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NIST X-ray Photoelectron Spectroscopy Database (SRD 20), Version 5.0

Details Summary:
Summary Page
Tab Page Summary

General:
Element:
Ru
Formula:
[Ru(NH3)5(NCCH3)](PF6)2
XPS Formula:
[Ru*(NH3)5(NCCH3)](PF6)2
Name:
pentaammine(acetonitrile)ruthenium bis(hexafluorophosphate))
CAS Registry No:
Class:
(iso)cyanide, ammonia-aminyl ligand, fluoride, nitrogen

Citation:
Author Name(s):
Shepherd R.E., Proctor A., Henderson W.W., Myser T.K.
Journal:
Inorg. Chem. 26, 2440
DOI:
Pub Year:
1987

Data Processing:
Data Type:
Photoelectron Line
Line Designation:
3d5/2
Binding Energy (eV)
280.50
Energy Uncertainty:
0.2
Background Subtraction Method:
other
Peak Location Method:
other type of curve fit
Full Width at Half-maximum Intensity (eV):
Gaussian Width (eV):
Lorentzian Width (eV):

Measurement:
Use of X-ray Monochromator:
Yes
Anode Material:
Al
X-ray Energy:
Overall Energy Resolution (eV):
Calibration:
Au4f7 = 84.00
Charge Reference:
Internal hydrocarbon
Energy Scale Evaluation:
Reliable, with one-point correction of energy scale
Comment:
The linearity of the spectrometer over 0-1000 eV was 0.1 eV. The binding energy of adventitious carbon on gold foil was 284.6 eV. Doublet separation for the Ru3d was 4.1 eV. Branching ratio was 0.69

Specimen:
Specimen:
Method of Determining Specimen Composition:
Method of Determining Specimen Crystallinity:
Specimen Temperature (K):
300
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