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NIST X-ray Photoelectron Spectroscopy Database (SRD 20), Version 5.0

Details Summary:
Summary Page
Tab Page Summary

General:
Element:
S
Formula:
CH3SH/Ru
XPS Formula:
methylthiolate species adsorbed in high coordination bonding sites
Name:
methanethiol/ruthenium
CAS Registry No:
74-93-1
Class:
element, thiol

Citation:
Author Name(s):
Mullins D.R., Lyman P.F.
Journal:
J. Phys. Chem. 97, 12008
DOI:
Pub Year:
1993

Data Processing:
Data Type:
Photoelectron Line
Line Designation:
2p3/2
Binding Energy (eV)
162.95
Energy Uncertainty:
Background Subtraction Method:
Peak Location Method:
data
Full Width at Half-maximum Intensity (eV):
Gaussian Width (eV):
Lorentzian Width (eV):

Measurement:
Use of X-ray Monochromator:
Yes
Anode Material:
other source
X-ray Energy:
208
Overall Energy Resolution (eV):
Calibration:
FL = Fermi level
Charge Reference:
Conductor
Energy Scale Evaluation:
Reliable (reported energy within 300 eV of a reference energy)
Comment:
0.22 ML CH3SH was desorbed onto single crystalline Ru(0001) at 100 K. There is a shoulder at lower binding energies. The substrate was cleaned by Ar+ ion bombardment and annealing (T = 1500 K).

Specimen:
Specimen:
Method of Determining Specimen Composition:
Auger Electron Spectroscopy
Method of Determining Specimen Crystallinity:
X-ray Diffraction
Specimen Temperature (K):
150, 200
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