SI units, unit symbols, and unit prefixes are used in the NIST Property Data Summaries.
Uncertainties:
No attempt has been made to assign uncertainties to the individual values obtained
from the literature. A survey of data in the NIST Structural Ceramics Database
indicates that relative combined standard uncertainties in the range of 5 % to 15 %
are not unusual for fracture toughness measurements. Exceptional cases having reported
uncertainties as low as 1 % or as high as 30 % can be found, but such cases are very
unusual. For a comprehensive discussion on estimates of uncertainty, see "Guidelies
for Evaluating and Expressing the Uncertainty of NIST Measurement Results,"
by B. N. Taylor and C. E. Kuyatt, NIST Technical Note 1297.
DISCLAIMERS:
A substantial effort has been made to select data for this database on the basis of sound scientific judgment. However, the National Institute of Standards and Technology (NIST) makes no warranties regarding its use, and NIST shall not be liable for any damage that may result from errors or omissions in the database.
Certain trade names and other commercial designations are used in this work for the purpose of clarity. In no case does such identification imply endorsement by the National Institute of Standards and Technology, nor does it imply that products or services so identified are necessarily the best available for the purpose.
DATA EVALUATION:
How are data evaluated?
Scientific and technical data may be examined from three viewpoints:
how well is the data generation described,
how do the data follow the known physical laws,
and how do the data compare to other measurements or calculations of the same phenomena.
The description of data generation is crucial. The identification and control of all relevant independent variables must be addressed and demonstrated. For mature areas such as thermodynamics and atomic physics, many measurement techniques are well characterized. In these cases, the adherence to physical laws and intercomparisons predominate. For areas in which behavior is not well understood, such as corrosion, data from different experiments are not usually comparable. Consequently, documentation of control of the experimental condition is most important.
Property Data Summaries are collections of property values derived from surveys of published data.
These collections typically focus on either one material or one particular property.
Studies of specific materials typically include thermal, mechanical, structural, and chemical properties,
while studies of particular properties survey one property across many materials. The property values may be typical,
evaluated, or validated. Values described as typical are derived from values for nominally similar materials.
CAUTION!
Typical values are only representative of trends of values commonlyfound for a general class
of materials and are not necessarily the best or most appropriate valuesfor any particular material.
Data Evaluation Levels
The data evaluation levels used throughout the NIST Ceramics WebBook are:
Certified (standard reference values)
Validated (confirmed via correlations and models)
Evaluated (basic acceptance criteria satisfied)
Commercial (manufacturer's data)
Typical (derived from surveys)
Research (preliminary values; work in progress)
Unevaluated (all other data)
Use of Commercial Names
Certain commercial equipment, instruments, or materials are identified in this document to specify adequately
the experimental procedures and conditions. Such identification does not imply recommendation or endorsement
by the National Institute of Standards and Technology, nor does it imply that the materials or equipment identified
are necessarily the best available for the purpose.
Fracture Toughness / Fracture Energy Data for Ceramics
Fracture Toughness Data for Brittle Materials
R.G. Munro, S.W. Freiman, and T.L. Baker
NISTIR 6153 (National Institute of Standards and Technology, 1998)
[Ref. 1-5] [Ref. 6-8] [Ref. 9]
Manufacturer........: In laboratory In laboratory Toyo Soda Manf. Co.
Material Designation: zirconia (TZP) zirconia (TZP) zirconia (TZP)
Material Form.......: polycrystal polycrystal polycrystal
Composition.........: ZrO2·xY2O3 ZrO2·xCeO2 ZrO2· 3% Y2O3
(mole fraction)
Processing..........: Sintered Sintered Sintered and post-hipped
References:
[1] T.E. Fischer, M.P. Anderson, and S. Jahanmir, "Influence of Fracture Toughness
on the Wear Resistance of Yttria-Doped Zirconium Oxide,"
Journal of the American Ceramic Society, Vol. 72, pp. 252-257 (1989).
[2] G.D. Quinn, R.J. Gettings, and J.J. Kubler, "Fracture Toughness by the
Surface Crack in Flexure (SCF) Method: Results of the VAMAS Round Robin,"
Ceramic Engineering and Science Proceedings, Vol. 15, pp. 846-855 (1994).
[3] J. Wang, W.M. Rainforth, T. Wadsworth, and R. Stevens,
"The Effects of Notch Width on the SENB Toughness for Oxide Ceramics,"
Journal of the European Ceramic Society, Vol. 10, pp. 21-31 (1992).
[4] G.A. Gogotsi, A.V. Drozdov, V.P. Zavata, and M.V. Swain,
"Comparison of the Mechanical Behaviour of Zirconia Partially Stabilized
with Yttria and Magnesia," Journal of the Australasian Ceramic Society,
Vol. 27, pp. 37-49 (1991).
[5] G.A. Gogotsi, E.E. Lomonova, and V.G. Pejchev, "Strength and Fracture
Toughness of Zirconia Crystals," Journal of the European Ceramic Society,
Vol. 11, pp. 123-132 (1993).
[6] S. Maschio, O. Sbaizero and S. Meriani, "Mechanical Properties in
the Ceria-Zirconia System," Journal of the European Ceramic Society,
Vol. 9, pp. 127-132 (1992).
[7] K. Tsukuma and M. Shimada, "Strength, Fracture Toughness and
Vickers Hardness of CeO2-Stabilized Tetragonal ZrO2 Polycrystals (Ce-TZP),"
Journal of Materials Science, Vol. 20, pp. 1178-1184 (1985).
[8] K. Tsukuma, "Mechanical Properties and Thermal Stability of CeO2 Containing
Tetragonal Zirconia Polycrystals," American Ceramic Society Bulletin,
Vol. 65, pp. 1386-1389 (1986).
[9] J. Kubler, "Fracture Toughness of Ceramics Using the SEVNB Method: Preliminary Results,"
Ceramic Engineering and Science Proceedings, Vol. 18 (4), pp. 155-162 (1997).
Property Table:
Temperature = 23 °C
Grain Porosity Fracture Fracture Measurement Measurement Comments
Size Toughness Energy Method Environment
[µm] [%] [MPa·m1/2] [J/m2]
------ -------- ------------ --------- ----------- ----------- --------------------------------
11.6 NDC air Ref. 1; 3 % Y2O3
--------------------------------------------------------------------------------------------------------
4.4 SCF air Ref. 2; 3 % Y2O3
--------------------------------------------------------------------------------------------------------
1.4 17.2 SENB air Ref. 3; 2.0 % Y2O3;
250 µm notch width
1.4 11.2 SENB air 2.5 %; 93 µm notch width
1.3 12.3 SENB air 3.0 %; 130 µm notch width
--------------------------------------------------------------------------------------------------------
Ref. 4; 2.6 % Y2O3;
9.5 SENB air notch
5.6 SENB air sharp crack
--------------------------------------------------------------------------------------------------------
10.6 SENB air Ref. 5; 3 % Y2O3
--------------------------------------------------------------------------------------------------------
10.0 SENB air Ref. 6; 10 % CeO2
8.5 SENB air 12 %
4.4 SENB air 14 %
4.3 SENB air 16 %
4.0 SENB air 24 %
3.2 SENB air 32 %
2.6 SENB air 40 %
2.0 SENB air 48 %
--------------------------------------------------------------------------------------------------------
0.5 8.7 ICS air Ref. 7; 8.6 % CeO2
0.5 6.4 ICS air 9.5 %
0.5 5.3 ICS air 10.8 %
0.5 4.9 ICS air 12.2 %
0.5 4.4 ICS air 15.8 %
2.5 17.1 ICS air 8.6 %
2.5 16.9 ICS air 9.5 %
2.5 12.6 ICS air 10.8 %
2.5 9.5 ICS air 12.2 %
2.5 5.8 ICS air 15.8 %
--------------------------------------------------------------------------------------------------------
0.5 23.0 ICS air Ref. 8; 12 % CeO2
0.5 8.0 ICS air 14 %
0.5 4.0 ICS air 16 %
1.0 36.0 ICS air 12 %
1.0 9.0 ICS air 14 %
1.0 5.0 ICS air 16 %
--------------------------------------------------------------------------------------------------------
0.45 4.7 SENB air Ref. 9; V-notch;
3 % Y2O3
--------------------------------------------------------------------------------------------------------