NIST Structural Ceramics Database (SCD) Database

NIST Standard Reference Database 30

Last Update to Data Content: 2002

DOI: http://dx.doi.org/10.18434/T4F30D


SCD Citation Number: Z00796

Bibliographic Information

Reference:
"True Heat Capacity of Zirconium, Niobium, and Tantalum Carbides by a Pulse Method," I.I. Petrova and V.Y. Chekhovskoi, High Temperature, Vol. 16 [6], pp. 1045-1050 (1979), published by Plenum Publishing Corporation.
Language: English
Notes: Translated from Teplofizika Vysokikh Temperatur, Vol. 16, 1226 (1978)

General Materials Processing Notes

"An investigation of the true heat capacity of zirconium, niobium, and tantalum carbides was carried out on samples obtained by the method of cold pressing followed by sintering."

Measurement Methods

Heat pulse method
The authors cite N.S. Rasor et al., Rev. Sci. Instrum., Vol. 31, 595 (1960), and summarize the procedure as follows. "The sample under investigation is put into a vacuum or into an inert gas medium, and heated to some constant temperature in a resistance furnace. A pulse of direct current is then passed through the sample, with a value and length such that the radiative losses from the sample during the whole time of the pulse make up a small amount of the energy introduced. In our case they did not exceed 1%. This offers the possibility of making a correction to the losses of energy with a high degree of accuracy. ... the heat capacity can be determined by the (heat balance) relation... The error in determination of the heat capacity in the present work in the investigated interval of tempeatures for ZrC, NbC, and TaC is 3.4%, 3.2%, and 3.3%, respectively."

Index of Materials and Properties (Click on a selected Material Number to expand material properties menu)

Material Specification and Properties for ZrC

Material number 1 of 3
in SCD Citation Number: Z00796
Chemical Class: Carbide
Chemical Family: Zr-C
Formula: ZrC
Informal Name: zirconium carbide
Structure Type: Polycrystalline
Manufacturer: In-House
Process: Sintering

ZrC

Material number 1 of 3
in SCD Citation Number: Z00796
Specific Heat
Temperature
 
( K )
Molar Heat
Capacity
( J mol-1 K-1 )
Specific
Heat
( J kg-1 K-1 )
1650 52.7 510
1750 53.2 515
1780 52.9 512
1820 53.4 517
1910 54.1 524
2020 55.2 535
2080 55.2 535
2230 56.6 548
2295 58.2 564
Measurement Method: Heat pulse method
Evaluation Status: Qualified by acceptance criteria
Cautions:
Data were digitized from Fig. 2 of the reference.

Material Specification and Properties for NbC

Material number 2 of 3
in SCD Citation Number: Z00796
Chemical Class: Carbide
Chemical Family: Nb-C
Formula: NbC
Informal Name: niobium carbide
Structure Type: Polycrystalline
Manufacturer: In-House
Process: Sintering

NbC

Material number 2 of 3
in SCD Citation Number: Z00796
Specific Heat
Temperature
 
( K )
Molar Heat
Capacity
( J mol-1 K-1 )
Specific
Heat
( J kg-1 K-1 )
1700 55.7 531
1770 56.1 535
1850 56.8 541
1930 57.1 544
1980 58.2 555
2045 57.7 550
2170 58.2 555
2245 58.2 555
Measurement Method: Heat pulse method
Evaluation Status: Qualified by acceptance criteria
Cautions:
Data were digitized from Fig. 2 of the reference.

Material Specification and Properties for TaC

Material number 3 of 3
in SCD Citation Number: Z00796
Chemical Class: Carbide
Chemical Family: Ta-C
Formula: TaC
Informal Name: tantalum carbide
Structure Type: Polycrystalline
Manufacturer: In-House
Process: Sintering

TaC

Material number 3 of 3
in SCD Citation Number: Z00796
Specific Heat
Temperature
 
( K )
Molar Heat
Capacity
( J mol-1 K-1 )
Specific
Heat
( J kg-1 K-1 )
1645 57.3 297
1720 58.0 301
1760 58.0 301
1855 58.9 305
1900 59.1 306
1940 58.6 304
1995 58.8 305
2055 60.4 313
2155 60.5 314
2230 61.6 319
2270 61.8 320
Measurement Method: Heat pulse method
Evaluation Status: Qualified by acceptance criteria
Cautions:
Data were digitized from Fig. 2 of the reference.