NIST X-ray Photoelectron Spectroscopy Database

NIST X-ray Photoelectron Spectroscopy Database (SRD 20), Version 5.0

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O

Rh₄(CO)₁₂/C

oxygens in terminal carbonyl ligands

tetra-mu-carbonyl-nonacarbonyl tetrahedro-tetrarhodium/carbon

CAS Registry No:

19584-30-6

carbonyl ligand, catalyst, cluster, organometallic

Author Name(s):

Apai G., Frederick B.G.

Langmuir 3, 395

Pub Year:

1987

book All Records in this Publication

Photoelectron Line

Line Designation:

1s

Binding Energy (eV):

534.20

Energy Uncertainty:

Background Subtraction Method:

Other

Peak Location Method:

Gaussian

Full Width at Half-maximum Intensity (eV):

1.5

Gaussian Width (eV):

Lorentzian Width (eV):

Use of X-ray Monochromator:

No

Anode Material:

Mg

X-ray Energy:

Overall Energy Resolution (eV):

Calibration:

Other, C1s=284.44

Charge Reference:

Internal hydrocarbon

Energy Scale Evaluation:

Reliable, with one-point correction of energy scale

Comment:

1-3 ML Rh6(CO)12/C. C1s energy of the substrate carbon atoms (Eb = 284.44 eV) was used for charge reference.

surface coverage from 1ML to 2ML (1ML <= coverage < 2ML), surface coverage from 2ML to 3ML (2ML <= coverage < 3ML), surface coverage from 3ML to 4ML (3ML <= coverage < 4ML), thin layer, vapor deposited

Method of Determining Specimen Composition:

Method of Determining Specimen Crystallinity:

Specimen Temperature (K):

193

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