoB2
Informal Name: molybdenum diboride
Structure Type: Polycrystalline
Process:

MoB2

Material number 10 of 15
in SCD Citation Number: Z00795
Specific Heat
Temperature
 
( K )
Molar Heat
Capacity
( J mol-1 K-1 )
Specific
Heat
( J kg-1 K-1 )
298.16 60.46 514
300 60.54 515
400 59.58 507
500 62.26 530
600 66.40 565
700 71.21 606
800 76.40 650
900 81.84 696
1000 87.36 743
1100 92.97 791
1200 98.66 839
Measurement Method: Calorimetry
Evaluation Status: Evaluated by acceptance criteria

Material Specification and Properties for NbB2

Material number 11 of 15
in SCD Citation Number: Z00795
Chemical Class: Boride
Chemical Family: Nb-B
Formula: NbB2
Informal Name: niobium diboride
Structure Type: Polycrystalline
Process:

NbB2

Material number 11 of 15
in SCD Citation Number: Z00795
Specific Heat
Temperature
 
( K )
Molar Heat
Capacity
( J mol-1 K-1 )
Specific
Heat
( J kg-1 K-1 )
298.16 49.41 431
300 49.58 433
400 57.11 499
500 62.72 548
600 67.53 590
700 72.01 629
800 76.27 666
900 80.46 703
1000 84.56 738
1100 88.58 773
1200 92.63 809
Measurement Method: Calorimetry
Evaluation Status: Evaluated by acceptance criteria

Material Specification and Properties for TaB2

Material number 12 of 15
in SCD Citation Number: Z00795
Chemical Class: Boride
Chemical Family: Ta-B
Formula: TaB2
Informal Name: tantalum diboride
Structure Type: Polycrystalline
Process:

TaB2

Material number 12 of 15
in SCD Citation Number: Z00795
Specific Heat
Temperature
 
( K )
Molar Heat
Capacity
( J mol-1 K-1 )
Specific
Heat
( J kg-1 K-1 )
298.16 58.49 289
300 58.62 289
400 62.26 307
500 65.94 326
600 69.62 344
700 73.26 362
800 76.94 380
900 80.63 398
1000 84.27 416
1100 87.95 434
1200 91.59 452
Measurement Method: Calorimetry
Evaluation Status: Evaluated by acceptance criteria

Material Specification and Properties for TiB2

Material number 13 of 15
in SCD Citation Number: Z00795
Chemical Class: Boride
Chemical Family: Ti-B
Formula: TiB2
Informal Name: titanium diboride
Structure Type: Polycrystalline
Process:

TiB2

Material number 13 of 15
in SCD Citation Number: Z00795
Specific Heat
Temperature
 
( K )
Molar Heat
Capacity
( J mol-1 K-1 )
Specific
Heat
( J kg-1 K-1 )
298.16 54.48 784
300 54.60 786
400 57.57 829
500 60.54 871
600 63.51 914
700 66.48 957
800 69.45 1000
900 72.38 1042
1000 75.35 1084
1100 78.32 1127
1200 81.30 1170
Measurement Method: Calorimetry
Evaluation Status: Evaluated by acceptance criteria

Material Specification and Properties for ZrB2

Material number 14 of 15
in SCD Citation Number: Z00795
Chemical Class: Boride
Chemical Family: Zr-B
Formula: ZrB2
Informal Name: zirconium diboride
Structure Type: Polycrystalline
Process:

ZrB2

Material number 14 of 15
in SCD Citation Number: Z00795
Specific Heat
Temperature
 
( K )
Molar Heat
Capacity
( J mol-1 K-1 )
Specific
Heat
( J kg-1 K-1 )
298.16 54.89 486
300 55.06 488
400 63.97 567
500 69.04 612
600 72.59 643
700 75.44 668
800 77.91 690
900 80.12 710
1000 82.26 729
1100 84.27 747
1200 86.19 764
Measurement Method: Calorimetry
Evaluation Status: Evaluated by acceptance criteria

Material Specification and Properties for W2B5

Material number 15 of 15
in SCD Citation Number: Z00795
Chemical Class: Boride
Chemical Family: W-B
Formula: W2B5
Informal Name: ditungsten pentaboride
Structure Type: Polycrystalline
Process:

W2B5

Material number 15 of 15
in SCD Citation Number: Z00795
Specific Heat
Temperature
 
( K )
Molar Heat
Capacity
( J mol-1 K-1 )
Specific
Heat
( J kg-1 K-1 )
298.16 88.24 209
300 89.20 212
400 124.06 294
500 140.67 334
600 150.08 356
700 156.11 370
800 160.33 380
900 163.51 388
1000 166.02 394
1100 168.11 399
1200 169.91 403
Measurement Method: Calorimetry
Evaluation Status: Evaluated by acceptance criteria