NIST Structural Ceramics Database (SCD) Database

NIST Standard Reference Database 30

Last Update to Data Content: 2002

DOI: http://dx.doi.org/10.18434/T4F30D


SCD Citation Number: Z00797

Bibliographic Information

Reference:
"Thermal Expansion of TiB2," E.C. Skaar and William J. Croft, Journal of the American Ceramic Society, Vol. 56 [1], pp. 45-45 (1973), published by American Ceramic Society.
Language: English

General Materials Processing Notes

"...TiB2 (Union Carbide Corp., New York, NY) powder in acetone was applied to the sample stage. The acetone was allowed to evaporate, leaving a fine uniform layer of powder on the stage."

Measurement Methods

X-ray diffraction
The authors cite J. Intrater et al., Rev. Sci. Instrum., Vol. 32, No. 8, 905 (1961), and summarize the procedure as follows. "The X-ray measurements were made on a high-angle diffractometer using Ni-filtered Cu radiation from a high-intensity tube (40 kV and 20 mA). The diffraction angle (2ϑ) was varied continuously from 20° to 122°. Divergence angles of 1° and 4°, respectively, were used on the low and high diffraction angles. The detector was a scintillation counter which was fed into a pulse-height analyzer. The X-ray sample was mounted under vacuum in a high-temperature camera. For low temperatures (25 °C to 800 °C), the sample stage was made of a Pt-Rh alloy, and for the higher temperatures, the Ta stage was used. The temperature was measured and controlled by a Pt - Pt13Rh thermocouple welded to the underside of the stage. A suspension of fine (<200 mesh) TiB2 powder in acetone was applied to the sample stage. The acetone was allowed to evaporate, leaving a fine uniform layer of powder on the stage. The lattice parameters were calculated with each reflection weighted according to Hess' scheme. The Nelson-Riley function was used to allow for the effect of absorption and beam divergence. The cell size was then calculated by extrapolating 2ϑ to 180° and fitted by a least-squares method. ... No hysteresis was observed in any of the measurements."

Index of Materials and Properties

Material Number 1: TiB2

Material Specification and Properties for TiB2

Material number 1 of 1
in SCD Citation Number: Z00797
Chemical Class: Boride
Chemical Family: Ti-B
Formula: TiB2
Informal Name: titanium diboride
Structure Type: Polycrystalline
Manufacturer: Union Carbide Corp.
Process:

TiB2

Material number 1 of 1
in SCD Citation Number: Z00797
Crystal Cell Axes
Temperature
 
( °C )
Temperature
 
( K )
Axis
 
 
Axis Length
 
( Å )
25 298 a 3.027(1)
25 298 c 3.231(1)

Measurement Method: X-ray diffraction
Evaluation Status: Qualified by acceptance criteria

TiB2

Material number 1 of 1
in SCD Citation Number: Z00797
Thermal Expansion
Temperature
 
( °C )
Temperature
 
( K )
Axis
 
 
Thermal
Expansion
( 10-6 K-1 )
25 298 a 7.30
500 773 a 7.28
1000 1273 a 7.25
25 298 c 10.27
500 773 c 10.23
1000 1273 c 10.20

Measurement Method: X-ray diffraction
Evaluation Status: Qualified by acceptance criteria