NIST Standard Reference Database 30
Last Update to Data Content: 2002
"True Heat Capacity of Zirconium, Niobium, and Tantalum Carbides by a Pulse Method," I.I. Petrova and V.Y. Chekhovskoi, High Temperature, Vol. 16 [6], pp. 1045-1050 (1979), published by Plenum Publishing Corporation.Language: English
"An investigation of the true heat capacity of zirconium, niobium, and tantalum carbides was carried out on samples obtained by the method of cold pressing followed by sintering."
The authors cite N.S. Rasor et al., Rev. Sci. Instrum., Vol. 31, 595 (1960), and summarize the procedure as follows. "The sample under investigation is put into a vacuum or into an inert gas medium, and heated to some constant temperature in a resistance furnace. A pulse of direct current is then passed through the sample, with a value and length such that the radiative losses from the sample during the whole time of the pulse make up a small amount of the energy introduced. In our case they did not exceed 1%. This offers the possibility of making a correction to the losses of energy with a high degree of accuracy. ... the heat capacity can be determined by the (heat balance) relation... The error in determination of the heat capacity in the present work in the investigated interval of tempeatures for ZrC, NbC, and TaC is 3.4%, 3.2%, and 3.3%, respectively."
| Temperature ( K ) |
Molar Heat Capacity ( J mol-1 K-1 ) |
Specific Heat ( J kg-1 K-1 ) |
|---|---|---|
| 1650 | 52.7 | 510 |
| 1750 | 53.2 | 515 |
| 1780 | 52.9 | 512 |
| 1820 | 53.4 | 517 |
| 1910 | 54.1 | 524 |
| 2020 | 55.2 | 535 |
| 2080 | 55.2 | 535 |
| 2230 | 56.6 | 548 |
| 2295 | 58.2 | 564 |
Data were digitized from Fig. 2 of the reference.
| Temperature ( K ) |
Molar Heat Capacity ( J mol-1 K-1 ) |
Specific Heat ( J kg-1 K-1 ) |
|---|---|---|
| 1700 | 55.7 | 531 |
| 1770 | 56.1 | 535 |
| 1850 | 56.8 | 541 |
| 1930 | 57.1 | 544 |
| 1980 | 58.2 | 555 |
| 2045 | 57.7 | 550 |
| 2170 | 58.2 | 555 |
| 2245 | 58.2 | 555 |
Data were digitized from Fig. 2 of the reference.
| Temperature ( K ) |
Molar Heat Capacity ( J mol-1 K-1 ) |
Specific Heat ( J kg-1 K-1 ) |
|---|---|---|
| 1645 | 57.3 | 297 |
| 1720 | 58.0 | 301 |
| 1760 | 58.0 | 301 |
| 1855 | 58.9 | 305 |
| 1900 | 59.1 | 306 |
| 1940 | 58.6 | 304 |
| 1995 | 58.8 | 305 |
| 2055 | 60.4 | 313 |
| 2155 | 60.5 | 314 |
| 2230 | 61.6 | 319 |
| 2270 | 61.8 | 320 |
Data were digitized from Fig. 2 of the reference.